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The use of thermal analysis in assessing the effect of temperature on a cement paste

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TLDR
In this article, the effect of temperature in the mineralogical composition of cement hydration products has been studied using thermogravimetric analysis (TGA) and DTG curves, which can be used to determine fire conditions and the consequent deterioration expected in the cement paste.
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This article is published in Cement and Concrete Research.The article was published on 2005-03-01. It has received 709 citations till now. The article focuses on the topics: Cement & Portlandite.

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Confined Water Dissociation in Disordered Silicate Nanometer-Channels at Elevated Temperatures: Mechanism, Dynamics and Impact on Substrates

TL;DR: The effects of elevated temperature on the physical and chemical properties of water molecules filled in the nanometer-channels of calcium silicate hydrate have been investigated by performing reactive molecular dynamics simulation on C-S-H gel subjected to high temperature from 500 to 1500 K.
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Performance Assessment of Passive Fire Protection Materials

TL;DR: In this article, the performance of fireproofing materials in providing effective protection from fire strongly depends on the thermophysical properties and on the behavior of the material during fire exposure, and the changes in morphology and in the physical properties of active and non-active materials were investigated.
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Spalling, Thermal, and Hydrous Behavior of Ordinary and High-Strength Concrete Subjected to Elevated Temperature

TL;DR: In this paper, the experimental results of five concrete mixes subjected to high temperatures were presented with the aim of highlighting explosive spalling, and the authors showed that the thermal stability of the concrete mixes was a function of the water to cement ratio, heating rate, and specimen dimensions.
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Effect of Graphene Oxide on Mechanical Properties of Cement Mortar and its Strengthening Mechanism.

TL;DR: A possible working mechanism was proposed by which GO nanosheets prevented the expansion of microcracks in the cement pastes via a shield effect, thus enhancing the strength and toughness of the cement composites.
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The properties of reactive powder concrete using PP fiber and pozzolanic materials at elevated temperature

TL;DR: In this paper, the effect of polypropylene (PP) fiber on spalling protection of Reactive Powder Concrete (RPC) subjected to fire was investigated and the results showed that the modified RPC significantly reduced the content of cement and silica fume compared to the conventional RPC mixture by the combination of ternary pozzolanic materials.
References
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Compressive strength of concrete at high temperatures: a reassessment

TL;DR: In this paper, a reassessment of the subject is given, which considers material and environmental factors/mechanisms influencing the strength of concrete during the heat cycle and after cooling, not all of which necessarily result in strength loss.
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Thermal stability and decomposition mechanisms of ettringite at <120°C

TL;DR: In this article, the decomposition and reformation of ettringite is studied as a function of water vapour pressure and temperature, and the authors make recommendations for the upper safe service limits for ETTringite-based cements.
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Physicochemical, mineralogical, and morphological characteristics of concrete exposed to elevated temperatures

TL;DR: In this paper, the effect of elevated temperatures on the mineralogical changes occurring in the hydrated phases of concrete cubes were studied by measuring ultrasonic pulse velocity (UPV) and consequent deterioration in the compressive strength with increase in temperature.
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Differential scanning calorimetry study of ordinary Portland cement

TL;DR: In this article, the thermal behavior of hydration products in ordinary Portland cement as a function of age was investigated using differential scanning calorimeter (DSC) and X-ray diffraction analysis.
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Elastic properties of high alumina cement castables from room temperature to 1600°C

TL;DR: In this article, high-alumina refractory castables with compositions in the systems CaO-Al2O3 and CaO−Al 2O3-SiO2 were studied using an ultrasonic technique.