Journal ArticleDOI
Thermal kinetics and reactive mechanism of cellulose nitrate decomposition by traditional multi kinetics and modeling calculation under isothermal and non-isothermal conditions
TLDR
In this article, a high-fitting degree was obtained for isothermal and non-isothermal DSC experiments of cellulose nitrate, and the model corresponding to isothermal conditions was f(α) = 4(1 − α)[−ln( 1 − α)]3/4, while for nonisothermal conditions the model was identified as f( α) = (1 −α)3.About:
This article is published in Industrial Crops and Products.The article was published on 2020-03-01. It has received 41 citations till now. The article focuses on the topics: Isothermal process & Thermal decomposition.read more
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Pyrolysis kinetics and reaction mechanism of expandable polystyrene by multiple kinetics methods
TL;DR: In this article, the authors investigated the pyrolysis of expandable polystyrene (EPS) and established a reaction mechanism and calculated the kinetic parameters by Coats-Redfern and masterplots methods.
Journal ArticleDOI
Synthesis, Characterization, and Thermal Decomposition Kinetics of Nitrogen-Rich Energetic Biopolymers from Aminated Giant Reed Cellulosic Fibers
Ahmed Fouzi Tarchoun,Ahmed Fouzi Tarchoun,Djalal Trache,Thomas M. Klapötke,Mekki Belmerabet,Amir Abdelaziz,Mehdi Derradji,Raouf Belgacemi +7 more
TL;DR: In this paper, the exploration of giant reed (Arundo donax L., AD) as a viable and underutilized sustainable resource for the development of energetic nitrogen-rich dense biopolymers base is discussed.
Journal ArticleDOI
New insensitive high-energy dense biopolymers from giant reed cellulosic fibers: their synthesis, characterization, and non-isothermal decomposition kinetics
Ahmed Fouzi Tarchoun,Ahmed Fouzi Tarchoun,Djalal Trache,Thomas M. Klapötke,Aimen Selmani,Mohamed Chiheb Saada,Salim Chelouche,Abderrahmane Mezroua,Amir Abdelaziz +8 more
TL;DR: Renewable giant reed has been explored for the first time to develop new advanced high-energy dense biopolymers through carbamate surface functionalization and nitration of native cellulose and cellulose microcrystals.
Journal ArticleDOI
Characterization and prediction of ceiling temperature propagation of thermal plume in confined environment of common services tunnel
TL;DR: In this article, a numerical investigation on the propagation of ceiling gas temperature of thermal plume in a common services tunnel, especially focusing on the influence of the isolated closed-end, which causes significant difference from the traffic tunnel.
Journal ArticleDOI
Towards investigating the characteristics and thermal kinetic behavior of emergent nanostructured nitrocellulose prepared using various sulfonitric media
Ahmed Fouzi Tarchoun,Zakaria Bekkar Djelloul Sayah,Djalal Trache,Thomas M. Klapötke,Mekki Belmerabt,Amir Abdelaziz,Slimane Bekhouche +6 more
References
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Journal ArticleDOI
Kinetic Parameters from Thermogravimetric Data
A. W. Coats,J. P. Redfern +1 more
TL;DR: In this article, a thermocouple is used to measure the sample temperature in a Stanton HT-D thermobalance, the bead of which is positioned in or near the sample, depending on crucible design.
Journal ArticleDOI
A New Method of Analyzing Thermogravimetric Data
TL;DR: In this paper, a new method of obtaining the kinetic parameters from thermogravimetric curves has been proposed, which is simple and applicable to reactions which can not be analyzed by other methods.
Journal ArticleDOI
ICTAC Kinetics Committee recommendations for performing kinetic computations on thermal analysis data
Sergey Vyazovkin,Alan K. Burnham,José M. Criado,Luis A. Pérez-Maqueda,Crisan Popescu,Nicolas Sbirrazzuoli +5 more
TL;DR: In this article, the authors have developed recommendations for reliable evaluation of kinetic parameters (the activation energy, the preexponential factor, and the reaction model) from the data obtained by means of thermal analysis methods such as TGA, differential scanning calorimetry (DSC), and differential thermal analysis (DTA).
Journal ArticleDOI
Kinetics of thermal degradation of char-forming plastics from thermogravimetry. Application to a phenolic plastic
TL;DR: In this article, a technique was devised for obtaining rate laws and kinetic parameters which describe the thermal degradation of plastics from TGA data, based on the inter-comparison of experiments which were performed at different linear rates of heating.
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