scispace - formally typeset
Journal ArticleDOI

Viscosity and Density of Five Hydrocarbon Liquids at Pressures up to 200 MPa and Temperatures up to 473 K

Reads0
Chats0
TLDR
In this paper, Caudwell et al. reported the results of simultaneous measurements of the viscosity and density of five pure hydrocarbon liquids (octane, decane, 1,3-dimethylbenzene, 1 2,3,4-tetrahydronaphthalene, and 1-methylnaphalene) at temperatures between (298.15 and 473.15) K and at pressures ranging from 0.1 MPa to approximately 200 MPa.
Abstract
We report the results of simultaneous measurements of the viscosity and density of five pure hydrocarbon liquids (octane, decane, 1,3-dimethylbenzene, 1,2,3,4-tetrahydronaphthalene, and 1-methylnaphthalene) at temperatures between (298.15 and 473.15) K and at pressures ranging from 0.1 MPa to approximately 200 MPa. The measurements were made with a vibrating-wire instrument, and the estimated expanded relative uncertainties are ± 2 % for viscosity and ± 0.2 % for density with a coverage factor of 2. The densities were correlated by means of a modified Tait equation, while the viscosities were correlated both with the theory of Dymond and Assael and in terms of an empirical function of temperature and pressure. We also present correlations of the viscosity of dodecane and octadecane based on results that we published previously [Caudwell et al. Int. J. Thermophys. 2004, 25, 1340−1352]. Extensive comparisons with literature data are presented.

read more

Citations
More filters
Journal ArticleDOI

Recent progress in the development of diesel surrogate fuels

TL;DR: There has been much recent progress in the area of surrogate fuels for diesel as discussed by the authors, however, major research gaps remain, and no detailed chemical kinetic models or experimental investigations are available for such compounds.
Journal ArticleDOI

Group Contribution Method for Viscosities Based on Entropy Scaling Using the Perturbed-Chain Polar Statistical Associating Fluid Theory

TL;DR: In this paper, a new predictive entropy-scaling approach for Newtonian shear viscosities based on group contributions is proposed, which is formulated as a third order polynomial in terms of the residual entropy as calculated from a group-contribution perturbed-chain polar statistical associating fluid theory (PCP-SAFT).
Journal ArticleDOI

Equation of state modeling of high-pressure, high-temperature hydrocarbon density data

TL;DR: In this article, the authors reported experimental densities for n-pentane, n-octane, cyclooctane, 2,2,4-trimethylpentane and toluene to ∼280 MPa and ∼250 °C.
Journal ArticleDOI

Viscosity models for pure hydrocarbons at extreme conditions: A review and comparative study

TL;DR: In this paper, the performance of seven select viscosity models, representative of various predictive and correlative approaches, is discussed and evaluated by comparison to experimental data of 52 pure hydrocarbons including straight-chain alkanes, branched alkane, cycloalkanes, and aromatics.
Journal ArticleDOI

Entropy scaling based viscosity predictions for hydrocarbon mixtures and diesel fuels up to extreme conditions

TL;DR: In this article, an entropy scaling based technique using the Perturbed-Chain Statistical Associating Fluid Theory is described for predicting the viscosity of hydrocarbon mixtures and diesel fuels up to high temperatures and high pressures.
References
More filters
Journal ArticleDOI

Short Fundamental Equations of State for 20 Industrial Fluids

TL;DR: In this paper, the coefficients of these short forms for the equations of state have been fitted for the fluids acetone, carbon monoxide, carbonyl sulfide, decane, hydrogen sulfide and fluoromethane.
Journal ArticleDOI

Equations of state for technical applications. III. Results for polar fluids

TL;DR: In this article, new functional forms have been developed for multiparameter equations of state for non-and weakly polar fluids and for polar fluids, which were established with an optimization algorithm which considers data sets for different fluids simultaneously.
Journal ArticleDOI

Correlation and prediction of dense fluid transport coefficients. I. n-alkanes

TL;DR: In this article, a method based on considerations of hard-sphere theory is used for simultaneous correlation of the coefficients of viscosity, self-diffusion, and thermal conductivity for then-alcohols, from methanol ton-decanol, in excellent agreement with experiment, over extended temperature and pressure ranges.
Book

Transport Properties of Fluids: Their Correlation, Prediction and Estimation

TL;DR: The paper presents a meta-analyses of the properties of dilute gases and gaseous mixtures at low density - alkali metal vapours through the lens of E. V. Vesovic, E. Vogel, and the corresponding-states principle, which describes the behaviour of dense fluids under these conditions.
Journal ArticleDOI

The Viscosity and Density of n-Dodecane and n-Octadecane at Pressures up to 200 MPa and Temperatures up to 473 K

TL;DR: In this paper, a vibrating-wire instrument for simultaneous measurement of the density and viscosity of liquids under conditions of high pressure is described, which is capable of operation at temperatures between 298.15 and 473.15 K at pressures up to 200 MPa.
Related Papers (5)