Many materials systems are currently under consideration as potential replacements for SiO2 as the gate dielectric material for sub-0.1 μm complementary metal–oxide–semiconductor (CMOS) technology. A systematic consideration of the required properties of gate dielectrics indicates that the key guidelines for selecting an alternative gate dielectric are (a) permittivity, band gap, and band alignment to silicon, (b) thermodynamic stability, (c) film morphology, (d) interface quality, (e) compatibility with the current or expected materials to be used in processing for CMOS devices, (f) process compatibility, and (g) reliability. Many dielectrics appear favorable in some of these areas, but very few materials are promising with respect to all of these guidelines. A review of current work and literature in the area of alternate gate dielectrics is given. Based on reported results and fundamental considerations, the pseudobinary materials systems offer large flexibility and show the most promise toward success...

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High-κ gate dielectrics: Current status and materials properties considerations

Hafnium and zirconium silicate (HfSixOy and ZrSixOy, respectively) gate dielectric films with metal contents ranging from ∼3 to 30 at. % Hf, or 2 to 27 at. % Zr (±1 at. % for Hf and Zr, respectively, within a given film), have been investigated, and films with ∼2–8 at. % Hf or Zr exhibit excellent electrical properties and high thermal stability in direct contact with Si. Capacitance–voltage measurements show an equivalent oxide thickness tox of about 18 A (21 A) for a 50 A HfSixOy (50 A ZrSixOy) film deposited directly on a Si substrate. Current–voltage measurements show for the same films a leakage current of less than 2×10−6 A/cm2 at 1.0 V bias. Hysteresis in these films is measured to be less than 10 mV, the breakdown field is measured to be EBD∼10 MV/cm, and the midgap interface state density is estimated to be Dit∼1–5×1011 cm−2 eV−1. Au electrodes produce excellent electrical properties, while Al electrodes produce very good electrical results, but also react with the silicates, creating a lower e l...

Hafnium and zirconium silicates for advanced gate dielectrics

Starting with a brief review on 0.1-/spl mu/m (100 nm) CMOS status, this paper addresses the key challenges in further scaling of CMOS technology into the nanometer (sub-100 nm) regime in light of fundamental physical effects and practical considerations. Among the issues discussed are: lithography, power supply and threshold voltage, short-channel effect, gate oxide, high-field effects, dopant number fluctuations and interconnect delays. The last part of the paper discusses several alternative or unconventional device structures, including silicon-on-insulator (SOI), SiGe MOSFET's, low-temperature CMOS, and double-gate MOSFET's, which may lead to the outermost limits of silicon scaling.

CMOS scaling into the nanometer regime

Quantum-mechanical modeling of electron tunneling current from the quantized inversion layer of ultra-thin-oxide (<40 /spl Aring/) nMOSFET's is presented, together with experimental verification. An accurate determination of the physical oxide thickness is achieved by fitting experimentally measured capacitance-versus-voltage curves to quantum-mechanically simulated capacitance-versus-voltage results. The lifetimes of quasibound states and the direct tunneling current are calculated using a transverse-resonant method. These results are used to project an oxide scaling limit of 20 /spl Aring/ before the chip standby power becomes excessive due to tunneling currents,.

Quantum-mechanical modeling of electron tunneling current from the inversion layer of ultra-thin-oxide nMOSFET's

A three-dimensional (3-D) "atomistic" simulation study of random dopant induced threshold voltage lowering and fluctuations in sub-0.1 /spl mu/m MOSFETs is presented. For the first time a systematic analysis of random dopant effects down to an individual dopant level was carried out in 3-D on a scale sufficient to provide quantitative statistical predictions. Efficient algorithms based on a single multigrid solution of the Poisson equation followed by the solution of a simplified current continuity equation are used in the simulations. The effects of various MOSFET design parameters, including the channel length and width, oxide thickness and channel doping, on the threshold voltage lowering and fluctuations are studied using typical samples of 200 atomistically different MOSFETs. The atomistic results for the threshold voltage fluctuations were compared with two analytical models based on dopant number fluctuations. Although the analytical models predict the general trends in the threshold voltage fluctuations, they fail to describe quantitatively the magnitude of the fluctuations. The distribution of the atomistically calculated threshold voltage and its correlation with the number of dopants in the channel of the MOSFETs was analyzed based on a sample of 2500 microscopically different devices. The detailed analysis shows that the threshold voltage fluctuations are determined not only by the fluctuation in the dopant number, but also in the dopant position.

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Random dopant induced threshold voltage lowering and fluctuations in sub-0.1 /spl mu/m MOSFET's: A 3-D "atomistic" simulation study

In this paper, normal operation of a MOSFET with an ultra-thin direct-tunneling gate oxide is reported for the first time. These high current drive n-MOSFET's were fabricated with a 1.5 nm direct-tunneling gate oxide. They operate well at gate lengths of around 0.1 /spl mu/m, because the gate leakage current falls in proportional to the gate length, while the drain current increases in inverse proportion. A current drive of more than 1.0 mA//spl mu/m and a transconductance of more than 1,000 mS/mm were obtained at a gate length of 0.09 /spl mu/m at room temperature. These are the highest values ever obtained with Si MOSFET's at room temperature. Further, hot-carrier reliability is shown to improve as the thickness of the gate oxide is reduced, even in the 1.5 nm case. This work clarifies that excellent performance-a transconductance of over 1,000 mS/mm at room temperature-can be obtained with Si MOSFET's if a high-capacitance gate insulator is used.

1.5 nm direct-tunneling gate oxide Si MOSFET's

The sheet resistance of TiSi/sub 2/-polycide (TiSi/sub 2/-polysilicon) lines increases as they are made narrower. This phenomenon has been investigated in detail. It is found that the relationship between sheet resistance and line width (W) is characterized by three distinct regions according to the value of W. The abrupt increase in sheet resistance observed in the region W/spl les/0.2 /spl mu/m cannot be explained in terms of the phase transition from C54 to C49, which we show to be the cause of the rising resistance at larger W. By adopting a new test pattern for sheet resistance measurements and using it in combination with TEM and EDX analysis we conclude that the cause of this abrupt increase is the presence of large inter-grain layers where silicide is very sparse. On the contrary, NiSi films have no such inter-grain layers, and good resistance values can be obtained even with 0.1 /spl mu/m lines. The NiSi process appears to be a suitable candidate to replace TiSi/sub 2/ in future deep-sub-micron high-speed CMOS devices. >

Analysis of resistance behavior in Ti- and Ni-salicided polysilicon films

Although direct tunneling gate oxide MOSFETs are expected to be useful in high-performance applications of future large-scale integrated circuits (LSIs), there are many concerns related to their manufacture. The uniformity, reliability, and dopant penetration of 1.5-nm direct-tunneling gate oxide MOSFETs were investigated for the first time. The variation of oxide thickness in an entire 150-mm wafer was evaluated by TEM and electrical measurements. Satisfactory values of standard deviations in the TEM measurements and threshold voltage measurements for MOSFETs with a gate area of 5 /spl mu/m/spl times/0.75 /spl mu/m, were obtained. These values improved significantly in the case of MOS capacitors with larger gate areas. The oxide breakdown field and the reliability with respect to charge injection were evaluated for the 1.5-nm gate oxides and found to be better than those of thicker gate oxides. Dopant penetration was not observed in n/sup +/ polysilicon gates subjected to RTA at 1050/spl deg/C for 20 s and furnace annealing at 850/spl deg/C for 30 min. Although much more data will be required to judge the manufacturing feasibility, these results suggest that 1.5-nm direct-tunneling oxide MOSFETs are likely to have many practical applications.

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Study of the manufacturing feasibility of 1.5-nm direct-tunneling gate oxide MOSFETs: uniformity, reliability, and dopant penetration of the gate oxide

Ultra-high performance n-MOSFETs were fabricated with a tunneling gate oxide 1.5 nm thick. It was found that these devices operate well when the gate length is around 0.1 /spl mu/m, because gate leakage current falls in proportion to the gate length and the drain current increases in inverse proportion. A very high drivability of 1.1 mAspl mu/m at 15 V was obtained, even in devices with a 0.14 pm gate length. A record high transconductance, 1,010 mS/mm at room temperature was also obtained in 0.09 /spl mu/m MOSFETs. Confirmation was obtained that hot-carrier reliability improves as the gate oxide thickness is reduced, even in the 1.5 nm case. High current drive at the low supply voltage of 0.5 V was also demonstrated. We made clear that very high performance is obtained in Si MOSFETs, if we can use a high capacitance gate insulator. In future devices, the tunnel gate oxide may be a good candidate for such a gate film, depending upon their applications. >

Tunneling gate oxide approach to ultra-high current drive in small geometry MOSFETs

An 0.18-/spl mu/m CMOS technology with multi-V/sub th/s for mixed high-speed digital and RF-analog applications has been developed. The V/sub th/s of MOSFETs for digital circuits are 0.4 V for NMOS and -0.4 V for PMOS, respectively. In addition, there are n-MOSFET's with zero-volt-V/sub th/ for RF analog circuits. The zero-volt-V/sub th/ MOSFETs were made by using undoped epitaxial layer for the channel regions. Though the epitaxial film was grown by reduced pressure chemical vapor deposition (RP-CVD) at 750/spl deg/C, the film quality is as good as the bulk silicon because high pre-heating temperature (940/spl deg/C for 30 s) is used in H/sub 2/ atmosphere before the epitaxial growth. The epitaxial channel MOSFET shows higher peak g/sub m/ and f/sub T/ values than those of bulk cases. Furthermore, the g/sub m/ and f/sub T/ values of the epitaxial channel MOSFET show significantly improved performances under the lower supply voltage compared with those of bulk. This is very important for RF analog application for low supply voltage. The undoped-epitaxial-channel MOSFETs with zero-V/sub th/ will become a key to realize high-performance and low-power CMOS devices for mixed digital and RF-analog applications.

S. Nakamura

Papers

1.5 nm direct-tunneling gate oxide Si MOSFET's

Analysis of resistance behavior in Ti- and Ni-salicided polysilicon films

Study of the manufacturing feasibility of 1.5-nm direct-tunneling gate oxide MOSFETs: uniformity, reliability, and dopant penetration of the gate oxide

Tunneling gate oxide approach to ultra-high current drive in small geometry MOSFETs

An 0.18-/spl mu/m CMOS for mixed digital and analog applications with zero-volt-V/sub th/ epitaxial-channel MOSFETs