T
Tomas Hudlicky
Researcher at Brock University
Publications - 461
Citations - 11149
Tomas Hudlicky is an academic researcher from Brock University. The author has contributed to research in topics: Total synthesis & Toluene dioxygenase. The author has an hindex of 51, co-authored 460 publications receiving 10540 citations. Previous affiliations of Tomas Hudlicky include Procter & Gamble & University of Geneva.
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Unexpected reactivity of the burgess reagent with thiols: synthesis of symmetrical disulfides.
TL;DR: Reaction of the Burgess reagent with a series of aliphatic and aromatic thiols led to the corresponding symmetrical disulfides in high yields.
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Cyclotrimerization strategy toward analogues of amaryllidaceae constituents. synthesis of deoxygenated pancratistatin core.
TL;DR: A derivative of pancratistatin having no oxygenation in the aromatic ring was synthesized by a new strategy based on the cobalt-catalyzed cyclotrimerization of acetylenes as a prelude to diversity-oriented synthesis of further analogues.
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Oxa- and Azabicyclo[4.1.0]heptenes as New Synthons for C-Disaccharide and Alkaloid Synthesis. Reactivity Trends with Carbon Nucleophiles
TL;DR: In this paper, homochiral vinyloxiranes and vinylaziridines were reacted with a series of organometallic reagents in order to determine the regio-and stereoselectivity of the ring opening with carbon nucleophiles.
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Improved Synthesis of Buprenorphine from Thebaine and/or Oripavine via Palladium-Catalyzed N-Demethylation/Acylation and/or Concomitant O-Demethylation
TL;DR: An improved preparation of buprenorphine via palladium-catalyzed N-demethylation/acylation is reported and experimental and spectral data are provided for all new compounds.
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Total synthesis of epi-7-deoxypancratistatin via aza-Payne rearrangement and intramolecular cyclization.
TL;DR: In this article, the cis-fused phenanthridone core was synthesized in 12 steps from bromobenzene, using the enzymatic oxidation of bromomethane.