V
Vadim A. Soloshonok
Researcher at University of the Basque Country
Publications - 417
Citations - 16252
Vadim A. Soloshonok is an academic researcher from University of the Basque Country. The author has contributed to research in topics: Enantioselective synthesis & Amino acid. The author has an hindex of 64, co-authored 406 publications receiving 14170 citations. Previous affiliations of Vadim A. Soloshonok include University of Oklahoma & Centre national de la recherche scientifique.
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Operationally Convenient Asymmetric Synthesis of (S)‐ and (R)‐3‐Amino‐4,4,4‐trifluorobutanoic Acid. Part 2. Enantioselective Biomimetic Transamination of 4,4,4‐Trifluoro‐3‐oxo‐N‐[(R)‐1‐phenylethyl]butanamide.
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Catalytic Asymmetric α-Functionalization of α-Branched Aldehydes
TL;DR: In the last 15 years, several catalytic approaches for α-functionalization of prostereogenic α-branched aldehydes that proceed in useful yields and diastereo-and enantioselectivity have been uncovered as mentioned in this paper .
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Design and synthesis of quasi-diastereomeric molecules with unchanging central, regenerating axial and switchable helical chirality via cleavage and formation of Ni(II)-O and Ni(II)-N coordination bonds.
TL;DR: The design and synthesis of asymmetric, pentadentate ligands, which are able to coordinate to Ni(II) cations leading to quasi-diastereomeric complexes displaying two new elements of chirality: stereogenic axis and helix along with configurational stabilization of the stereogenic center on the nitrogen.
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Synthesis of Isothiazoles through N-Propargylsulfinylamide: TFA-Promoted Sulfinyl Group-Involved Intramolecular Cyclization.
TL;DR: In this article, a new reactivity mode of tert-butanesulfinamide has been developed, which proceeds through C-S and O-S bond cleavage of N-propargyl tertbutane sulfinylamide allowing rapid assembly of poly functionalized isothiazoles.
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Asymmetric Mannich reactions of (S)-N-tert-butylsulfinyl-3,3,3-trifluoroacetaldimines with yne nucleophiles.
Ziyi Li,Li Wang,Yunqi Huang,Haibo Mei,Hiroyuki Konno,Hiroki Moriwaki,Vadim A. Soloshonok,Jianlin Han +7 more
TL;DR: In the present work, arylethynes were studied as new C-nucleophiles in the asymmetric Mannich addition reactions with (S)-N-tert-butylsulfinyl-3, 3,3,3-trifluoroacetaldimine to give the target enantiomerically pure trifluoromethylpropargylamines.