V
Vadim A. Soloshonok
Researcher at University of the Basque Country
Publications - 417
Citations - 16252
Vadim A. Soloshonok is an academic researcher from University of the Basque Country. The author has contributed to research in topics: Enantioselective synthesis & Amino acid. The author has an hindex of 64, co-authored 406 publications receiving 14170 citations. Previous affiliations of Vadim A. Soloshonok include University of Oklahoma & Centre national de la recherche scientifique.
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Journal ArticleDOI
Evolution and Future of Hetero‐ and Hydro‐trifluoromethylations of Unsaturated C–C Bonds
Shintaro Kawamura,Pablo Royer del Barrio,Santos Fustero,Jorge Escorihuela,Jianlin Han,Vadim A. Soloshonok,Mikiko Sodeoka +6 more
TL;DR: The difunctionalizative trifluoromethylation of unsaturated C−C bonds has been extensively studied during the last decade as discussed by the authors , and a comprehensive survey enables the categorization of reactions into those that are synthetically mature and those with room for further development.
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Thermal 1,3-Proton Shift Reaction and Its Application for Operationally Convenient and Improved Synthesis of α-(Trifluoromethyl)benzylamine.
TL;DR: In this article, a base-free biomimetic reductive amination of α,α,α-trifluoroacetophenone with benzylamine was described.
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Asymmetric Synthesis of α-Difluorinated β-Amino Sulfones through Detrifluoroacetylative Mannich Reactions
Ziyi Li,Nana Wang,Haibo Mei,Haibo Mei,Hiroyuki Konno,Vadim A. Soloshonok,Vadim A. Soloshonok,Jianlin Han +7 more
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Transition Metal Catalyzed Diastereoselective Aldol Reactions of Prochiral Ketones with Methyl Isocyanoacetate.
TL;DR: In this article, the transition metal-catalyzed aldol reactions of certain prochiral ketones with methyl isocyanoacetate have been made, and high diastereoselectivity (80-98% de) of these condensations, leading to methyl (4R∗,5R ∗)-4,5-dihydro-5,5-(disubstituted)-4-oxazolecaboxylates was shown to be controlled by the nature of both catalyst and substituents on the
Journal ArticleDOI
Asymmetric synthesis of organoelemental analogs of natural compounds. 7. (2R,3S)-2-amino-3-hydroxy-5-phosphonovaleric acid
Vadim A. Soloshonok,N. Yu. Svistunova,V. P. Kukhar,A. O. Gudima,N. A. Kuz'mina,Yu. N. Belokon +5 more
TL;DR: The Ni(II) complex of the Schiff base of glycine with (S)-2-N-(N1-benzylprolyl)-o-aminobenzophenone with diethyl-3-bromo-2-hydroxypropyl phosphonate yields the corresponding complex from which (2R, 3S)2-amino-3 -hydroxy-5-phosphonovaleric acid is separated with HCl as discussed by the authors.