V
Vadim A. Soloshonok
Researcher at University of the Basque Country
Publications - 417
Citations - 16252
Vadim A. Soloshonok is an academic researcher from University of the Basque Country. The author has contributed to research in topics: Enantioselective synthesis & Amino acid. The author has an hindex of 64, co-authored 406 publications receiving 14170 citations. Previous affiliations of Vadim A. Soloshonok include University of Oklahoma & Centre national de la recherche scientifique.
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Design and synthesis of molecules with switchable chirality via formation and cleavage of metal-ligand coordination bonds.
TL;DR: A design and synthesis of organic molecules with switchable central chirality via simple cleavage and formation of metal−ligand coordination bonds is described, as a potentially useful and conceptually new approach to the design of a new generation of organic chiroptical molecular switches.
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Mannich-Type Addition Reactions between Lithium Derivatives of Benzo[d]thiazoles and N-tert-Butylsulfinyl-3,3,3-trifluoroacetaldimine: Convenient Generalized Synthesis of Bis(benzothiazole)s
TL;DR: In this paper, the anomalous outcome of the Mannich-type reaction of N-tert-butylsulfinyl-3,3-3-trifluoroacetaldimine and Li derivatives of benzo[d]thiazoles was described.
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Catalytic asymmetric aldol addition reactions of 3-fluoro-indolinone derived enolates
TL;DR: The reactions were conducted under operationally convenient conditions and displayed wide substrate/functional group generality including unprotected N-H on the tertiary enolates, and aromatic, hetero-aromatic and aliphatic aldehydes.
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Convenient synthesis of fluoroalkyl α- and β-aminophosphonates
Gerd-Volker Röschenthaler,Valery P. Kukhar,Irene B. Kulik,Alexander E. Sorochinsky,Vadim A. Soloshonok,Vadim A. Soloshonok +5 more
TL;DR: In this article, the addition of both alkyl phosphites and phosphonate α-carbanions to N-substituted aldimines derived from fluoroalkyl aldehydes presents a convenient method for synthesis of fluoro-alkyl α- and β-aminophosphonates in good yield (55-86%) under mild conditions.
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Asymmetric synthesis of C–F quaternary α-fluoro-β-amino-indolin-2-ones via Mannich addition reactions; facets of reactivity, structural generality and stereochemical outcome
TL;DR: In this paper, a new approach for the preparation of enantiomerically pure α-fluoro-β-amino-indolin-2-ones possessing tetrasubstituted fluorinated stereogenic centers is presented.