Showing papers by "Zhigang Suo published in 2013"

Stretchable, Transparent, Ionic Conductors

Abstract: Existing stretchable, transparent conductors are mostly electronic conductors. They limit the performance of interconnects, sensors, and actuators as components of stretchable electronics and soft machines. We describe a class of devices enabled by ionic conductors that are highly stretchable, fully transparent to light of all colors, and capable of operation at frequencies beyond 10 kilohertz and voltages above 10 kilovolts. We demonstrate a transparent actuator that can generate large strains and a transparent loudspeaker that produces sound over the entire audible range. The electromechanical transduction is achieved without electrochemical reaction. The ionic conductors have higher resistivity than many electronic conductors; however, when large stretchability and high transmittance are required, the ionic conductors have lower sheet resistance than all existing electronic conductors.

Robotic Tentacles with Three‐Dimensional Mobility Based on Flexible Elastomers

Abstract: Soft robotic tentacles that move in three dimensions upon pressurization are fabricated by composing flexible elastomers with different tensile strengths using soft lithographic molding. These actuators are able to grip complex shapes and manipulate delicate objects. Embedding functional components into these actuators (for example, a needle for delivering fluid, a video camera, and a suction cup) extends their capabilities.

Strengthening Alginate/Polyacrylamide Hydrogels Using Various Multivalent Cations

Abstract: We successfully synthesized a family of alginate/polyacrylamide hydrogels using various multivalent cations. These hydrogels exhibit exceptional mechanical properties. In particular, we discovered that the hydrogels cross-linked by trivalent cations are much stronger than those cross-linked by divalent cations. We demonstrate stretchability and toughness of the hydrogels by inflating a hydrogel sheet into a large balloon, and the elasticity by using a hydrogel block as a vibration isolator in a forced vibration test. The excellent mechanical properties of these hydrogels may open up applications for hydrogels.

Giant voltage-induced deformation in dielectric elastomers near the verge of snap-through instability

Abstract: Dielectric elastomers are capable of large voltage-induced deformation, but achieving such large deformation in practice has been a major challenge due to electromechanical instability and electric breakdown. The complex nonlinear behavior suggests an important opportunity: electromechanical instability can be harnessed to achieve giant voltage-induced deformation. We introduce the following principle of operation: place a dielectric elastomer near the verge of snap-through instability, trigger the instability with voltage, and bend the snap-through path to avert electric breakdown. We demonstrate this principle of operation with a commonly used experimental setup—a dielectric membrane mounted on a chamber of air. The behavior of the membrane can be changed dramatically by varying parameters such as the initial pressure in the chamber, the volume of the chamber, and the prestretch of the membrane. We use a computational model to analyze inhomogeneous deformation and map out bifurcation diagrams to guide the experiment. With suitable values of the parameters, we obtain giant voltage-induced expansion of area by 1692%, far beyond the largest value reported in the literature.

Maximizing the Energy Density of Dielectric Elastomer Generators Using Equi-Biaxial Loading

Abstract: Dielectric elastomer generators (DEGs) for harvesting electrical energy from mechanical work have been demonstrated but the energy densities achieved are still small compared with theoretical predictions. In this study, signifi cant improvements in energy density (560 J/kg with a power density of 280 W/ kg and an effi ciency of 27%) are achieved using equi-biaxial stretching, a mechanical loading confi guration that maximizes the capacitance changes. The capacitance of dielectric elastomers subjected to equi-biaxial stretches is demonstrated to be proportional to the fourth power of the stretch. Quantifi cation of the individual energy contributions indicates that attaining higher conversion effi ciencies is limited by viscous losses within the acrylic elastomer, suggesting that still higher conversion effi ciencies with other elastomers should be attainable with our novel mechanical loading design.

Measurements of the fracture energy of lithiated silicon electrodes of Li-ion batteries.

Abstract: We have measured the fracture energy of lithiated silicon thin-film electrodes as a function of lithium concentration. To this end, we have constructed an electrochemical cell capable of testing multiple thin-film electrodes in parallel. The stress in the electrodes is measured during electrochemical cycling by the substrate curvature technique. The electrodes are disconnected one by one after delithiating to various states of charge, that is, to various concentrations of lithium. The electrodes are then examined by optical microscopy to determine when cracks first form. All of the observed cracks appear brittle in nature. By determining the condition for crack initiation, the fracture energy is calculated using an analysis from fracture mechanics. In the same set of experiments, the fracture energy at a second state of charge (at small concentrations of lithium) is measured by determining the maximum value of the stress during delithiation. The fracture energy was determined to be Γ = 8.5 ± 4.3 J/m2 at s...

Rational Design of Mechano-Responsive Optical Materials by Fine Tuning the Evolution of Strain-Dependent Wrinkling Patterns

Abstract: Rational design strategies for mechano-responsive optical material systems are created by introducing a simple experimental system that can continuously vary the state of bi-axial stress to induce various wrinkling patterns, including stripes, labyrinths, herringbones, and rarely observed checkerboards, that can dynamically tune the optical properties. In particular, a switching of two orthogonally oriented stripe wrinkle patterns from oxidized polydimethylsiloxane around the critical strain value is reported, as well as the coexistence of these wrinkles forming elusive checkerboard patterns, which are predicted only in previous simulations. These strain-induced wrinkle patterns give rise to dynamic changes in optical transmittance and diffraction patterns. A theoretical description of the observed pattern formation is presented which accounts for the residual stress in the membrane and allows for the fi ne-tuning of the window of switching of the orthogonal wrinkles. Applications of wrinkle-induced changes in optical properties are demonstrated, including a mechanically responsive instantaneous privacy screen and a transparent sheet that reversibly reveals a message or graphic and dynamically switches the transmittance when stretched and released.

Elastomeric substrates with embedded stiff platforms for stretchable electronics

Abstract: Stretchable electronics typically integrate hard, functional materials on soft substrates. Here we report on engineered elastomeric substrates designed to host stretchable circuitry. Regions of a stiff material, patterned using photolithography, are embedded within a soft elastomer leaving a smooth surface. We present the associated design rules to produce stretchable circuits based on experimental as well as modeling data. We demonstrate our approach with thin-film electronic materials. The “customized” elastomeric substrates may also be used as a generic elastic substrate for stretchable circuits prepared with alternative technologies, such as transfer-printing of inorganic, thinned devices.

Reactive flow in solids

Abstract: When guest atoms diffuse into a host solid and react, the host may flow inelastically. Often a reaction can stimulate flow in a host too brittle to flow under a mechanical load alone. We formulate a theory of reactive flow in solids by regarding both flow and reaction as nonequilibrium processes, and placing the driving forces for flow and reaction on equal footing. We construct chemomechanical rate-dependent kinetic models without yield strength. In a host under constant stress and chemical potential, flow will persist indefinitely, but reaction will arrest. We also construct chemomechanical yield surface and flow rule by extending the von Mises theory of plasticity. We show that the host under a constant deviatoric stress will flow gradually in response to ramp chemical potential, and will ratchet in response to cyclic chemical potential.

Localization of folds and cracks in thin metal films coated on flexible elastomer foams.

Abstract: Keywords: thin films ; cellular materials ; strain ; flexible electronics Reference EPFL-ARTICLE-188968doi:10.1002/adma.201300587View record in Web of Science Record created on 2013-10-01, modified on 2017-05-10

Nano-optomechanical Actuator and Pull-Back Instability

Abstract: This paper studies the nonlinear behavior of a nano-optomechanical actuator, consisting of a free-standing arc in a ring resonator that is coupled to a bus waveguide through evanescent waves. The arc deflects when a control light of a fixed wavelength and optical power is pumped into the bus waveguide, while the amount of deflection is monitored by measuring the transmission spectrum of a broadband probe light. This nanoactuator achieves a maximal deflection of 43.1 nm, with a resolution of 0.28 nm. The optical force is a nonlinear function of the deflection of the arc, leading to pull-back instability when the control light is red-tuned. This instability is studied by a combination of experiment and modeling. Potential applications of the nanoactuator include bio-nanomotor, optical switches, and optomechanical memories.

Creases and wrinkles on the surface of a swollen gel

Abstract: Consider a layer of a gel attached to a rigid substrate, immersed in a solvent, and swelling in the thickness direction. The flat surface of the gel remains stable if the swelling ratio is small, but becomes unstable if the swelling ratio is large. While creases have been commonly observed, wrinkles have also been observed under certain conditions. We compare the critical conditions for the onset of creases and wrinkles by using a nonlinear field theory of gels. The critical swelling ratio for the onset of creases is calculated by using a finite element method, and that for wrinkles is calculated by using an analytical method. We find that the critical swelling ratio for the onset of creases is significantly lower than that for wrinkles.

Force and stroke of a hydrogel actuator

Abstract: Hydrogels that undergo a volume phase transition in response to an external stimulus are of great interest because of their possible use as actuator materials. The performance of an actuator material is normally characterized by its force–stroke curve, but little is known about the force–stroke behavior of hydrogels. We use the theory of the ideal elastomeric gel to predict the force–stroke curves of a temperature-sensitive hydrogel and introduce an experimental method for measuring the curve. The technique is applied to PNIPAm hydrogels with low cross-link densities. The maximum force generated by the hydrogel increases with increasing cross-link density, while the maximum stroke decreases. The force–stroke curves predicted by the theory of the ideal elastomeric gel are in very good agreement with the experimental curves.

Interpenetrating networks with covalent and ionic crosslinks

Abstract: The invention features a composition comprising a self-healing interpenetrating network hydrogel comprising a first network and a second network. The first network comprises covalent crosslinks and the second network comprises ionic or physical crosslinks. For example, the first network comprises a polyacrylamide polymer and second network comprises an alginate polymer.

Morphological evolution of Si nanowires upon lithiation: a first-principles multiscale model.

Abstract: Silicon is a promising anode material for high-capacity Li-ion batteries. Recent experiments show that lithiation of crystalline silicon nanowires leads to highly anisotropic morphologies. This has been interpreted as due to anisotropy in equilibrium interface energies, but this interpretation does not capture the dynamic, nonequilibrium nature of the lithiation process. Here, we provide a comprehensive explanation of experimentally observed morphological changes, based on first-principles multiscale simulations. We identify reaction paths and associated structural transformations for Li insertion into the Si {110} and {111} surfaces and calculate the relevant energy barriers from density functional theory methods. We then perform kinetic Monte Carlo simulations for nanowires with surfaces of different orientations, which reproduce to a remarkable degree the experimentally observed profiles and the relative reaction front rates.

Computational model of deformable lenses actuated by dielectric elastomers

Abstract: A recent design of deformable lens mimics the human eye, adjusting its focal length in response to muscle-like actuation. The artificial muscle is a membrane of a dielectric elastomer subject to a voltage. Here, we calculate the coupled and inhomogeneous deformation of the lens and the dielectric elastomer actuator by formulating a nonlinear boundary-value problem. We characterize the strain-stiffening elastomer with the Gent model and describe the voltage-induced deformation using the model of ideal dielectric elastomer. The computational predictions agree well with experimental data. We use the model to explore the space of parameters, including the prestretch of the membrane, the volume of the liquid in the lens, and the size of the dielectric elastomer actuator relative to the lens. We examine how various modes of failure limit the minimum radius of curvature.

Kinetics of swelling under constraint

Abstract: Swellable elastomers are used to seal flow channels in oilfield operations. After sealing, the elastomers are constrained triaxially, and a contact load builds up between the elastomers and surrounding rigid materials. For these applications, the ability to predict the evolution of the contact load is important. This work introduces an experimental setup to measure the contact load as a function of time. The experimental data are well represented by a simple time-relaxation equation derived from the linear poroelastic theory, enabling a determination of the effective diffusivity of solvent inside the elastomers.

Dielectric elastomer generator with equi-biaxial mechanical loading for energy harvesting

Abstract: Dielectric elastomer generators (DEGs) are attractive candidates for harvesting electrical energy from mechanical work since they comprise relatively few moving parts and large elastomer sheets can be mass produced. Successfully demonstrations of the DEG prototypes have been reported from a diverse of energy sources, including ocean waves, wind, flowing water and human movement. The energy densities achieved, however, are still small compared with theoretical predictions. We show that significant improvements in energy density (550 J/kg with an efficiency of 22.1%), can be achieved using an equi-biaxial mechanical loading configuration, one that produces uniform deformation and maximizes the capacitance changes. Analysis of the energy dissipations indicates that mechanical losses, which are caused by the viscous losses both within the acrylic elastomer and within the thread materials used for the load transfer assembly, limits the energy conversion efficiency of the DEG. Addressing these losses is suggested to increase the energy conversion efficiency of the DEG.

Islands stretch test for measuring the interfacial fracture energy between a hard film and a soft substrate

Abstract: We present a technique for measuring the interfacial fracture energy, Ci, between a hard thin film and a soft substrate. A periodic array of hard thin islands is fabricated on a soft substrate, which is then subjected to uniaxial tension under an optical microscope. When the applied strain reaches a critical value, delamination between the islands and the substrate starts from the edge of the islands. As the strain is increased, the interfacial cracks grow in a stable fashion. At a given applied strain, the width of the delaminated region is a unique function of the interfacial fracture energy. We have calculated the energy release rate driving the delamination as a function of delamination width, island size, island thickness, and applied strain. For a given materials system, this relationship allows determination of the interfacial fracture energy from a measurement of the delamination width. The technique is demonstrated by measuring the interfacial fracture energy of plasma-enhanced chemical vapor deposition SiNx islands on a polyimide substrate. We anticipate that this technique will find application in the flexible electronics industry where hard islands on soft substrates are a common architecture to protect active devices from fracture. V C 2013 AIP Publishing LLC .[ http://dx.doi.org/10.1063/1.4810763]

Systems and methods for providing flexible robotic actuators

Abstract: Systems and methods for providing flexible robotic actuators are disclosed. Some embodiments of the disclosed subject matter include a soft robot capable of providing a radial deflection motions: a soft tentacle actuator capable of providing a variety of motions and providing transportation means for various types of materials; and a hybrid robotic system that retains desirable characteristics of both soft robots and hard robots. Some embodiments of the disclosed subject matter also include methods for operating the disclosed robotic systems.

Large, Uni-directional Actuation In Dielectric Elastomers Achieved By Fiber Stiffening

Abstract: Cylindrical actuators are made with dielectric elastomer sheets stiffened with fibers in the hoop direction. When a voltage is applied through the thickness of the sheets, large actuation strains are achievable in the axial direction, with or without pre-straining and mechanical loading. For example, actuation strains of 35.8% for a cylinder with a prestrain of 40%, and 28.6% for a cylinder without pre-strain have been achieved without any optimization. Furthermore, the actuation strain is independent of the aspect ratio of the cylinder, so that both large strains and large displacements are readily actuated by using long cylinders.Cylindrical actuators are made with dielectric elastomer sheets stiffened with fibers in the hoop direction. When a voltage is applied through the thickness of the sheets, large actuation strains are achievable in the axial direction, with or without pre-straining and mechanical loading. For example, actuation strains of 35.8% for a cylinder with a prestrain of 40%, and 28.6% for a cylinder without pre-strain have been achieved without any optimization. Furthermore, the actuation strain is independent of the aspect ratio of the cylinder, so that both large strains and large displacements are readily actuated by using long cylinders.

Réseaux imbriqués avec réticulations ioniques et covalentes

Abstract: La presente invention concerne un hydrogel de reseaux imbriques comprenant un premier reseau et un second reseau. Ledit premier reseau comporte des reticulations covalentes et le second reseau comprend des reticulations ioniques ou physiques. Par exemple, le premier reseau comporte un polymere polyacrylamide et le second reseau comporte un polymere d'alginate.