Chiba Institute of Technology

About: Chiba Institute of Technology is a education organization based out in Narashino, Japan. It is known for research contribution in the topics: RNA & Magnet. The organization has 2663 authors who have published 4999 publications receiving 56870 citations. The organization is also known as: Chiba kōgyō daigaku & Kōa Institute of Technology.

Dynamics of hypervelocity jetting during oblique impacts of spherical projectiles investigated via ultrafast imaging

Abstract: A series of hypervelocity impact experiments was conducted in a new laboratory at Planetary Exploration Research Center of Chiba Institute of Technology (Japan). We present the results of high-speed imaging observations of impact jetting during blunt-body penetration under oblique impacts. The observations were sampled at a frame rate of 100 ns frame−1, which is much shorter than the characteristic time of projectile penetration under our experimental conditions. The maximum jet velocity was obtained as a function of both impact velocity and the contrast of shock impedance between a projectile and target, enabling us to test theoretical models of impact jetting during oblique impacts of spherical projectiles. We find that the jet velocities measured in this study are much slower than the prediction by the standard theory based on the previous experimental/theoretical results of collisions between two metal plates. A decaying shock pressure during blunt-body penetration is a possible origin of the discrepancy. We also present a new formulation of the jet velocity with the equations of state for realistic materials. The particle velocities of ejected materials from a free surface are calculated using the Riemann invariant along the isentropes and the Tillotson equations of state in this study. Based on the extremely high velocity of the jet, we point out that impact jetting might contribute to chemistry near the ground surface of planets/satellites with a thick atmosphere, such as Titan.

The Uplink Visible Light Communication Beacon System for Universal Traffic Management

Abstract: This paper presents a feasibility study of the uplink visible light communication (VLC) beacon system for the universal traffic management system (UTMS). The UTMS is a traffic management system beneath the National Police Agency of Japan. Currently, 55 000 UTMS infrared beacon systems have been installed, and they provide expressway and ordinary road information to cars. However, the data rate is 1 Mbps, and a faster data rate is necessary to support automotive and smart mobility devices. In this paper, we propose an uplink V2I system for the UTMS. The system is designed to match the current beacon system as closely as possible, so that the system can easily be replaced and still provide sufficient bandwidth for future automotive and smart mobility devices. We adopt a photo diode (PD) as the VLC receiver and a commercially available off-the-shelf LED headlight as a transmitter. Unfortunately, the bandwidth of such an LED is usually small, so we consider applying a bit-loading algorithm to direct-current-biased optical orthogonal frequency division multiplexing. To reduce strong background noise, such as from the sun, we narrow down the field-of-view by applying a lens to the PD, which forms a tiny communication area, smaller than the current infrared beacon system. We then consider multiple PDs with the lens to create a similar communication area as the infrared beacon system. As a result, we achieve 3.1-Mbps throughput.

PubChemQC PM6: Data Sets of 221 Million Molecules with Optimized Molecular Geometries and Electronic Properties.

Abstract: We report on optimized molecular geometries and electronic properties calculated by the PM6 method for 94.0% of the 91.6 million molecules cataloged in PubChem Compounds retrieved on August 29, 2016. In addition to neutral states, we also calculated those for cationic, anionic, and spin flipped electronic states of 56.2%, 49.7%, and 41.3% of the molecules, respectively. Thus, the grand total of the PM6 calculations amounted to 221 million. We compared the resulting molecular geometries with B3LYP/6-31G* optimized geometries for 2.6 million molecules. The root-mean-square deviations in bond length and bond angle were approximately 0.016 A and 1.7°, respectively. Then, using linear regression to examine the HOMO energy levels E(HOMO) in the B3LYP and PM6 calculations, we found that EB3LYP(HOMO) = 0.876EPM6(HOMO) + 1.975 (eV) and calculated the coefficient of determination to be 0.803. Likewise, we examined the LUMO energy levels and found EB3LYP(LUMO) = 1.069EPM6(LUMO) - 0.420 (eV); the coefficient of determination was 0.842. We also generated four subdata sets, each of which was composed of molecules with molecular weights less than 500. Subdata set i contained C, H, O and N, ii contained C, H, N, O, P, and S, iii contained C, H, N, O, P, S, F, and Cl, and iv contained C, H, N, O, P, S, F, Cl, Na, K, Mg, and Ca. The data sets are available at http://pubchemqc.riken.jp/pm6_datasets.html under a Creative Commons Attribution 4.0 International license.

Mechanisms of Aggregation-Induced Emission and Photo/Thermal E/Z Isomerization of a Cyanostilbene Derivative: Theoretical Insights

Abstract: In this study, aggregation-induced emission (AIE) of a cyanostilbene derivative, called 1-cyano-1,2-bis-(4′-methylbiphenyl)ethylene (CN-MBE), was investigated using molecular simulations. The E-form of CN-MBE has been known to exhibit AIE, which is non-emissive in dilute solutions but becomes highly emissive in aggregated states, whereas its Z-form is non-emissive even in its crystalline form. In addition, upon UV light irradiation, the Z-form exhibits a Z-to-E isomerization, whereas the E-form keeps its conformation at room temperature and undergoes a nonradiative E-to-Z isomerization only at a high temperature. The results from the electronic structure calculations employed in this work showed that the potential energies of CN-MBE for the electronic ground (S0) and first excited (S1) states were degenerate at a twisted conformation around the ethylenic C═C π-bond, which led to fluorescence quenching of the molecule. Molecular dynamics simulations and free-energy analyses revealed that the E-form molecul...