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Showing papers in "Applied Clay Science in 2020"


Journal ArticleDOI
TL;DR: In this article, the main characteristics of clays and clay minerals in nitrate uptake are evaluated and the known shortcomings of their application discussed, leading to suggestions for further research, and a review aims to assemble the available literature research on the application of Clays and Clay minerals as well as the mechanisms that lead to successful removal of nitrate from water.

130 citations


Journal ArticleDOI
TL;DR: In this article, the in-situ growth of zeolite imidazolate frameworks (ZIF-67) on layered double hydroxides (LDH) to form porous composites to develop materials for removal of methylene blue (MB) and methyl orange (MO).

104 citations


Journal ArticleDOI
TL;DR: In this paper, the design and preparation of Mater-Bi/halloysite nanocomposite materials that could be employed as bioplastics alternative to the petroleum derived products were investigated.

103 citations


Journal ArticleDOI
TL;DR: In this paper, a review of the catalytic utility of the halloysite nanocomposites/hybrids is presented, which is based on the types of the components that were hybridized with Halloysite.

85 citations


Journal ArticleDOI
TL;DR: In this article, industrial wastes such as Granulated Blast Furnace Slag (GBFS) and Basic Oxygen Furnace SLag (BOFS) activated with calcium oxide (CaO) and medium reactive magnesia (MgO) are used for chemical stabilization of a soft clay.

81 citations


Journal ArticleDOI
TL;DR: In this article, the authors discuss the thermoplastics-based nanocomposites reinforced with the hybrid of montmorillonite and carbon nanotubes, for high-performance applications.

72 citations


Journal ArticleDOI
TL;DR: In this paper, a novel tailor-made TiO2 nanoparticles-bentonite (TNBT) nanocomposite-enhanced drilling mud was tested, which showed excellent performance; lubricity was enhanced, thin and well-intact mud cakes were created, coating was provided on shale and bentonite plugs, and clay and shale swelling were mitigated.

70 citations


Journal ArticleDOI
TL;DR: In this article, the phase composition, thermal stability and microstructure of metakaolin-based geopolymer blended with rice husk ash with replacement levels of 5-20% by weight of MK was investigated.

66 citations


Journal ArticleDOI
TL;DR: In this article, a review on the use of biopolymer-clays nanocomposites for environmental remediation is presented, where physicochemical and structural properties of clays and biopolymers as well as main characterization and preparation techniques are discussed.

60 citations


Journal ArticleDOI
TL;DR: In this article, the authors investigated the effects of precalcination temperatures ranging from 450°C to 1000°C on the microstructures and mechanical properties of halloysite-based geopolymer.

55 citations


Journal ArticleDOI
TL;DR: In this paper, the geochemistry, pore structure and fractal characteristics of the Upper Cretaceous Nenjiang shale in the Songliao Basin of NE China were investigated, combining geochemistry experiments, physical property analysis, FE-SEM and nano-CT image observation, CO2/N2 gas adsorption, mercury intrusion porosimetry, and methane methane sorption analysis.

Journal ArticleDOI
TL;DR: A versatile catalyst based on halloysite and zinc oxide (HNT@ZnO) was prepared, for the first time, starting from ZnO commercial bulk form as Zn precursor source, in a one-pot procedure.

Journal ArticleDOI
TL;DR: The in-depth analysis presented in this paper shows the unsuitability of the linearized function to evaluate the goodness of the PSO model for adsorption data.

Journal ArticleDOI
TL;DR: The fabricated chitosan/PEO/HAL membranes exhibited appropriate tensile strength properties to support the growth of osteoblast cells and showed a hydrophilic nature appropriate for bone tissue regeneration.

Journal ArticleDOI
TL;DR: In this paper, a comparison between the mechanical and microstructural properties of poly(sialate-siloxo) networks based on metakaolins from halloysite and kaolin was made.

Journal ArticleDOI
TL;DR: In this article, a halloysite-CeOx (x = 1.5-2.0) nanocomposites were prepared using a redox-precipitation method, and the As(III) removal performance of the obtained materials was evaluated.

Journal ArticleDOI
Xiaohui Xu1, Yu Cheng1, Xiao Wu1, Peidong Fan1, Rui Song1 
TL;DR: In this paper, a low-cost adsorbent consisting of lanthanum (La)-doped bentonite and chitosan, with a simple, facile and scalable method combining direct calcination and subsequent blending, was presented.

Journal ArticleDOI
TL;DR: In this article, the B-MgAl-LDH was employed for enhanced aqueous uptake of methylene blue (MB) and showed good adsorptive performances of MB at varied pH values (4-10).

Journal ArticleDOI
TL;DR: In this paper, the effects of pH on the structures, compositions, morphologies, Zeta potential, and gel properties of montmorillonite, palygorskite and their composite clays were investigated in the study.

Journal ArticleDOI
TL;DR: In this paper, the isotherm adsorption curves of CH4 and CO2 on montmorillonite at 288,K, 308,K and 328,K were obtained using gravimetric apparatus.

Journal ArticleDOI
Yinhong Zou1, Runyu Zhang1, Liying Wang1, Ke Xue1, Jingan Chen1 
TL;DR: In this article, the results demonstrated that Zr was successfully introduced to the surface and interlayer of raw CaM in the presence of the [Si O]…[HO Zr ] hydrogen bond and that it increased the specific surface area.

Journal ArticleDOI
TL;DR: The surface properties and surface contacts of kaolinite (Kaol) particles were found to involve in the formation of aggregates in natural sediments, which shows that they are crucial for nucleation, distribution, and crystallinity of CH4 hydrate as mentioned in this paper.

Journal ArticleDOI
TL;DR: In this article, the effect of simultaneous incorporation of two silicate-based nanofillers, including montmorillonite (Mt) and halloysite nanotube (Hal), on mechanical and shape memory performance of thermoplastic polyurethane (TPU) nanocomposites was studied.

Journal ArticleDOI
TL;DR: In this article, batch sorption experiments were conducted to investigate Sb removal from water by a hydroxyl-intercalated, mechanochemically synthesized Mg-Fe-LDH.

Journal ArticleDOI
TL;DR: In this paper, the authors used the term "hydrotalcite" to describe layered double hydroxides (LDH) composed of Mg, Al, and CO3 (Mg-Al LDH).

Journal ArticleDOI
TL;DR: A simple and rapid synthesis of hexagonal boron nitride/halloysite-nanotube (h-BN/HNTs) nanocomposite and its potential application towards highly selective electrochemical determination of furazolidone (FZ) was reported in this paper.

Journal ArticleDOI
TL;DR: In this paper, electrospun fibrous membranes based on polycaprolactone (PCL)/polyethylene oxide (PEO) blended with pure, 3-Aminopropyltriethoxysilane (APTES) or 3-Glycidoxypropyltrimethoxylynne (GPTMS) modified halloysite nanotubes (HNT) were prepared by electrospinning for curcumin (Cur) delivery system.

Journal ArticleDOI
TL;DR: This formulation of hydrophobic halloysite nanotubes coated with octadecyltrimethoxysilane did not have an apoptosis-inducing effect on the cells, did not increase the activity of NO-synthase and can be employed for intracellular delivery of drugs, proteins and DNA without any toxic side effects.

Journal ArticleDOI
TL;DR: In this article, the effect of multivalent-ion specificity on the kaolinite surface was analyzed using the measured zeta potential of a sample treated with di- and trivalent chloride salts (up to 100mM).

Journal ArticleDOI
TL;DR: In this paper, four samples of meta-halloysite from widely available Cameroon halloysite clay calcined at 600, 650, 700 and 750°C, respectively, and the resultant geopolymer binders were systematically characterized.