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Showing papers in "Carbon in 2004"


Journal ArticleDOI
01 Jan 2004-Carbon
TL;DR: In this paper, the current knowledge about the fundamental factors that control the adsorption process from aqueous phase is presented, and the carbon surface chemistry has a great influence on both electrostatic and non-electrostatic interactions.

1,259 citations


Journal ArticleDOI
Masukazu Hirata1, Takuya Gotou1, Shigeo Horiuchi1, Masahiro Fujiwara1, Michio Ohba1 
01 Jan 2004-Carbon
TL;DR: In this paper, a modified Hummers' method was used to synthesize thin-film graphite oxide particles with high yield by combining a very long oxidation period with a high purity purification process.

830 citations


Journal ArticleDOI
01 Jan 2004-Carbon
TL;DR: In this paper, the C 1s XPS spectrum was fitted to graphitization of anthracene semi-cokes and during milling of graphite powders under different atmospheres.

662 citations


Journal ArticleDOI
01 Jan 2004-Carbon
TL;DR: Park et al. as discussed by the authors synthesize X-rayamorphous silver nanoparticles by the pulse sonoelectrochemical method. Carbon 2003;41(5):1079-85; Park SJ, Jang YS.

515 citations


Journal ArticleDOI
01 Jan 2004-Carbon
TL;DR: In this paper, a volume production of a single carbon nanofiber type which can be used in a wide range of systems beyond, but not restricted to polymer composites is discussed.

490 citations


Journal ArticleDOI
01 Jan 2004-Carbon
TL;DR: In this article, the fabrication aspects of carbon membranes, which can be divided into six steps: precursor selection, polymeric membrane preparation, pretreatment of the precursor, pyrolysis process, post-treatment of pyroglyzed membranes and module construction.

488 citations


Journal ArticleDOI
01 Jan 2004-Carbon
TL;DR: In this paper, the authors discuss the virtues and drawbacks of different hypotheses about basic carbon sites in view of experimental and theoretical results and discuss the importance of basic sites on carbon surfaces.

466 citations


Journal ArticleDOI
01 Jan 2004-Carbon
TL;DR: In this article, the isotherms of N2, Ar, CO2, and H2 were measured on selected activated carbons representing various pore size distributions using the DFT method.

430 citations


Journal ArticleDOI
01 Jan 2004-Carbon
TL;DR: In this paper, natural flake graphite was exfoliated into ex-foliated graphite via an acid intercalation procedure, and the resulting ex-graphite was a worm-like particle composed of graphite sheets with thickness in the nanometer scale.

430 citations


Journal ArticleDOI
01 Jan 2004-Carbon
TL;DR: In 2003, the 117 Committee of the Japan Society for the Promotion of Sciences (JSPS) specified standard procedures for the determination of lattice constants and crystallite sizes of carbon materials, especially graphitized materials, the so-called Gakushin method.

413 citations


Journal ArticleDOI
01 Jan 2004-Carbon
TL;DR: An ultrathin sheet-like carbon nanostructure, carbon nanosheet, has been effectively synthesized with CH4 diluted in H2 by an inductively coupled radio-frequency plasma enhanced chemical vapor deposition.

Journal ArticleDOI
01 Jan 2004-Carbon
TL;DR: In this article, a mathematical model was developed to predict the VOC breakthrough characteristics on the activated carbon fiber (ACF) under dynamic conditions, including the effects of the gas-particle film mass transfer resistance, adsorbent pore diffusion and the adsorption/desorption rates within the pore.

Journal ArticleDOI
01 Jan 2004-Carbon
TL;DR: In this paper, the process of chemical activation by hydroxides has been extended to different coal precursors to confirm that such a chemical activation process starts through a solid-solid reaction and continues as a solid liquid reaction.

Journal ArticleDOI
01 Jan 2004-Carbon
TL;DR: This paper showed that very porous carbon materials can be synthesized by evaporative drying and pyrolysis of aqueous resorcinol-formaldehyde gels provided that the operating variables are correctly chosen.

Journal ArticleDOI
01 Jan 2004-Carbon
TL;DR: In this paper, the main objective is to coat carbon multiwall nanotubes surface with TiO2 as anatase in view of photocatalytic application for these nanocomposites.

Journal ArticleDOI
01 Jan 2004-Carbon
TL;DR: In this article, the authors compared N2 and CO2 adsorption at subatmospheric and high pressures at 77 and 273 K, respectively, and showed that both adsorptives give the same micropore size distribution (MPSD) for open porosity activated carbons.

Journal ArticleDOI
01 Jan 2004-Carbon
TL;DR: In this article, it was shown that trans-polyacetylene originates from the diamond film and the diamond mode around 1332 cm−1 does not, while the deuterium and H-D substituted hydrocarbon sources do.

Journal ArticleDOI
01 Jan 2004-Carbon

Journal ArticleDOI
01 Jan 2004-Carbon
TL;DR: In this article, the authors compared the porosity of carbon fibres with KOH and NaOH and found that NaOH developed the highest value of porosity and KOH developed samples with narrower micropore size distribution.

Journal ArticleDOI
Maria C. Paiva1, B. Zhou1, K. A. S. Fernando1, Yi Lin1, J. M. Kennedy1, Ya-Ping Sun1 
01 Jan 2004-Carbon
TL;DR: In this paper, carbon nanotubes were functionalized with polyvinyl alcohol (PVA) and then embedded into PVA matrix via a wet-casting method, resulting in polymer-carbon nanocomposite films with homogeneous nanotube dispersion.

Journal ArticleDOI
01 Jan 2004-Carbon
TL;DR: In this paper, the surface atomic oxygen percent increased from 6.3 to 18.5% for 10−90 min oxidations followed by a drop to 14−15% after 10−24 h oxidations.

Journal ArticleDOI
01 Jan 2004-Carbon
TL;DR: In this article, composites of polycarbonate (PC) having different amounts of multiwalled carbon nanotubes (MWNT) were prepared by diluting a masterbatch of PC with 15 wt% MWNT using melt mixing in a DACA-Micro Compounder.

Journal ArticleDOI
01 Jan 2004-Carbon
TL;DR: In this article, the effect of liquid-phase oxidation on the texture and surface properties of carbon nanofibers has been studied using XRD, TEM, SEM, N2-physisorption, TGA-MS, XPS and acid-base titrations.

Journal ArticleDOI
01 Jan 2004-Carbon
TL;DR: A review of the production of activated carbons from waste tyres is presented in this paper, where the effects of various process parameters, particularly, temperature and heating rate, on the pyrolysis stage are reviewed.

Journal ArticleDOI
01 Jan 2004-Carbon
TL;DR: In this paper, the Pt/CNT electrode for oxygen reduction reaction has been investigated by linear sweep voltammetry and the results imply that the Pt has good potential applications in proton exchange membrane fuel cells.

Journal ArticleDOI
01 Jan 2004-Carbon
TL;DR: In this paper, the authors report on the protocol which standardizes measurements in TEM, SEM, TGA, Raman and UV-VIS spectrometer, which is used to compare these measurements across the board.

Journal ArticleDOI
01 Jan 2004-Carbon
TL;DR: In this paper, bituminous coal-based activated carbon was modified by impregnation with melamine and heat treatment at 850 °C and the results revealed that carbons modified with nitrogen-containing species and heat-treated at 850°C have a hydrogen sulfide removal capacity exceeding more then 10 times the capacity of unmodified sample.


Journal ArticleDOI
01 Jan 2004-Carbon
TL;DR: In this paper, three thermal regeneration methods have been tested: (1) pyrolysis, (2) pyroxis-gasification and (3) direct gasification, the gasifying agents being air and CO2, the results show that the pyroxys treatment does not completely eliminate the contaminant from the carbon and the recovery of the initial adsorption properties is rather limited.

Journal ArticleDOI
01 Jan 2004-Carbon
TL;DR: In this article, the impact of carbon treatment on the DOM adsorption was examined by conducting isotherm experiments at a neutral pH using the modified carbons and a DOM isolated from the influent to Myrtle Beach drinking water treatment plant in South Carolina (USA).