Showing papers in "Transport in Porous Media in 2006"

A Criterion for Non-Darcy Flow in Porous Media

Abstract: Non-Darcy behavior is important for describing fluid flow in porous media in situations where high velocity occurs. A criterion to identify the beginning of non-Darcy flow is needed. Two types of criteria, the Reynolds number and the Forchheimer number, have been used in the past for identifying the beginning of non-Darcy flow. Because each of these criteria has different versions of definitions, consistent results cannot be achieved. Based on a review of previous work, the Forchheimer number is revised and recommended here as a criterion for identifying non-Darcy flow in porous media. Physically, this revised Forchheimer number has the advantage of clear meaning and wide applicability. It equals the ratio of pressure drop caused by liquid–solid interactions to that by viscous resistance. It is directly related to the non-Darcy effect. Forchheimer numbers are experimentally determined for nitrogen flow in Dakota sandstone, Indiana limestone and Berea sandstone at flowrates varying four orders of magnitude. These results indicate that superficial velocity in the rocks increases non-linearly with the Forchheimer number. The critical Forchheimer number for non-Darcy flow is expressed in terms of the critical non-Darcy effect. Considering a 10% non-Darcy effect, the critical Forchheimer number would be 0.11.

3D stochastic modelling of heterogeneous porous media - applications to reservoir rocks

Abstract: The creation of a 3D pore-scale model of a porous medium is often an essential step in quantitatively characterising the medium and predicting its transport properties. Here we describe a new stochastic pore space reconstruction approach that uses thin section images as its main input. The approach involves using a third-order Markov mesh where we introduce a new algorithm that creates the reconstruction in a single scan, thus overcoming the computational issues normally associated with Markov chain methods. The technique is capable of generating realistic pore architecture models (PAMs), and examples are presented for a range of fairly homogenous rock samples as well as for one heterogeneous soil sample. We then apply a Lattice–Boltzmann (LB) scheme to calculate the permeabilities of the PAMs, which in all cases closely match the measured values of the original samples. We also develop a set of software methods – referred to as pore analysis tools (PATs) – to quantitatively analyse the reconstructed pore systems. These tools reveal the pore connectivity and pore size distribution, from which we can simulate the mercury injection process, which in turn reproduces the measured curves very closely. Analysis of the topological descriptors reveals that a connectivity function based on the specific Euler number may serve as a simple predictor of the threshold pressure for geo-materials.

Adaptive Local–Global Upscaling for General Flow Scenarios in Heterogeneous Formations

Abstract: A new technique for upscaling highly variable permeability descriptions is developed and demonstrated. The method provides coarse scale numerical properties (transmissibilities) that are specifically adapted to a particular flow scenario. Global coarse scale simulations are used for the determination of the local boundary conditions required for the upscaling calculations. Near-well effects are incorporated directly into the coarse scale description. The technique avoids the need for any global fine scale simulations and introduces only a modest overhead compared to existing methods that do not account for global effects. A thresholding procedure, which provides computational efficiency and acts to minimize the number of anomalous coarse scale transmissibilities, is introduced. The method is demonstrated on highly heterogeneous channelized systems in two dimensions. Results are presented for flows driven by boundary conditions and wells and for cases with changing well rates. The method is well-suited to highly heterogeneous systems, where existing methods often do not suffice. Significant improvement in the accuracy of the coarse simulations is achieved for both single and two-phase flow scenarios.

Stability of a fluid in a horizontal saturated porous layer: effect of non-linear concentration profile, initial, and boundary conditions

Abstract: Carbon dioxide injected into saline aquifers dissolves in the resident brines increasing their density, which might lead to convective mixing. Understanding the factors that drive convection in aquifers is important for assessing geological CO2 storage sites. A hydrodynamic stability analysis is performed for non-linear, transient concentration fields in a saturated, homogenous, porous medium under various boundary conditions. The onset of convection is predicted using linear stability analysis based on the amplification of the initial perturbations. The difficulty with such stability analysis is the choice of the initial conditions used to define the imposed perturbations. We use different noises to find the fastest growing noise as initial conditions for the stability analysis. The stability equations are solved using a Galerkin technique. The resulting coupled ordinary differential equations are integrated numerically using a fourth-order Runge–Kutta method. The upper and lower bounds of convection instabilities are obtained. We find that at high Rayleigh numbers, based on the fastest growing noise for all boundary conditions, both the instability time and the initial wavelength of the convective instabilities are independent of the porous layer thickness. The current analysis provides approximations that help in screening suitable candidates for homogenous geological CO2 sequestration sites.

Numerical Analysis of Coupled Stokes/Darcy Flows in Industrial Filtrations

Abstract: Free flow channel confined by porous walls is a feature of many of the natural and industrial settings. Viscous flows adjacent to saturated porous medium occur in cross-flow and dead-end filtrations employed primarily in pharmaceutical and chemical industries for solid–liquid or gas–solid separations. Various mathematical models have been put forward to describe the conjugate flow dynamics based on theoretical grounds and experimental evidence. Despite this fact, there still exists a wide scope for extensive research in numerical solutions of these coupled models when applied to problems with industrial relevance. The present work aims towards the numerical analysis of coupled free/porous flow dynamics in the context of industrial filtration systems. The free flow dynamics has been expressed by the Stokes equations for the creeping, laminar flow regime whereas the flow behaviour in very low permeability porous media has been represented by the conventional Darcy equation. The combined free/porous fluid dynamical behaviour has been simulated using a mixed finite element formulation based on the standard Galerkin technique. A nodal replacement technique has been developed for the direct linking of Stokes and Darcy flow regimes which alleviates specification of any additional constraint at the free/porous interface. The simulated flow and pressure fields have been found for flow domains with different geometries which represent prototypes of actual industrial filtration equipment. Results have been obtained for varying values of permeability of the porous medium for generalised Newtonian fluids obeying the power law model. A series of numerical experiments has been performed in order to validate the coupled flow model. The developed model has been examined for its flexibility in dealing with complex geometrical domains and found to be generic in delivering convergent, stable and theoretically consistent results. The validity and accuracy of the simulated results has been affirmed by comparing with available experimental data.

A Two-Scale Model for Coupled Electro-Chemo-Mechanical Phenomena and Onsager’s Reciprocity Relations in Expansive Clays: I Homogenization Analysis

Abstract: The macroscopic model governing coupled electro-chemo-mechanical phenomena in expansive clays is revisited within a rigorous homogenization procedure applied to the microscopic governing equations which describe the local interaction between charged clay particles and a binary monovalent aqueous electrolyte solution. The up-scaling of the microscopic electro-hydro-dynamics leads to a two-scale approach wherein the macroscopic model appears governed by a fully coupled form of Onsager’s reciprocity relations, mass conservation equations and a modified Terzaghi’s effective stress principle. In addition, the two-scale approach provides microscopic representations for the effective coefficients which are exploited herein to obtain further insight in the constitutive behavior of the electrochemical parameters and the swelling pressure. Among other effects, we show that these microscopic closure relations are mainly dictated by the spatial variability of a microscale electric potential which satisfies a local version of the Poisson–Boltzmann problem in a periodic unit cell, The proposed framework allows to address various relevant still open issues regarding the constitutive behavior of swelling systems, Among them we give particular emphasis on the analysis of the influence of the fluctuation and distortion of the electrical double layer upon the magnitude of the electrochemical coefficients and the precise local conditions for the validity of the symmetry of Onsager’s relations.

Trapped Gas Fraction During Steady-State Foam Flow

Abstract: Trapped or stationary gas contributes significantly to the extent of gas mobility reduction for aqueous foams. Simultaneous measurements of effluent bubble sizes and trapped gas saturation in sandstone are reported for the first time. Roughly 80% of the gas saturation in an aqueous foam is stationary at steady state in this permeable porous medium. The experiments show that as gas velocity increases, the trapped gas fraction decreases. Similarly, as injected gas–liquid ratio increases, the trapped gas fraction decreases. Hence, the absolute velocities of gas and aqueous surfactant solution are fundamental to foamed-gas mobility reduction for they help determine in situ foam texture. Effluent foam bubbles range in size from 60 to 120 μm in diameter. The smaller the effluent bubble, the smaller is the fraction of mobile gas. Scaling laws from network percolation theory are used to engender a mechanistic understanding of the various parameters identified as important in the experimental program. The closed form approimation predicts that the trapped gas fraction is a weak function of pressure gradient, foam-bubble size, and the permeability of the porous medium. Moreover, the theory reproduces well the newly obtained experimental data.

A New Stochastic Bubble Population Model for Foam Flow in Porous Media

Abstract: Foam has been widely used as a mobility control agent for Improved and Enhanced Oil Recovery IOR/EOR, gas blocking, and acid diversion during matrix stimulation. The prediction of foam performance relies on macroscopic modeling. Traditionally, foam modeling approaches include fractional flow theories and population balance models. However, fractional foam models assume implicitly that foam is incompressible and do not account directly for the evolution of bubble population. The population balance models, instead, rely on the idea that foam mobility depends on bubble density and are more comprehensive. Yet, population balance models did not gain full acceptance thus far, because of their perceived complexity, with parameters that are hard to obtain experimentally. This article presents an improved foam model based on a simpler but realistic foam rheology and stochastic bubble generation ideas. Physical ideas in agreement with pictures emerging from recent foam studies using X-ray computed tomography form the basis for the new model.

Multiphase Thermohaline Convection in the Earth's Crust: I. A New Finite Element - Finite Volume Solution Technique Combined With a New Equation of State for NaCl-H2O

Abstract: We present a new finite element – finite volume (FEFV) method combined with a realistic equation of state for NaCl–H2O to model fluid convection driven by temperature and salinity gradients. This method can deal with the nonlinear variations in fluid properties, separation of a saline fluid into a high-density, high-salinity brine phase and low-density, low-salinity vapor phase well above the critical point of pure H2O, and geometrically complex geological structures. Similar to the well-known implicit pressure explicit saturation formulation, this approach decouples the governing equations. We formulate a fluid pressure equation that is solved using an implicit finite element method. We derive the fluid velocities from the updated pressure field and employ them in a higher-order, mass conserving finite volume formulation to solve hyperbolic parts of the conservation laws. The parabolic parts are solved by finite element methods. This FEFV method provides for geometric flexibility and numerical efficiency. The equation of state for NaCl–H2O is valid from 0 to 750°C, 0 to 4000 bar, and 0–100 wt.% NaCl. This allows the simulation of thermohaline convection in high-temperature and high-pressure environments, such as continental or oceanic hydrothermal systems where phase separation is common.

Suction Induced Effects on the Fabric of a Structured Soil

Abstract: This paper presents the mathematical modelling of the modification of the pore space geometry of a structured soil subjected to suction increase. Structured soil concepts are first introduced considering different fabric units, such as aggregates and fissures. The numerical modelling of the structural evolution is based on experimental test results in which the evolution of the structure of the samples subjected to different suctions is determined using the mercury intrusion porosimetry technique. From this information, the macro and micropore volume evolutions are determined. The results show that drying produces a reduction in the soil total porosity which mainly corresponds to a reduction of the macropore volume. Associated with this phenomenon, an increase in micropore volume is also observed. The proposed model divides pore size distribution into three pore classes (micropores, macropores and non-affected areas). Using the concept of a suction-influenced domain, the proposed model is able to reproduce the main observed fabric evolution between the saturated and dry states.

Estimation of dynamic relative permeability and capillary pressure from countercurrent imbibition experiments

Abstract: Direct laboratory measurements of in situ water-phase saturation history are used to estimate relative permeability and capillary pressure functions. The magnitude of so-called nonequilibrium effects during spontaneous imbibition is quantified and, if significant, these effects are incorporated within the estimation technique. The primary constraint employed is that curves must increase or decrease monotonically; otherwise, no predetermined functionality is assumed. The technique is demonstrated using water saturation profile histories obtained for diatomite (a low-permeability and high-porosity rock). Results indicate that nonequilibrium effects detected at laboratory scale in low-permeability rocks influence the estimation of unsteady-state relative permeability and capillary pressure.

Enhancing the Bolzon-Schrefler-Zienkiewicz constitutive model for partially saturated soil

Abstract: This paper presents an enhanced version of the elasto-plastic model for partially saturated soil first proposed by Bolzon, Schrefler and Zienkiewicz in 1996, “BSZ” model, which uses the effective stress tensor and suction as independent stress variables. It is recalled that the effective stress tensor proposed by Lewis and Schrefler in 1982 is thermodynamically consistent and, compared with other choices of stress tensors, results particularly suitable for partially saturated soil mechanics. A hydraulic constitutive relationship and a hydraulic hysteresis are introduced in the model, to take into account the irreversible deformation during cyclic drying and wetting until structural collapse. For this reason the plastic rate of strain is split into the sum of two components: one depending on the effective stress tensor and the other one on suction. This is the new feature of the BSZ model. This enhanced model is then cast into a thermodynamical framework at macroscopic level and it is shown that it is possible to derive the constitutive law from the Helmholtz free energy and a dissipation function, both for associative and non- associative plasticity. Finally the model predictions have been compared with experimental data for Sion slime, with particular emphasis on the deviatoric part, and model predictions of hysteretic behaviour have been investigated in case of a wetting and drying cycle on compacted betonite–kaolin.

A Stochastic Model for Particulate Suspension Flow in Porous Media

Abstract: A population balance model for a particulate suspension transport with size exclusion capture of particles by porous rock is derived. The model accounts for particle flux reduction and pore space accessibility due to restriction for large particles to move through smaller pores – a particle is captured by a smaller pore and passes through a larger pore. Analytical solutions are obtained for a uniform pore size medium, and also for a medium with small pore size variation. For both cases, the equations for averaged concentrations significantly differ from the classical deep bed filtration model.

Lattice Boltzmann Simulation of Fluid Flow in Synthetic Fractures

Abstract: Fractures play an important role in reservoir engineering as they dominate the fluid flow in the reservoir. All evidence suggests that rarely can one model flow and transport in a fractured rock consistently by treating it as a uniform or mildly nonuniform isotropic continuum. Instead, one must generally account for the highly erratic heterogeneity, directional dependence, dual or multicomponent nature and multiscale behavior of fractured rocks. As experimental methods are expensive and time consuming most of the time numerical methods are used to study flow and transport in a fractured rock. In this work, we present results of the numerical computations for single phase flow simulations through two-dimensional synthetically created fracture apertures. These synthetic rock fractures are created using different fractal dimensions, anisotropy factors, and mismatch lengths. Lattice Boltzmann method (LBM), which is a new computational approach suitable to simulate fluid flow especially in complex geometries, was then used to determine the permeability for different fractures. Regions of high velocity and low velocity flow were identified. The resulting permeability values were less than the ones obtained with the cubic law estimates. It has been found that as the mean aperture–fractal dimension ratio increased permeability increased. Moreover as the anisotropy factor increased permeability decreased. Neural network simulations were used to generalize the results.

Finite Element Modelling of Flow Through a Porous Medium Between Two Parallel Plates Using The Brinkman Equation

Abstract: Despite the widespread use of the Darcy equation to model porous flow, it is well known that this equation is inconsistent with commonly prescribed no slip conditions at flow domain walls or interfaces between different sections. Therefore, in cases where the wall effects on the flow regime are expected to be significant, the Darcy equation which is only consistent with perfect slip at solid boundaries, cannot predict velocity and pressure profiles properly and alternative models such as the Brinkman equation need to be considered. This paper is devoted to the study of the flow of a Newtonian fluid in a porous medium between two impermeable parallel walls at different Darcy parameters (Da). The flow regime is considered to be isothermal and steady. Three different flow regimes can be considered using the Brinkman equation: free flow (Da > 1), porous flow (high permeability, 1 > Da > 10−6) and porous flow (low permeability Da < 10−6). In the present work the described bench mark problem is used to study the effects of solid walls for a range of low to high Darcy parameters. Both no-slip and slip conditions are considered and the results of these two cases are compared. The range of the applicability of the Brinkman equation and simulated results for different cases are shown.

A Two-Scale Model for Coupled Electro-Chemo-Mechanical Phenomena and Onsager's Reciprocity Relations in Expansive Clays: II Computational Validation

Abstract: In Part I Moyne and Murad [Transport in Porous Media 62, (2006), 333–380] a two-scale model of coupled electro-chemo-mechanical phenomena in swelling porous media was derived by a formal asymptotic homogenization analysis. The microscopic portrait of the model consists of a two-phase system composed of an electrolyte solution and colloidal clay particles. The movement of the liquid at the microscale is ruled by the modified Stokes problem; the advection, diffusion and electro-migration of monovalent ions Na+ and Cl− are governed by the Nernst–Planck equations and the local electric potential distribution is dictated by the Poisson problem. The microscopic governing equations in the fluid domain are coupled with the elasticity problem for the clay particles through boundary conditions on the solid–fluid interface. The up-scaling procedure led to a macroscopic model based on Onsager’s reciprocity relations coupled with a modified form of Terzaghi’s effective stress principle including an additional swelling stress component. A notable consequence of the two-scale framework are the new closure problems derived for the macroscopic electro-chemo-mechanical parameters. Such local representation bridge the gap between the macroscopic Thermodynamics of Irreversible Processes and microscopic Electro-Hydrodynamics by establishing a direct correlation between the magnitude of the effective properties and the electrical double layer potential, whose local distribution is governed by a microscale Poisson–Boltzmann equation. The purpose of this paper is to validate computationally the two-scale model and to introduce new concepts inherent to the problem considering a particular form of microstructure wherein the clay fabric is composed of parallel particles of face-to-face contact. By discretizing the local Poisson–Boltzmann equation and solving numerically the closure problems, the constitutive behavior of the diffusion coefficients of cations and anions, chemico-osmotic and electro-osmotic conductivities in Darcy’s law, Onsager’s parameters, swelling pressure, electro-chemical compressibility, surface tension, primary/secondary electroviscous effects and the reflection coefficient are computed for a range particle distances and sat concentrations.

Nonequilibrium Effects During Spontaneous Imbibition

Abstract: Accurate models of multiphase flow in porous media and predictions of oil recovery require a thorough understanding of the physics of fluid flow. Current simulators assume, generally, that local capillary equilibrium is reached instantaneously during any flow mode. Consequently, capillary pressure and relative permeability curves are functions solely of water saturation. In the case of imbibition, the assumption of instantaneous local capillary equilibrium allows the balance equations to be cast in the form of a self-similar, diffusion-like problem. Li et al. [J. Petrol. Sci. Eng. 39(3) (2003), 309–326] analyzed oil production data from spontaneous countercurrent imbibition experiments and inferred that they observed the self-similar behavior expected from the mathematical equations. Others (Barenblatt et al. [Soc. Petrol. Eng. J. 8(4) (2002), 409–416]; Silin and Patzek [Transport in Porous Media 54 (2004), 297–322]) assert that local equilibirum is not reached in porous media during spontaneous imbibition and nonequilibirium effects should be taken into account. Simulations and definitive experiments are conducted at core scale in this work to reveal unequivocally nonequilbirium effects. Experimental in-situ saturation data obtained with a computerized tomography scanner illustrate significant deviation from the numerical local-equilibrium based results. The data indicates: (i) capillary imbibition is an inherently nonequilibrium process and (ii) the traditional, multi-phase, reservoir simulation equations may not well represent the true physics of the process.

Effects of Fracture Boundary Conditions on Matrix-fracture Transfer Shape Factor

Abstract: The matrix-fracture transfer shape factor is one of the important parameters in modeling naturally fractured reservoirs. Four decades after Warren and Root (1963, SPEJ, 245–255.) introduced the double porosity concept and suggested a relation for it, this parameter is still not completely understood. Even for a single-phase flow problem, investigators report different shape factors. This study shows that for a single-phase flow in a particular matrix block, the shape factor that Warren and Root defined is not unique and depends on the pressure in the fracture and how it changes with time. We use the Laplace domain analytical solutions of the diffusivity equation for different geometries and different boundary conditions to show that the shape factor depends on the fracture pressure change with time. In particular, by imposing a constant fracture pressure as it is typically done, one obtains the shape factor that Lim and Aziz (1995, J. Petrolean Sci. Eng. 13, 169.) calculated. However, other shape factors, similar to those reported in other studies are obtained, when other boundary conditions are chosen. Although, the time variability of the boundary conditions can be accounted for by the Duhamel’s theorem, in practice using large time-steps in numerical simulations can potentially introduce large errors in simulation results. However, numerical simulation models make use of a stepwise approximation of this theorem. It is shown in this paper that this approximation could lead to large errors in matrix-fracture transfer rate if large time-steps are chosen.

Convective Instability of Oldroyd-B Fluid Saturated Porous Layer Heated from Below using a Thermal Non-equilibrium Model

Abstract: The linear stability of a viscoelastic fluid saturated densely packed horizontal porous layer heated from below and cooled from above is investigated by considering the Oldroyd-B type fluid. A generalized Darcy model, which takes into account the viscoelastic properties, is employed as momentum equation and a two-field model is used for energy equation each representing solid and fluid phases separately. Linear stability analysis suggests that, there is a competition between the processes of viscous relaxation and thermal diffusion that causes the first convective instability to be oscillatory rather than stationary. Analytical expression for the occurrence of oscillatory onset is obtained, and it is found that the necessary condition for the existence of the same is Λ < 1. Besides, the effect of viscoelastic parameters and the thermal non-equilibrium on the stability of the system is analyzed.

Influence of Relative Permeability on the Stability Characteristics of Immiscible Flow in Porous Media

Abstract: Relative permeability functions for immiscible displacements in porous media show a wide range of profiles. Although, this behavior is well known, its impact on the stability of the displacement process is unexplored. Our analysis clearly demonstrates for the first time that the viscous instability characteristics of two-phase flows are governed not only by their end point values, but are strongly dependent on the actual profile of relative permeability functions. Linear stability analysis predicts the capacity of the flow to develop large scale fingers which can result in substantial bypassing of the resident fluid. It is observed that relative permeability functions attributed to drainage processes yield a more unstable displacement as compared to functions related to imbibition processes. Moreover, instability is observed to increase for those relative permeability functions which result from increased wettability of the wetting fluid. High accuracy numerical simulations show agreement with these predictions and demonstrate how large amplitude viscous fingers result in significant bypassing for certain relative permeability functions. In the nonlinear regime, the finger amplitude grows at a rate ∝ t1/2 initially, drops to t1/4 at a later time and finally grows ∝ t. The basic mechanisms of finger interaction, however, are not substantially influenced by relative permeability functions.

Multiphase Thermohaline Convection in the Earth's Crust: II. Benchmarking and Application of a Finite Element - Finite Volume Solution Technique with a NaCl-H2O Equation of State

Abstract: We present the benchmarking of a new finite element – finite volume (FEFV) solution technique capable of modeling transient multiphase thermohaline convection for geological realistic p-T-X conditions. The algorithm embeds a new and accurate equation of state for the NaCl–H2O system. Benchmarks are carried out to compare the numerical results for the various component-processes of multiphase thermohaline convection. They include simulations of (i) convection driven by temperature and/or concentration gradients in a single-phase fluid (i.e., the Elder problem, thermal convection at different Rayleigh numbers, and a free thermohaline convection example), (ii) multiphase flow (i.e., the Buckley–Leverett problem), and (iii) energy transport in a pure H2O fluid at liquid, vapor, supercritical, and two-phase conditions (i.e., comparison to the U.S. Geological Survey Code HYDROTHERM). The results produced with the new FEFV technique are in good agreement with the reference solutions. We further present the application of the FEFV technique to the simulation of thermohaline convection of a 400°C hot and 10 wt.% saline fluid rising from 4 km depth. During the buoyant rise, the fluid boils and separates into a high-density, high-salinity liquid phase and a low-density, low-salinity vapor phase.

Homogenization of the Ionic Transport Equations in Periodic Porous Media

Abstract: The transport of an N-component electrolyte in a dilute Newtonian solvent through a rigid, porous body subjected to a static (d.c.) electric field is studied. The microscopic description is given by the linearized ionic transport (electrokinetic) equations, including the effects of ion diffusion, electromigration and convection. Periodic homogenization is used to derive effective governing equations for the fluid velocity, ionic flux and current density that capture the macroscopic behavior. Explicit expressions for the transport coefficient tensors are given in terms of solutions to cell problems. Without any additional assumptions, we rigorously prove that these transport coefficient tensors obey certain fundamental thermodynamic requirements, namely, Onsager’s reciprocal relations and the positive definiteness of the diagonal coefficient tensors.

Coupling of foam drainage and viscous fingering in porous media revealed by X-ray computed tomography

Abstract: We investigate the development foam in granular porous media and the subsequent flow of the surfactant solution, where the fluid fraction variations are visualized and quantified using X-ray computed tomography. It is found that foam flows in a front like manner leading to a residual liquid fraction of 0.18±0.01, far from the inlet surface of the porous sample. A desaturation backward wave is also observed during foam development. We provided direct evidence that the flow of surfactant solution in porous media containing foam gives rise to superposition of a drainage wave and a characteristic viscous fingering pattern. In the wave the liquid fraction ranges from the above residual value to nearly 0.25±0.01. The liquid fraction associated with the viscous fingering decays as a function of distance but the inlet value increases up to 0.06±0.01. Certain ideas about the physics of foam flow in porous media are revised in the light of our findings.

Forced Convection with Slip-flow in a Channel or Duct Occupied by a Hyper-porous Medium Saturated by a Rarefied Gas

Abstract: An analytic solution is obtained for forced convection flow in a parallel-plates channel or a circular duct occupied by a hyper-porous medium saturated with a rarefied gas in the slip-flow regime, for the case of uniform flux boundary conditions. As expected, it is found that velocity slip leads in general to increased heat transfer and temperature slip leads to reduced heat transfer.

Effects of Snap-Off in Imbibition in Porous Media with Different Spatial Correlations

Abstract: Quasi-static imbibition was simulated using random and correlated stochastic network models. Using the snap-off pore-scale displacement observed by Lernormand et al. (1983) the effects of many parameters on relative permeabilities and residual saturation reported in the literature were reproduced and explained. Increased relative permeabilities and decreased residual non-wetting phase saturation were the results of an increased contact angle (Li and Wardlaw, 1986b; Gauglitz and Radke, 1990; Blunt et al., 1992; Mogensen and Stenby, 1998) a decreased pore–throat aspect ratio, the presence of long-range pore-pore size correlations (Iaonnidis and Chatzis, 1993; Blunt, 1997a), or local pore–throat correlations (Jerauld and Salter, 1990; Iaonnidis and Chatzis, 1993). By modifying the level of snap-off, or its spatial distribution, these parameters varied the efficiency of the displacement patterns and ultimately affect relative permeabilities and residual saturations. Mani and Mohanty (1999) performed simulations on networks with infinite-ranged fractional Brownian motion (fBm) correlations and reported trends of relative permeabilities and residual saturations that were opposite to others’ results (Ioannidis and Chatzis, 1993; Blunt, 1997a). Applying a cut-off length to the fBm correlations reversed Mani and Mohanty’s trends to conform with the common observations.

Immiscible Displacement in the Interacting Capillary Bundle Model Part II. Applications of Model and Comparison of Interacting and Non-Interacting Capillary Bundle Models

Abstract: In the first part of this work (Dong et al., Transport Porous Media, 59, 1–18, 2005), an interacting capillary bundle model was developed for analysing immiscible displacement processes in porous media. In this paper, the second part of the work, the model is applied to analyse the fluid dynamics of immiscible displacements. The analysis includes: (1) free spontaneous imbibition, (2) the effects of injection rate and oil–water viscosity ratio on the displacement interface profile, and (3) the effect of oil–water viscosity ratio on the relative permeability curves. Analysis of a non-interacting tube bundle model is also presented for comparison. Because pressure equilibration between the capillaries is stipulated in the interacting capillary model, it is able to reproduce the behaviour of immiscible displacement observed in porous media which cannot be modelled by using non-interacting tube bundle models.

Reflection and Transmission of Elastic Waves from the Interface of a Fluid-saturated Porous Solid and a Double Porosity Solid

Abstract: The reflection and transmission characteristics of an incident plane P1 wave from the interface of a fluid-saturated single porous solid and a fluid-saturated double porosity solid are investigated. The fluid-saturated porous solid is modeled with the classic Biot’s theory and the double porosity medium is described by an extended Biot’s theory. In a double-porosity model with dual-permeability there exist three compressional waves and a shear wave. The effects of the incident angle and frequency on amplitude ratios of the reflected and transmitted waves to the incident wave are discussed. Two boundary conditions are discussed in detail: (a) Open-pore boundary and (b) Sealed-pore boundary. Numerical results reveal that the characteristics of the reflection and transmission coefficients to the incident angle and the frequency are quite different for the two cases of boundary conditions. Properties of the bulk waves existing in the fluid-saturated porous solid and the double porosity medium are also studied.

Achieving Rapid Absorption and Extensive Liquid Uptake Capacity in Porous Structures by Decoupling Capillarity and Permeability: Nanoporous Modified Calcium Carbonate

Abstract: Porous media with rapid absorption properties are greatly sought after in the fields of super absorbers and catalysts. Natural materials, such as diatomite, or synthetic zeolite feature strongly in industrial reaction processes. Most, or all, of such materials, however, are surface acidic. A novel rapidly absorbing alkaline porous structure, with a high absorption capacity, is presented here. As in the case of diatomite or zeolite, the pigment design incorporates strong capillarity within a highly permeable packed medium. A model is proposed for general use with highly absorbing media that can be proven microscopically to have separate domains of micro- or nano-capillarity embedded within a permeable matrix. The new pigment morphology, based on natural ground calcium carbonate (gcc), exhibits this property using special surface structure modifications. It is contrasted with standard gcc by using consolidated tablet blocks made from a suspension of the pigment and chosen mixtures thereof. The blocks are characterised after drying by mercury porosimetry, and the absorption dynamic of a selected liquid is studied. It is shown that using a self-assembly method of discrete pore structures provides a much faster absorption rate and a liquid capacity for up to 10 times more fluid than a conventional homogeneously distributed pore concept. In such unique discrete network systems, the mercury intrusion curve provides a separable analysis of permeability and capillarity in respect to the inflection point of the cumulative intrusion curve. The discrete decoupled properties each follow the absorption behaviour predicted by previous modelling (Ridgway and Gane, Colloids and Surfaces A: Physicochemical and Engineering Aspects, 206(1–3), 2002). The absorption driving force is shown to be determined by the proportion of fine pores present up to a size equal to a Bosanquet inertially-defined optimum within the timescale of absorption. Combining the wetting force, from the capillarity-controlled fine pore structure, with the experimental flow resistance of the sample, consisting of the assembly of particles, it is possible to predict the trends in absorption dynamic using the pore and throat model Pore-Cor.* Use of this model allows existing materials as well as new synthetic designs to be modelled prior to manufacture. The novel alkaline material is compared with independent absorption data for diatomite and shown to be comparable.

Fingering Instability in Water-Oil Displacement

Abstract: Following the classical Buckley–Leverett theory for the two-phase immiscible flows in porous media a non-linear evolution equation for the water-oil displacement front is formulated and studied numerically. The numerical simulations yield a physically plausible picture of the fingering instability known to develop in water-oil systems. A way to control the unrestricted growth of fingers is discussed. Distinctions and similarities with dynamically related Saffman–Taylor and Darrieus–Landau problems are outlined.

Natural Convection Inside an Inclined Wavy Enclosure Filled with a Porous Medium

Abstract: The Darcy flow model with the Boussinesq approximation is used to investigate numerically the natural convection inside an inclined wavy cavity filled with a porous medium. Finite Element Method is used to discretize the governing differential equations with non-staggered variable arrangement. Results are presented for $$0^{\circ}\leqslant \phi \leqslant 90^{\circ}, 10\leqslant Ra\leqslant 10^3, 1\leqslant A\leqslant 3$$ and $$0\leqslant \lambda \leqslant 0.3$$ , where ϕ, Ra, A and λ correspond to the cavity inclination angle, Rayleigh number, aspect ratio and surface waviness parameter, respectively. Stream and isotherm lines representing the corresponding flow and thermal fields, and local and average Nusselt numbers distribution expressing the rate of heat transfer are determined and shown on graphs and tables. A good agreement is observed between the present results and those known from the open literature. The flow and thermal structures found to be highly dependent on surface waviness for inclination angles less than 45°, especially for high Rayleigh numbers.