Journal ArticleDOI
3,3'-Disubstituted 2,2'-biphenols. Synthesis of nonplanar, tetradentate chelating ligands
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This article is published in Journal of Organic Chemistry.The article was published on 1985-12-01. It has received 15 citations till now. The article focuses on the topics: Claisen rearrangement.read more
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Nickel-Catalyzed Cyclizations, Couplings, and Cycloadditions Involving Three Reactive Components
TL;DR: This account outlines work primarily from the author's laboratory on the development of nickel-catalyzed multicomponent coupling processes, an overview of new synthetic methods, a discussion of potential mechanisms, and a description of applications in complex-molecule synthesis are provided.
Journal ArticleDOI
Asymmetric conjugate 1,4-addition of arylboronic acids to alpha, beta-unsaturated esters catalyzed by Rhodium(I)/(S)-binap
TL;DR: The rhodium/(S)-binap complex provided (R)-3-phenylbutanoate in the addition of phenylboronic acid to benzyl crotonate and the effects on the enantioselectivity of chiral phosphine ligands, r Rhodium precursors, and substituents on alpha,beta-unsaturated esters are discussed.
Patent
Heterocyclic compounds as immunomodulators
TL;DR: In this paper, compounds of Formula (I), methods of using the compounds as immunomodulators, and pharmaceutical compositions comprising such compounds are discussed. But they are useful in treating, preventing or ameliorating diseases or disorders such as cancer or infections.
Journal ArticleDOI
Unprecedented Alkene Complex of Zinc(II): Structures and Bonding of Divinylzinc Complexes
TL;DR: This report describes the solid-state structures of a series of divinylzinc complexes, one of which represents the only structurally characterized zinc(II) pi-complex, which exhibits an infinite polymeric architecture in the solid state via aseries of zinc-pi and zinc-sigma-bonded interactions.
Journal ArticleDOI
Synthesis and Coordination Properties of Chelating Dithiophenolate Ligands
TL;DR: The tin complex (4c)SnPh(2) (6c) was additionally synthesized to prove the coordinating abilities of the allyl substituted ligand 4c, and it was shown to severely effect their ligating properties.
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