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Open AccessJournal ArticleDOI

3D Monodisperse Oligofluorenes with Non-Conjugated Triphenylamine-Based Cores: Synthesis and Optoelectronic Properties

TLDR
Two 3D monodisperse oligofluorenes with non-conjugated triphenylamine-based cores have been synthesized by Friedel-Crafts copolycondensation reaction and emit deep-blue fluorescence with high efficiencies in thin films.
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This article is published in European Journal of Organic Chemistry.The article was published on 2010-04-01 and is currently open access. It has received 12 citations till now. The article focuses on the topics: Triphenylamine.

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Citations
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Stabilized Blue Emission from Polyfluorene-Based Light-Emitting Diodes: Elimination of Fluorenone Defects

Xiong Gong
TL;DR: In this paper, the photoluminescence (PL) and electroluminescent (EL) of polyfluorene (PF)-based light-emitting diodes (LEDs) were studied and it was shown that the low-energy emission band originates from fluorenone defects which are introduced by photo-oxidization, thermal oxidation, or during device fabrication.
Journal ArticleDOI

Novel Deep Blue OLED Emitters with 1,3,5-Tri(anthracen-10-yl)benzene-Centered Starburst Oligofluorenes

TL;DR: A series of starburst materials (T1−T3) bearing a 1,3,5-tri(anthracen-10-yl)benze-ne core (T0) and three oligofluorenes arms have been synthesized and characterized.
Journal ArticleDOI

A solution-processable triphenylamine-fluorene host for exciplex based white phosphorescent organic light-emitting diodes

TL;DR: In this article, a triphenylamine-fluorene oligomer with macro-spirocyclic structure was designed and prepared as a host for exciplex based white phosphorescent organic light-emitting diodes (white PhOLEDs), in which only iridium(III)bis(4,6-(difluorophenyl)pyridinato-N,C2)picolinate (FIrpic) was employed as the dopant.
Journal ArticleDOI

Dipyrido[3,2‐a:2′,3′‐c]phenazine‐Based Donor–Acceptor Aromatic Heterocyclic Compounds with Thienyl and Triphenylamino Chromophores at the 2,7‐ and/or 10,13‐Positions

TL;DR: A series of T- and H-shaped donor-acceptor (D-A) types of dipyrido[3,2-a:2',3'-c]phenazine (DPPZ)-based molecules, extended by thienyl and triphenylamino chromophores at the 2,7-(bottom) and/or 10,13-positions (top), have been designed and prepared successfully.
Journal Article

Electrochemical and fluorescent properties of alternating copolymers of 9,9-dioctylfluorene and oxadiazole as blue electroluminescent and electron transport materials : Molecular photonics and electronics

TL;DR: In this paper, the properties of alternating copolymers of 9,9-dioctylfluorene and oxadiazole (F/Ox) have been studied by cyclic voltammetry (CV), photoluminescence (PL) and electroluminecence (EL).
References
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Journal ArticleDOI

New Base-Doped Polyfluorene Derivatives

TL;DR: A series of new well-defined acidic poly(2,7-fluorene) derivatives have been synthesized by palladium-catalyzed Suzuki couplings.
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Synthesis and Characterization of Pyrene‐Centered Starburst Oligofluorenes

TL;DR: A series of starburst materials (T1-T3) based on a pyrene core with four oligofluorene arms of different length have been synthesized and characterized as mentioned in this paper.
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Giant Extended π-Conjugated Dendrimers Containing the 10,15-Dihydro-5H-diindeno[1,2-a;1‘,2‘-c]fluorene Chromophore: Synthesis, NMR Behaviors, Optical Properties, and Electroluminescence

TL;DR: The facile synthetic strategy of a series of novel pi-conjugated dendrimers based on 10,15-dihydro-5H-diindeno[1,2-a;1',2'-c]fluorene (truxene) in which the benzene cores are generated "in-situ" from acetyl aromatics by the acid-promoted cyclotrimerizations is reported.
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Facile Synthesis of Complicated 9,9-Diarylfluorenes Based on BF3·Et2O-Mediated Friedel−Crafts Reaction

TL;DR: The 9,9-diarylfluorenes tethered with various functional substituents, e.g., bulky spiro units, hole-transporting moieties, and fluorescent dyes, will be promising building blocks for the construction of optoelectronic materials.
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Enhancement of spectral stability and efficiency on blue light-emitters via introducing dibenzothiophene-S,S-dioxide isomers into polyfluorene backbone

TL;DR: In this paper, Dai et al. showed that the FSO unit acts as a deep trap for electron in the polyfluorene backbone, which could suppress the long wavelength emission.
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