A Lithium-Sulfur Battery using a 2D Current Collector Architecture with a Large-Sized Sulfur Host Operated under High Areal Loading and Low E/S Ratio.
Matthew Li,Matthew Li,Yining Zhang,Zhengyu Bai,Wen Wen Liu,Tongchao Liu,Jihyeon Gim,Gaopeng Jiang,Yifei Yuan,Yifei Yuan,Dan Luo,Kun Feng,Reza Shahbazian Yassar,Xiaolei Wang,Zhongwei Chen,Jun Lu +15 more
TLDR
A spray-dried sulfur composite with large intrinsic internal pores, ensuring adequate local electrolyte availability, and evidence is provided that the high-frequency semicircle is mainly responsible for the often observed bypassing of the second plateau in lean electrolyte discharges.Abstract:
While backless freestanding 3D electrode architectures for batteries with high loading sulfur have flourished in the recent years, the more traditional and industrially turnkey 2D architecture has not received the same amount of attention. This work reports a spray-dried sulfur composite with large intrinsic internal pores, ensuring adequate local electrolyte availability. This material offers good performance with a electrolyte content of 7 µL mg-1 at high areal loadings (5-8 mg cm-2 ), while also offering the first reported 2.8 µL mg-1 (8 mg cm-2 ) to enter into the second plateau of discharge and continue to operate for 20 cycles. Moreover, evidence is provided that the high-frequency semicircle (i.e., interfacial resistance) is mainly responsible for the often observed bypassing of the second plateau in lean electrolyte discharges.read more
Citations
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Nitrogen-Doped Mesoporous Carbon Promoted Chemical Adsorption of Sulfur and Fabrication of High-Areal-Capacity Sulfur Cathode with Exceptional Cycling Stability for Lithium-Sulfur Batteries
TL;DR: In this article, a mesoporous nitrogen-doped carbon (MPNC)-sulfur nanocomposite is reported as a novel cathode for advanced Li-S batteries.
Journal ArticleDOI
Commercialization of Lithium Battery Technologies for Electric Vehicles
Xiaoqiao Zeng,Matthew Li,Matthew Li,Deia Abd El-Hady,Wael Alshitari,Abdullah S. Al-Bogami,Jun Lu,Khalil Amine,Khalil Amine +8 more
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Lithium-Sulfur Batteries under Lean Electrolyte Conditions: Challenges and Opportunities.
TL;DR: In this article, the impact of the electrolyte/sulfur ratio on the actual energy density and the economic cost of Li-S batteries is addressed, and challenges and recent progress are presented in terms of the sulfur electrochemical processes: the dissolution-precipitation conversion and the solid-solid multi-phasic transition.
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Current Status and Future Prospects of Metal–Sulfur Batteries
TL;DR: The current state of the research indicates that lithium-sulfur cells are now at the point of transitioning from laboratory-scale devices to a more practical energy-storage application, and over 450 research articles are summarized to analyze the research progress and explore the electrochemical characteristics, cell-assembly parameters, cell -testing conditions, and materials design.
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Bridging the academic and industrial metrics for next-generation practical batteries.
TL;DR: This Perspective discussed the best practices for reporting lab-scale performance metrics in battery papers, and explained metrics such as anode energy density, voltage hysteresis, mass of non-active cell components and anode/cathode mass ratio.
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Journal ArticleDOI
Nitrogen-Doped Mesoporous Carbon Promoted Chemical Adsorption of Sulfur and Fabrication of High-Areal-Capacity Sulfur Cathode with Exceptional Cycling Stability for Lithium-Sulfur Batteries
Jiangxuan Song,Terrence Xu,Mikhail L. Gordin,Pengyu Zhu,Dongping Lv,Ying Bing Jiang,Yongsheng Chen,Yuhua Duan,Donghai Wang +8 more
TL;DR: In this article, a mesoporous nitrogen-doped carbon (MPNC)-sulfur nanocomposite is reported as a novel cathode for advanced Li-S batteries.