Journal ArticleDOI
Alkynylation of C−H Bonds via Reaction with Acetylenic Triflones1
Jianchun Gong,Philip L. Fuchs +1 more
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This article is published in Journal of the American Chemical Society.The article was published on 1996-05-08. It has received 179 citations till now.read more
Citations
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Journal ArticleDOI
Good Partnership between Sulfur and Fluorine: Sulfur-Based Fluorination and Fluoroalkylation Reagents for Organic Synthesis
Chuanfa Ni,Mingyou Hu,Jinbo Hu +2 more
Journal ArticleDOI
Carbon trifluoromethylation reactions of hydrocarbon derivatives and heteroarenes.
Journal ArticleDOI
Strategies for nucleophilic, electrophilic, and radical trifluoromethylations
Jun-An Ma,Dominique Cahard +1 more
TL;DR: Recent advances in the development of new strategies in nucleophilic, electrophilic, and radical trifluoromethylations are reviewed in this article, where the emphasis is given to the description of the triffluoromethrylating agents, their activation mode, their reaction with carbonyl compounds and derivatives, as well as application in asymmetric synthesis.
Journal ArticleDOI
Direct Sp3α-C-H activation and functionalization of alcohol and ether.
TL;DR: Seven kinds of sp(3)α-C-H activation/C-C formation reactions of alcohols and ethers have been reviewed in this tutorial review, from the viewpoint of both methodology and synthetic application, towards the efficiency, chemo-, regio- and stereoselectivity, catalytic system, substrate scope and mechanistic study.
Journal ArticleDOI
Electrophilic alkynylation: the dark side of acetylene chemistry
Jonathan P. Brand,Jerome Waser +1 more
TL;DR: In addition to the well-established nucleophilic alkynylation, the use of electrophilic alkynes can expand tremendously the scope of acetylene transfer reactions, and sulfonyl acetylenes are efficient for alkyne transfer on carbon-centered radicals.
References
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Journal ArticleDOI
Trifluoromethylation of aromatic compounds with sodium trifluoromethanesulfinate under oxidative conditions.
TL;DR: In this paper, triluforomethylated aromatic compounds with sodium trifluoromethanesulfinate and t-butyl hydroperoxide are described.
Journal ArticleDOI
New method for trifluoromethylation of enolate anions and applications to regio-, diastereo- and enantioselective trifluoromethylation
Teruo Umemoto,Kenji Adachi +1 more
TL;DR: In this article, the effectiveness of different boron Lewis acids in mediating the trifluoromethylation of reactive enolate anions with S- and Se-(trifluorsicyl)chalcogen salts was assessed.
Journal ArticleDOI
“Pseudo-cationic” trifluoromethylation of enol esters with sodium trifluoromethanesulfinate.
TL;DR: In this article, enol esters are converted into α-trifluoromethylated ketones and/or enol ketones with catalytic amounts of Cu(II).
Related Papers (5)
Alkenylation of C−H Bonds via Reaction with Vinyl and Dienyl Triflones. Stereospecific Synthesis of Trisubstituted Vinyl Triflones via Organocopper Addition to Acetylenic Triflones1
Jason Xiang and,Philip L. Fuchs +1 more