An updated roadmap for the integration of metal–organic frameworks with electronic devices and chemical sensors
read more
Citations
Rapid Generation of Hierarchically Porous Metal–Organic Frameworks through Laser Photolysis
Proton conductive metal sulfonate frameworks
Applications of reticular diversity in metal–organic frameworks: An ever-evolving state of the art
Structure and properties of dynamic metal–organic frameworks: a brief accounts of crystalline-to-crystalline and crystalline-to-amorphous transformations
New OLEDs Based on Zirconium Metal-Organic Framework
References
The Chemistry and Applications of Metal-Organic Frameworks
Functional porous coordination polymers.
The missing memristor found
Verwendung von Schwingquarzen zur Wägung dünner Schichten und zur Mikrowägung
Related Papers (5)
Frequently Asked Questions (18)
Q2. What are the contributions mentioned in the paper "An updated roadmap for the integration of metal–organic frameworks with electronic devices and chemical sensors" ?
This review highlights the research aimed at the implementation of MOFs as an integral part of solid-state microelectronics. Both the fundamental and applied aspects of this two-pronged approach are discussed.
Q3. What is the importance of a low density of defects and high charge mobility?
A low density of electrically active defects and high charge mobility are also essential for an efficient LED so that injected holes and electrons can penetrate the emitting layer(s) and recombine to form excitons withminimal non-radiative recombination.
Q4. What is the role of a MOF in a DSSC?
MOFs are well suited to serve as the dye (i.e. light harvesting) component of a DSSC by virtue of the ability to build structures with multiple light absorbers locked into a stable crystalline structure.
Q5. What are the characteristics that make MOFs attractive for charge transport?
The same material characteristics that make MOFs attractive for charge transport operate here, namely synthetic tunability, long-range order and porosity as an additional design element.
Q6. What is the generalized concept of impedance in AC circuit analysis?
In AC circuit analysis, the generalized concept of impedance (Z, O) is defined in analogy to DC resistance, as the voltage to current ratio.
Q7. What is the reason why the MOF phase has an intrinsic preference for alignment parallel to the surface?
in some cases the MOF phase has an intrinsic preference for alignment parallel to the surface, because of the formation of well-defined crystal faces or the inherently layered nature of the material.
Q8. What is the effect of a reduction of the NO3anion on the MOF-5?
For instance, in a synthesis solution containing Zn(II) nitrate and terephthalic acid, the generation of OH ions through reduction of the NO3anion results in ligand deprotonation and formation of a MOF-5 film on the cathode.
Q9. What are the advantages of using metal oxide films as precursors for MOF coatings?
The approach of using metal oxide films as precursors for MOF coatings benefits from a range of established technologies for deposition of the former (PVD, CVD, ALD, sol–gel methods, etc.).
Q10. What are the promising strategies for proton transport in MOFs?
While most of the proton-conducting frameworks require hydration, several promising strategies have been developed for anhydrous proton transport in MOFs.
Q11. Why is the substitution of solid-state electrolytes an active research topic?
replacing these systems with solid-state electrolytes is an active research topic, mainly because of their volatility, flammability and reactivity towards the electrodes.
Q12. What are the reasons why integrating liquid components as part of vertical stacks is not possible?
In the context of microelectronic devices, integration of liquid components as part of vertical stacks is not possible due to structural reasons and incompatibility with vacuum technology.
Q13. How many materials have been characterized in depth?
Although nano-indentation is becoming a more common tool to characterize single MOF crystals and thin film, few materials have been characterized in depth.
Q14. How did the researchers combine the interfacial growth processes with subsequent film transfer?
To fabricate the first FETs based on semiconducting MOFs,28,46 interfacial growth processes were combined with subsequent film transfer.
Q15. How do MOF films differ from other thin film deposition technologies?
Compared to established thin film deposition technologies (e.g. sol–gel methods, PVD, CVD, ALD), MOF films typically show a higher roughness, often above 10% of the film thickness.
Q16. How can the electronic properties of MOFs be tuned?
In contrast to purely inorganic or organic conductors such as MoS2 or graphene, which do not easily lend themselves to chemical functionalization, the electronic properties of MOFs can be tuned by chemically altering the linker, metal ion or guest species adsorbed in the pore space.
Q17. How can analyte-permeable dielectric sensing materials be screened?
recent studies demonstrated that analyte-permeable dielectric sensing materials can also be screened using the KP method.
Q18. What is the way to combine MOFs with more recent sensors?
It will be interesting to see the performance gain by combining MOFs with more recent sensors that exploit different elastic wave propagation modes including acoustic-plate-mode and flexural-plate-wave devices.