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Aphanamixoid A, a Potent Defensive Limonoid, with a New Carbon Skeleton from Aphanamixis polystachya

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TLDR
The significant antifeedant activity of 1 against the generalist plant-feeding insect Helicoverpa armigera suggested it may be a potent defensive component of A. polystachya.
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This article is published in Organic Letters.The article was published on 2012-05-18. It has received 89 citations till now. The article focuses on the topics: Aphanamixis polystachya & Aphanamixis.

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Ring A rearranged limonoids from the fruits of Aphanamixis grandifolia and their cytotoxicity evaluation

TL;DR: Two new limonoids aphanamolides C (1) and D (2), together with two known limonoid A (3) and aphapolynin A (4), were isolated from the fruits of Aphanamixis grandifolia as mentioned in this paper.
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Aphananoid A is an Anti-Inflammatory Limonoid with a New 5/6/5 Fused Ring Featuring a C24 Carbon Skeleton from Aphanamixis polystachya.

TL;DR: The planar structure as well as the absolute configuration were identified based on extensive spectroscopic analysis and electronic circular dichroism (ECD) calculations and the biogenetic pathway of aphananoid A was speculated.
Journal ArticleDOI

Two new tirucallane triterpenoids from Aphanamixis grandifolia

TL;DR: In this article, two new tirucallane triterpenoids, 2 α-ethoxy-2,3-secotirucalla, 2,29-epoxy-7-ene-23-oxo-3-oic acid (1) and (23E)-2 α-hydroxytirucna-7,23,25-triene-3,one (2), along with the known 2,3secotiriucalla-2.
References
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Journal ArticleDOI

On enantiomorph‐polarity estimation

TL;DR: In this article, the behaviour of the Rogers's η parameter for enantiomorph-polarity estimation is examined theoretically and experimentally on simulated intensity data for seven well-assorted compounds.
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Meliaceous limonoids: chemistry and biological activities.

TL;DR: This paper aims to demonstrate the efforts towards in-situ applicability of EMMARM, as to provide real-time information about concrete mechanical properties such as E-modulus and compressive strength.
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Three new indole alkaloids from Trigonostemon lii.

TL;DR: Three unprecedented indole alkaloids, trigonoliimines A-C (1-3) with a unique polycyclic system, were isolated from the leaves of Trigonostemon lii Y. T. Chang.
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The Advances in the Limonoid Chemistry of the Meliaceae Family

TL;DR: The Meliaceae family is rich sources of limonoid (meliacin), which are well known for their antifeedant activity and bitterness as mentioned in this paper, although their existence also could be found in Rutaceae, Cneoraceae, Ptaeroxylaceae, and Simaroubaceae family.
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