Journal ArticleDOI
Asymmetric alkylation of beta-ketoesters
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This article is published in Journal of the American Chemical Society.The article was published on 1997-08-20. It has received 158 citations till now. The article focuses on the topics: Beta (finance) & Alkylation.read more
Citations
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Palladium-catalyzed cross-coupling reactions in total synthesis.
TL;DR: In this Review, highlights of a number of selected syntheses are discussed, demonstrating the enormous power of these processes in the art of total synthesis and underscore their future potential in chemical synthesis.
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Asymmetric transition-metal-catalyzed allylic alkylations: applications in total synthesis.
TL;DR: Alkylations with Phenols, Nitrogen Nucleophiles in AAA Total Synthesis, and Considerations for Enantioselective Allylic Alkylation are presented.
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Metal-catalyzed enantioselective allylation in asymmetric synthesis.
TL;DR: Metal-catalyzed enantioselective allylation, which involves the substitution of allylic metal intermediates with a diverse range of different nucleophiles or S(N)2'-type allylic substitution, leads to the formation of C-H, -C, -O, -N, -S, and other bonds with very high levels of asymmetric induction.
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Nitrogen-containing ligands for asymmetric homogeneous and heterogeneous catalysis.
TL;DR: It is shown here how the structure of the C−O Bond Formation following C−H Bond Oxidation following Baeyer−Villiger-type Reaction and Wacker-type Cyclization influenced the formation of the S−N Bond Formation.
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Palladiumkatalysierte Kreuzkupplungen in der Totalsynthese
Kyriacos C. Nicolaou,Kyriacos C. Nicolaou,Paul G. Bulger,Paul G. Bulger,David Sarlah,David Sarlah +5 more
TL;DR: In this paper, the authors discuss the effect of leistungsfahigen Reaktionen on the Potenzial f f zukunftige chemischen Synthesen unterstreichen, i. e.g., palladiumkatalysierten Kreuzkupplungen.
References
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Asymmetric Transition Metal-Catalyzed Allylic Alkylations.
TL;DR: The focus of this review is on the area of enantioselective transition metal-catalyzed allylic alkylations which may involve C-C as well as C-X (X ) H or heteroatom) bond formation.
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Allylic alkylation. Palladium-catalyzed substitutions of allylic carboxylates. Stereo- and regiochemistry
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