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C$_{60}$ in Reflection Nebulae

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TLDR
In this article, the spectral properties of neutral C$60$ in the interstellar medium were confirmed by detecting a third emission feature at 7.04 $pm$ 0.05 $m in the reflection nebula NGC 7023.
Abstract
The fullerene C$_{60}$ has four infrared-active vibrational transitions at 7.0, 8.5, 17.4 and 18.9 $\mu$m. We have previously observed emission features at 17.4 and 18.9 $\mu$m in the reflection nebula NGC 7023 and demonstrated spatial correlations suggestive of a common origin. We now confirm our earlier identification of these features with C$_{60}$ by detecting a third emission feature at 7.04 $\pm$ 0.05 $\mu$m in NGC 7023. We also report the detection of these three C$_{60}$ features in the reflection nebula NGC 2023. Our spectroscopic mapping of NGC 7023 shows that the 18.9 $\mu$m C$_{60}$ feature peaks on the central star and that the 16.4 $\mu$m emission feature due to polycyclic aromatic hydrocarbons peaks between the star and a nearby photodissociation front. The observed features in NGC 7023 are consistent with emission from UV-excited gas-phase C$_{60}$. We find that 0.1-0.6% of interstellar carbon is in C$_{60}$; this abundance is consistent with those from previous upper limits and possible fullerene detections in the interstellar medium. This is the first firm detection of neutral C$_{60}$ in the interstellar medium.

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The molecular universe

TL;DR: In this paper, a review of molecular observations in various spectral windows and summarizes the chemical and physical processes involved in the formation and evolution of interstellar molecules is presented, focusing on the characteristics of complex polycyclic aromatic hydrocarbon molecules and fullerenes.
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Laboratory confirmation of C60+ as the carrier of two diffuse interstellar bands

TL;DR: Maier et al. as discussed by the authors reported laboratory spectroscopy of C60+ in the gas phase, cooled to 5.8 kelvin, and confirmed that the diffuse interstellar bands that Foing and Ehrenfreund observed do arise from C60 molecules in the interstellar medium.
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Formation of buckminsterfullerene (C60) in interstellar space

TL;DR: It is argued that polycyclic aromatic hydrocarbons are converted into graphene, and subsequently C60, under UV irradiation from massive stars, shows that alternative—top-down—routes are key to understanding the organic inventory in space.
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Laboratory Formation of Fullerenes from PAHs: Top-down Interstellar Chemistry

TL;DR: In this article, the photochemical evolution of large polycyclic aromatic hydrocarbons (PAHs) was investigated and it was shown that PAHs in excess of 60 C-atoms efficiently photo-isomerize to buckminsterfullerene, C60.
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Laboratory astrophysics and astrochemistry in the Herschel/ALMA era

TL;DR: The interpretation of molecular line surveys at millimetre and submillimetre wavelengths towards astrophysical objects requires a good knowledge of the spectroscopy of the molecules present in the gas phase, and of the basic collisional processes between them and molecular and atomic Hydrogen, Helium, and electrons as mentioned in this paper.
References
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Journal ArticleDOI

C 60 : Buckminsterfullerene

TL;DR: In this article, the authors proposed a truncated icosahedron, a polygon with 60 vertices and 32 faces, 12 of which are pentagonal and 20 hexagonal.
Journal ArticleDOI

The Infrared Spectrograph on the Spitzer Space Telescope

TL;DR: The Infrared Spectrograph (IRS) is one of the three science instruments on the Spitzer Space Telescope as mentioned in this paper, which is optimized to take full advantage of the very low background in the space environment.
Journal ArticleDOI

Interstellar Polycyclic Aromatic Hydrocarbon Molecules

TL;DR: In this paper, a review of the observed mid-IR spectral properties of polycyclic aromatic hydrocarbons (PAHs) is presented, emphasizing the contribution of these species to photoelectric heating and the ionization balance of the interstellar gas and to the formation of small hydrocarbon radicals and carbon chains.
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