Cerium-based metal organic frameworks with UiO-66 architecture: synthesis, properties and redox catalytic activity.
Martin Lammert,Michael T. Wharmby,Simon Smolders,Bart Bueken,Alexandra Lieb,Kirill A. Lomachenko,Dirk De Vos,Norbert Stock +7 more
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A series of nine Ce(iv)-based metal organic frameworks with the UiO-66 structure containing linker molecules of different sizes and functionalities were obtained under mild synthesis conditions and short reaction times.About:
This article is published in Chemical Communications.The article was published on 2015-07-23 and is currently open access. It has received 312 citations till now. The article focuses on the topics: Benzyl alcohol & Metal-organic framework.read more
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Stable Metal-Organic Frameworks: Design, Synthesis, and Applications.
Shuai Yuan,Liang Feng,Kecheng Wang,Jiandong Pang,Matheiu Bosch,Christina T. Lollar,Yujia Sun,Jun-Sheng Qin,Xinyu Yang,Peng Zhang,Qi Wang,Lanfang Zou,Yingmu Zhang,Liangliang Zhang,Yu Fang,Jialuo Li,Hong-Cai Zhou +16 more
TL;DR: This review is expected to guide the design of stable MOFs by providing insights into existing structures, which could lead to the discovery and development of more advanced functional materials.
Journal ArticleDOI
Metal–organic and covalent organic frameworks as single-site catalysts
Sven Rogge,Anastasiya Bavykina,Julianna Hajek,Hermenegildo García,Alma I. Olivos-Suarez,Antonio Sepúlveda-Escribano,Alexandre Vimont,Guillaume Clet,Philippe Bazin,Freek Kapteijn,Marco Daturi,Enrique V. Ramos-Fernandez,F.X. Llabrés i Xamena,Veronique Van Speybroeck,Jorge Gascon +14 more
TL;DR: The potential of metal–organic frameworks (MOFs) and covalent organic frameworks (COFs) as platforms for the development of heterogeneous single-site catalysts is reviewed thoroughly.
Journal ArticleDOI
Metal-Organic Framework-Based Catalysts with Single Metal Sites.
TL;DR: This review overviews the recent developments of catalysis at single metal sites in MOF-based materials with emphasis on their structures and applications for thermocatalysis, electrocatalysis, and photocatalysis.
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Catalysis by Metal Organic Frameworks: Perspective and Suggestions for Future Research
Dong Yang,Bruce C. Gates +1 more
TL;DR: In this paper, the advantages and limitations of MOFs as catalysts are summarized and fundamental issues to be addressed about their potential applications, including shape-selective and bifunctional catalysis, and quantifying reaction/transport processes in MOFs, identifying catalytic sites, and determining intrinsic catalytic reaction rates.
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Cerium Metal–Organic Framework for Photocatalysis
TL;DR: It is found that linker functionalization with electron donating or withdrawing groups allows tuning of the LMCT energy, and increasing the number of functional groups on each linker enhances the tuning; these findings are encouraging for applying Ce-MOFs for visible-response photocatalytic water splitting.
References
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The Chemistry and Applications of Metal-Organic Frameworks
Hiroyasu Furukawa,Hiroyasu Furukawa,Kyle E. Cordova,Kyle E. Cordova,Michael O'Keeffe,Michael O'Keeffe,Omar M. Yaghi,Omar M. Yaghi,Omar M. Yaghi +8 more
TL;DR: Metal-organic frameworks are porous materials that have potential for applications such as gas storage and separation, as well as catalysis, and methods are being developed for making nanocrystals and supercrystals of MOFs for their incorporation into devices.
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Functional porous coordination polymers.
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Reticular synthesis and the design of new materials
Omar M. Yaghi,Michael O'Keeffe,Nathan W. Ockwig,Hee K. Chae,Hee K. Chae,Mohamed Eddaoudi,Jaheon Kim +6 more
TL;DR: This work has shown that highly porous frameworks held together by strong metal–oxygen–carbon bonds and with exceptionally large surface area and capacity for gas storage have been prepared and their pore metrics systematically varied and functionalized.
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Chemistry of the elements
TL;DR: In this article, the origins of the elements, isotopes and atomic weights Chemical periodicity and the periodic table were discussed, including the following elements: Hydrogen Lithium, sodium, potassium, rubidium, caesium and francium Beryllium, magnesium, calcium, strontium, barium and radium Boron Aluminium, gallium, indium and thallium Carbon Silicon Germanium, tin and lead Nitrogen Phosphorus Arsenic, antimony and bismuth Oxygen Sulfur Selenium, tellurium
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TL;DR: The state-of-the-art on hybrid porous solids, their advantages, their new routes of synthesis, the structural concepts useful for their 'design', aiming at reaching very large pores are presented.