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Chemical kinetics and reaction mechanisms
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TLDR
Reactions and reaction rates reactions with a simple kinetic form reversible and concurrent reactions consecutive reactions - the steady state and other approximations consecutive mechanisms - intermediates and numerical solutions deduction of reaction mechanisms transition state theory and microscopic reversibility chain reactions and oscillating reactions reactions in solution extrakinetic probes of mechanism reactions at extreme rates.Abstract:
Reactions and reaction rates reactions with a simple kinetic form reversible and concurrent reactions consecutive reactions - the steady state and other approximations consecutive mechanisms - intermediates and numerical solutions deduction of reaction mechanisms transition state theory and microscopic reversibility chain reactions and oscillating reactions reactions in solution extrakinetic probes of mechanism reactions at extreme rates.read more
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Journal ArticleDOI
Structure, substitution and hydrolysis of Bis(trifluorobenzoylacetonato-O,O′)dichloro titanium(IV) : an experimental and computational study
Annemarie Kuhn,Sonja Tischlik,Kathrin H. Hopmann,Marilé Landman,Petrus H. van Rooyen,Jeanet Conradie,Jeanet Conradie +6 more
TL;DR: In this article, the authors have received support from the South African National Research Foundation (JC, ML), the Central Research Fund of the University of the Free State (JC), and the Research Council of Norway through a Centre of Excellence Grant ( Grant No. 179568/V30, KH) and a FRIPRO grant (Grant No. 23170/F20, KH).
Journal ArticleDOI
Chemical Perspectives on Alkali and Earth Alkaline Nitrate and Nitrite Salts for Concentrated Solar Power Applications
TL;DR: An overview of the thermophysical properties of nitrate and nitrite salts and their kinetic stability limitations as they relate to concentrated solar power generation is presented in this paper. But, this paper is limited to a single application.
Journal ArticleDOI
Oxygen Atom Transfer in the Oxidation of Dimethyl Sulfoxide by Oxoammonium Cations.
Vasily D. Sen,V. A. Golubev,Gennadii V. Shilov,Alexander V. Chernyak,V. A. Kurmaz,Victor B. Luzhkov,Victor B. Luzhkov +6 more
TL;DR: In this article, the authors studied the reaction of six-and five-membered oxoammonium salts with DMSO and showed that the O atom from the >N+O group to the S atom of the O group was transferred and structural rearrangement of the remaining cationic framework led to the formation of hydrolytically unstable iminium salts.
Dissertation
A microreactor system for high-pressure, multiphase homogeneous and heterogeneous catalyst measurements under continuous flow
TL;DR: In this paper, a high-pressure microreactor system for catalyst study was designed, fabricated, and tested, with a unique reactor designed for each application, and the results were then reconciled with a mechanistic model.
ReportDOI
Degradation of Mustard on Moist Sand, Asphalt, and Limestone Using 13C SSMAS NMR
TL;DR: In this paper, the degradation of mustard [bis(2-chloroethyl) sulfide] on moist sand, limestone, and asphalt at 22 degrees C was followed using 13C solid state magic angle spinning (SSMAS) NMR and observed to form the sulfonium ion H-2TG and thiodiglycol within 8 weeks.