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Chemical kinetics and reaction mechanisms
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TLDR
Reactions and reaction rates reactions with a simple kinetic form reversible and concurrent reactions consecutive reactions - the steady state and other approximations consecutive mechanisms - intermediates and numerical solutions deduction of reaction mechanisms transition state theory and microscopic reversibility chain reactions and oscillating reactions reactions in solution extrakinetic probes of mechanism reactions at extreme rates.Abstract:
Reactions and reaction rates reactions with a simple kinetic form reversible and concurrent reactions consecutive reactions - the steady state and other approximations consecutive mechanisms - intermediates and numerical solutions deduction of reaction mechanisms transition state theory and microscopic reversibility chain reactions and oscillating reactions reactions in solution extrakinetic probes of mechanism reactions at extreme rates.read more
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Studies of Tungsten Alkyl Alkylidyne Compounds and Iron Porphyrin Derivatives
TL;DR: In this article, the 4a o 4b exchange at 283 K was shown to be slightly endothermic with ΔH° = 5.1(1.1) kcal/mol and ΔS° = 24(4) eu; ΔH1 = 4.0(0.9)
Biophysical Modeling and Optimal Control of DNA Amplific ation
TL;DR: A first sequence-dependent biophysical model for DNA amplifications has been developed and it is shown that amplification efficiency is affected by dynamic processes that are not accurately represented in simplified models of DNA amplification that are the basis of conventional temperature cycling protocols.
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Kinetics of unusual photoinduced currents in the solid state of some ferrocene derivatives
TL;DR: In this paper, the temperature-dependent change in photoinduced currents in the solid state of some ferrocene derivatives, namely, ferrocenecarboxylic acid (FCA), acetylferrocene (AFA), ferrocensecarbaldehyde (FBA), hydroxymethyl ferrocenes (HFR), have been studied in dry nitrogen gas atmosphere.
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Pd–C bond formation with the indole ring in palladium complexes of N,N,O-donor ligands. Effect of the nitrogen donor properties
Syogo Tanooka,Takuya Suzuki,Tatsuo Yajima,Tadashi Shiraiwa,Satoshi Iwatsuki,Yuichi Shimazaki +5 more
TL;DR: The Pd(II) complexes of three new N,N,O-donor ligands with a pendent indole ring and participation of the Indole ring in Pd-II binding have been studied by synthetic, structural, and kinetic methods.
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High trans,trans Conjugated Linoleic Acid-Rich Triacylglyceride Production by Photo-Irradiation
TL;DR: In this paper, the yield of trans,trans-CLA isomers resulting from photo-irradiation of Tonalin® (BASF Global, Florham Park, NJ, USA) was determined.