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Chemical kinetics and reaction mechanisms
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TLDR
Reactions and reaction rates reactions with a simple kinetic form reversible and concurrent reactions consecutive reactions - the steady state and other approximations consecutive mechanisms - intermediates and numerical solutions deduction of reaction mechanisms transition state theory and microscopic reversibility chain reactions and oscillating reactions reactions in solution extrakinetic probes of mechanism reactions at extreme rates.Abstract:
Reactions and reaction rates reactions with a simple kinetic form reversible and concurrent reactions consecutive reactions - the steady state and other approximations consecutive mechanisms - intermediates and numerical solutions deduction of reaction mechanisms transition state theory and microscopic reversibility chain reactions and oscillating reactions reactions in solution extrakinetic probes of mechanism reactions at extreme rates.read more
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Journal ArticleDOI
Physical, Thermal and Spectroscopic Characterization of m-Toluic Acid: an Impact of Biofield Treatment
TL;DR: In this paper, the impact of biofield treatment on physical, thermal and spectroscopic properties of m-toluic acid (MTA) was evaluated using X-ray diffraction (XRD), surface area analyser, differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), Fourier transform infrared (FT-IR) and ultraviolet-visible (UV-Vis) spectroscopy.
Journal ArticleDOI
Introduction to the dynamic self-organization of chemical systems
TL;DR: In this paper, the authors present a detailed discussion of the basic concepts of nonlinear dynamics in chemistry, such as multistability, spatiotemporal pattern formation, and deterministic chaos.
Journal ArticleDOI
Relative reactivity of vitamin A versus a mixture of β-carotene geometric isomers with electrochemically generated superoxide and hydroperoxyl radicals
TL;DR: In this paper, a kinetic comparison of the reactivity of electrochemically generated superoxide, O2 −, and hydroperoxyl, HO2, radicals toward a mixture of β-carotene geometric isomers versus all-trans-retinol (vitamin A) was conducted.
Proceedings ArticleDOI
Classical control theory approach to enzymatic reactions
Eli Gershon,R. Hiller,Uri Shaked +2 more
TL;DR: These models extend from simple and most abundant cases to more involved cases where (negative) feedback plays a major role at the level of a single enzyme reaction (including the so called ‘feed-back inhibition’).
Journal ArticleDOI
Kinetics and mechanisms of substitution of the axial and equatorial ligands in an iron(II) macrocyclic heme model complex
TL;DR: In this paper, the binding of a bipy to the [Fe(imox) (Nmim) (H2O)]+ complex proceeds according to k2 = 4.7×10−2 M−1 s−1 and k−2 = 3.6 × 10−4 S−1.