Journal ArticleDOI
CO2-Promoted Reactions: An Emerging Concept for the Synthesis of Fine Chemicals and Pharmaceuticals
TLDR
Carbon dioxide is a nontoxic and abundant chemical and has been widely used as a C1 building block for the synthesis of highly important chemicals as discussed by the authors, which has the ability to trigg...Abstract:
Carbon dioxide is a nontoxic and abundant chemical and has been widely used as a C1 building block for the synthesis of highly important chemicals. This greenhouse gas also has the ability to trigg...read more
Citations
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Journal ArticleDOI
A CO2-Catalyzed Transamidation Reaction.
TL;DR: In this article, the use of CO2 as a traceless catalyst for transamidation of peptide modification and polymer degradation has been investigated in the presence of catalytic amounts of CO 2, with primary, secondary and tertiary amide donors.
Journal ArticleDOI
Transfer Hydrogenation of CO2 and CO2 Derivatives using Alcohols as Hydride Sources: Boosting an H2-Free Alternative Strategy
TL;DR: In this article , the authors highlight the overall evolution of the transfer hydrogenation strategy for the reduction of CO2 gas (and its derivatives) to hydrogen-rich useful products achieved during the past decade.
Journal ArticleDOI
Acceleration Effect of Bases on Mn Pincer Complex-Catalyzed CO2 Hydroboration.
TL;DR: In this article , a pyridine-based Mn pincer catalyst system was designed to achieve CO2 hydroboration in low-temperature and base-free conditions through a metal-ligand cooperation mechanism.
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Catalyst-free hierarchical reduction of CO2 with BH3N(C2H5)3 for selective N-methylation and N-formylation of amines
TL;DR: An efficient and catalyst-free methodology for N-formylation and N-methylation of various amines using BH3N(C2H5)3 as a reductant and CO2 as C1 source is described.
Journal ArticleDOI
Challenges and recent advancements in the transformation of CO2 into carboxylic acids: straightforward assembly with homogeneous 3d metals.
TL;DR: In this paper , the authors summarize recent advances in 3D-metal complexes and their reactivity towards the activation of CO2 for the synthesis of carboxylic acids and discuss current research trends, knowledge gaps, and invigorating perspectives on future advances.
References
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Journal ArticleDOI
Visible Light Photoredox Catalysis with Transition Metal Complexes: Applications in Organic Synthesis
TL;DR: The conversion of these bench stable, benign catalysts to redox-active species upon irradiation with simple household lightbulbs represents a remarkably chemoselective trigger to induce unique and valuable catalytic processes.
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Palladium-Catalyzed Ligand-Directed C−H Functionalization Reactions
TL;DR: This is the first comprehensive review encompassing the large body of work in this field over the past 5 years, and will focus specifically on ligand-directed C–H functionalization reactions catalyzed by palladium.
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Palladium(II)-catalyzed C-H activation/C-C cross-coupling reactions: versatility and practicality.
TL;DR: A review of palladium-catalyzed coupling of CH bonds with organometallic reagents through a PdII/Pd0 catalytic cycle can be found in this paper.
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Aryl-aryl bond formation by transition-metal-catalyzed direct arylation.
TL;DR: A number of improvements have developed the former process into an industrially very useful and attractive method for the construction of aryl -aryl bonds, but the need still exists for more efficient routes whereby the same outcome is accomplished, but with reduced waste and in fewer steps.
Journal ArticleDOI
Transformation of carbon dioxide.
TL;DR: Reaction Mechanism, Synthesis of Urea and Urethane Derivatives, and Alcohol Homologation 2382 10.1.