Journal ArticleDOI
CO2-catalyzed/promoted transformation of organic functional groups
Waldemar Schilling,Shoubhik Das +1 more
TLDR
In this article, the authors present a review of organic functional group transformation reactions that are promoted or catalyzed by CO2 and draw a summary of the reactions that avoid toxic chemicals, expensive catalysts and often occur under mild reaction conditions.About:
This article is published in Tetrahedron Letters.The article was published on 2018-10-24. It has received 32 citations till now.read more
Citations
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Photoredox activation of carbon dioxide for amino acid synthesis in continuous flow
TL;DR: In this paper, a single-electron reduction of CO2 for continuous flow continuous flow synthesis of α-amino acids was demonstrated. But the results were limited to the selective α-carboxylation.
Journal ArticleDOI
Catalytic transformation of CO2 into C1 chemicals using hydrosilanes as a reducing agent
TL;DR: In this paper, the authors summarized the recent applications of hydrosilylation of CO2 using different catalysts such as metal catalysts, organocatalysts, and heterogeneous catalysts.
Journal ArticleDOI
A metal-free heterogeneous photocatalyst for the selective oxidative cleavage of CC bonds in aryl olefins via harvesting direct solar energy
Yu Zhang,Yu Zhang,Nareh Hatami,Niklas Simon Lange,Emanuel Ronge,Waldemar Schilling,Christian Jooss,Shoubhik Das +7 more
TL;DR: In this paper, a mild and efficient protocol has been developed using polymeric carbon nitrides (PCN) as metal-free heterogeneous photocatalysts to convert various olefins into the corresponding carbonyls.
Journal ArticleDOI
CO2-Catalyzed Efficient Dehydrogenation of Amines with Detailed Mechanistic and Kinetic Studies
Daniel Riemer,Waldemar Schilling,Anne Goetz,Yu Zhang,Sascha Gehrke,Igor Tkach,Oldamur Hollóczki,Shoubhik Das +7 more
TL;DR: In this paper, a CO2-catalyzed dehydrogenation of amines has been achieved under photocatalytic conditions, and various amines have been selectively dehydrogenated to the corresponding imines in the corresponding amines.
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Furfural – a versatile, biomass-derived platform chemical for the production of renewable chemicals
TL;DR: Furfural is an excellent and green platform chemical for the production of value-added chemicals as discussed by the authors , and it is suitable for use in many applications in the chemical industry.
References
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Journal ArticleDOI
Transformation of carbon dioxide.
TL;DR: Reaction Mechanism, Synthesis of Urea and Urethane Derivatives, and Alcohol Homologation 2382 10.1.
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Catalysis for the valorization of exhaust carbon: from CO2 to chemicals, materials, and fuels. technological use of CO2.
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Carbon capture and storage (CCS): the way forward
Mai Bui,Claire S. Adjiman,André Bardow,Edward J. Anthony,Andy Boston,Solomon Brown,Paul S. Fennell,Sabine Fuss,Amparo Galindo,Leigh A. Hackett,Jason P. Hallett,Howard J. Herzog,George Jackson,Jasmin Kemper,Samuel Krevor,Geoffrey C. Maitland,Michael Matuszewski,Ian S. Metcalfe,Camille Petit,Graeme Puxty,Jeffrey A. Reimer,David Reiner,Edward S. Rubin,Stuart A. Scott,Nilay Shah,Berend Smit,Berend Smit,J. P. Martin Trusler,Paul A. Webley,Jennifer Wilcox,Niall Mac Dowell +30 more
TL;DR: In this article, the authors review the current state-of-the-art of CO2 capture, transport, utilisation and storage from a multi-scale perspective, moving from the global to molecular scales.
Journal ArticleDOI
Using carbon dioxide as a building block in organic synthesis
TL;DR: A use of carbon dioxide as a renewable one-carbon (C1) building block in organic synthesis could contribute to a more sustainable use of resources.