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CoSi2 growth: Kinetics, phase sequence and mechanism

R. Pretorius, +2 more
- 01 May 1985 - 
- Vol. 3, pp 282-286
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TLDR
In the presence and absence of Au, very small amounts of Au (as little as 14 A at the Si Co interface) were found to increase the growth rate of CoSi2 dramatically and also caused a decrease in activation energy from 2.3 to 1.2 eV.
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This article is published in Materials Letters.The article was published on 1985-05-01. It has received 18 citations till now. The article focuses on the topics: Growth rate.

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Citations
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Journal ArticleDOI

Thin film compound phase formation sequence: An effective heat of formation model

TL;DR: In this article, an effective heat of formation (EHF) model for predicting compound phase formation sequence is described, which is based on the Miedema's model and is used to predict first phase formation during formation of silicides, germanides, aluminides and other metal-metal binary systems.
Journal ArticleDOI

Phase sequence of silicide formation at metal-silicon interfaces

R Pretorius
- 01 Jan 1990 - 
TL;DR: In this article, an effective heat of formation rule is formulated for predicting the sequence in which silicide phases form in metal-silicon binary systems, and the results show that in the presence of very small amounts of Au at the Si-Co interface, CoSi 2 is the first phase to form instead of Co 2 Si.
Journal ArticleDOI

Dominant diffusing species during cobalt silicide formation

TL;DR: The dominant moving species during cobalt monosilicide and cobalt disilicide formation has been examined using a thin tantalum layer as a metal marker in this article, where the marker data obtained following the formation of CoSi from Co2Si showed that cobalt growth was essentially due Si diffusion only.
Journal ArticleDOI

Phase separations of amorphous CoW films during oxidation and reactions with Si and Al

TL;DR: In this article, the phase separations were found in all the reactions and a compound formed is Co7 W6, which is CoSi2 in Si/CoW, Co2 Al9 in CoW/Al, and Co3 O4 in Co55 W45 with air.
Journal ArticleDOI

Nucleation and diffusion during growth of ternary Co1−xNixSi2 thin films studied by complementary techniques in real time

TL;DR: In this article, the growth kinetics of ternary Co1−xNixSi2 thin films were studied in real time using the "Kissinger" method applied to the results of ramped sheet resistance measurements to extract the apparent activation energy for the growth process.
References
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Book

Constitution of Binary Alloys

Max Hansen, +1 more
Book

Silicides for VLSI applications

TL;DR: This paper presents a meta-analysis of the physical properties of the Higgs boson gas molecule and its application in integrated circuit fabrication.
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Refractory silicides for integrated circuits

TL;DR: In this paper, various properties and the formation techniques of transition metal silicides have been reviewed and relations between the various properties of the metal or silicide electronic or crystallographic structure have been made to predict the more useful silicides for SIC applications.
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First phase nucleation in silicon–transition‐metal planar interfaces

TL;DR: In this article, the first compound nucleated in planar binary reaction couples is the most stable congruently melting compound adjacent to the lowest temperature eutectic on the bulk equilibrium phase diagram.
Journal ArticleDOI

Review of binary alloy formation by thin film interactions

TL;DR: In this article, the formation and properties of binary compounds made by thin-film interactions at temperatures well below the melting point of the various components were studied and it was suggested that the processes occurring at the interfaces control the phase formed.
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