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Crystal Engineering and Organometallic Architecture.
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This article is published in Chemical Reviews.The article was published on 1998-05-14. It has received 1116 citations till now.read more
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Reticular synthesis and the design of new materials
Omar M. Yaghi,Michael O'Keeffe,Nathan W. Ockwig,Hee K. Chae,Hee K. Chae,Mohamed Eddaoudi,Jaheon Kim +6 more
TL;DR: This work has shown that highly porous frameworks held together by strong metal–oxygen–carbon bonds and with exceptionally large surface area and capacity for gas storage have been prepared and their pore metrics systematically varied and functionalized.
Journal ArticleDOI
The hydrogen bond in the solid state.
TL;DR: The hydrogen bond is the most important of all directional intermolecular interactions, operative in determining molecular conformation, molecular aggregation, and the function of a vast number of chemical systems ranging from inorganic to biological.
Journal ArticleDOI
Covalent organic frameworks (COFs): from design to applications
San-Yuan Ding,Wei Wang +1 more
TL;DR: This critical review describes the state-of-the-art development in the design, synthesis, characterisation, and application of the crystalline porous COF materials.
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Hydrogen bridges in crystal engineering: interactions without borders.
TL;DR: The aim of this article is to highlight some features common to all hydrogen bonds and further to suggest that the term hydrogen bridge is perhaps a better descriptor for them.
Journal ArticleDOI
Crystal Engineering: A Holistic View
TL;DR: Among the topics discussed are the nature of intermolecular interactions and their role in crystal design, the sometimes diverging perceptions of the geometrical and chemical models for a molecular crystal, the relationship of these models to polymorphism, knowledge-based computational prediction of crystal structures, and efforts at mapping the pathway of the crystallization reaction.
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Journal ArticleDOI
Multi-dimensional crystal engineering of metal complexes based on complementary hydrogen bonding
TL;DR: In this paper, the bidentate ligand dithiobiuret (Hdtb) forms neutral S,S'-coordinated complexes with nickel, palladium and platinum, which possess an arrangement of hydrogen-bond donor and acceptor sites analogous to melamine and are capable of interacting with molecules with complementary hydrogenbonding capabilities.
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Phosphine derivatives of (mu -eta 2-methylidyne)(mu -hydrido)dodecacarbonyltetrairon
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Synthesis, properties, and solid-state structures of bis(alkyne)metal(0) complexes (metal = ni, pt) with substituted alkynediols and alkynols
TL;DR: In this article, a variety of tetrasubstituted alkynediols react with (cdt)Ni to give the homoleptic (alkyne)nickel complexes (HOR 1R2CC⋮CCR1R2OH)2Ni as yellow crystals that are stable in the solid state at room temperature.
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Mechanism of the low-energy fluxional process in[Fe3(CO)12-nLn] (n = 0–2): aperspective
TL;DR: In this paper, Burgi and Dunitz used crystal structures to map an exchange pathway for the carbonyls and its derivatives, and it was shown that the exchange pathway follows that predicted by the concerted bridge-opening and bridge-closing mechanism.
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A hydrogen atom in an organoplatinum-amine system: tautomers having either a bridging hydrogen with platinum(II) or a hydride on platinum(IV). The X-ray crystal structure at 100 K of [Pt{C10H6(NMe2)-8-C,N}{C10H6(NHMe2)-8-C}(Br)]
Ingrid C. M. Wehman-Ooyevaar,David M. Grove,Paul van der Sluis,Anthony L. Spek,Gerard van Koten +4 more
TL;DR: The unique zwitterionic complexes with a hydrogen atom bridging between the platinum(II) center and the formerly co-ordinating nitrogen (δH NH+ 15.8 ppm [1JPtH 180 Hz]; X-ray structure, X = Br), can be obtained from the reaction of cis-[Pt{C10H6(NMe2)-8-C,N}2] with R2SnX2(R = Me, Ph; X = BR, Cl) in CH2Cl2-MeOH; in nonprotic sol