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Crystal Engineering and Organometallic Architecture.

Dario Braga, +2 more
- 14 May 1998 - 
- Vol. 98, Iss: 4, pp 1375-1406
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This article is published in Chemical Reviews.The article was published on 1998-05-14. It has received 1116 citations till now.

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A 3-D lanthanide coordination polymer constructed from biphenyl-2,2′,6,6′-tetracarboxylic acid: synthesis of a trinodal (3,4,5)-connected topology and luminescence

TL;DR: A 3D lanthanide coordination polymer, [La2(bta)1.5(H2O)4·2H 2O] n (1) (H4bta = biphenyl-2,2′,6,6′-tetracarboxylic acid), has been hydrothermally synthesized and structurally characterized as an unprecedented trinodal (3,4,5)-connected (42.6).(44.62)
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The role of π-π stacking and hydrogen-bonding interactions in the assembly of a series of isostructural group IIB coordination compounds.

TL;DR: The syntheses, crystal structures and theoretical calculations of six group IIB coordination compounds containing a 2-{(2-methoxyphenyl)imino]methyl}phenol ligand are described to provide further insight into the role of π-stacking and hydrogen bonding in metallosupramolecular assembly.
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Self-Assembly of Ion-Pair Complexes

TL;DR: In this article, solid-state structures of cobalt(II) complexes of 4-methylumbelliferone-8-methyleneiminodiacetic acid (H3muia), also named Calcein Blue, are presented.
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3D network Mn-glutarate compound with Mn–O–Mn and Mn–O–C–O–Mn connectivity ☆

TL;DR: The reaction of MnCl2 and glutaric acid in aqueous solution affords a new 3D Mn-glutarate with an empirical formula of Mn3(H2O)[CO2(CH2)3CO2]3 (1) as discussed by the authors.
References
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Journal ArticleDOI

The Protein Data Bank: a computer-based archival file for macromolecular structures.

TL;DR: The Protein Data Bank is a computer-based archival file for macromolecular structures that stores in a uniform format atomic co-ordinates and partial bond connectivities, as derived from crystallographic studies.
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Patterns in Hydrogen Bonding: Functionality and Graph Set Analysis in Crystals

TL;DR: In this article, a review of the most promising systematic approaches to resolving this enigma was initially developed by the late M. C. Etter, who applied graph theory to recognize, and then utilize, patterns of hydrogen bonding for the understanding and design of molecular crystals.
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Supramolecular Synthons in Crystal Engineering—A New Organic Synthesis

TL;DR: In this article, the authors show that crystal engineering is a new organic synthesis, and that rather than being only nominally relevant to organic chemistry, this subject is well within the mainstream, being surprisingly similar to traditional organic synthesis in concept.
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Perspectives in Supramolecular Chemistry—From Molecular Recognition towards Molecular Information Processing and Self‐Organization

TL;DR: In this article, the authors proposed a self-assembly approach for the generation of a well-defined supramolecular architecture by self-assembling from their components under a given set of conditions.
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