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Crystal Engineering and Organometallic Architecture.

Dario Braga, +2 more
- 14 May 1998 - 
- Vol. 98, Iss: 4, pp 1375-1406
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This article is published in Chemical Reviews.The article was published on 1998-05-14. It has received 1116 citations till now.

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Synthesis and structural analysis of dehydrophenylalanine cyclophanes

TL;DR: The syntheses and structures of three cyclophanes containing two (Z)-dehydrophenylalanine residues are reported; the length of the tethers between the two amino acid residues is easily altered and changing this parameter has a significant effect on the solid state structures of the cyclophane.
Journal ArticleDOI

Syntheses of chromium tricarbonyl organometals of 1-methyl-naphthalene and different polycyclic aromatic hydrocarbons, characterisation of the (C11H10)Cr(CO)3 isomers and the crystal structure of the [(η6-5,6,7,8,9,10-C11H10)Cr(CO)3] complex

TL;DR: In this paper, the synthesis of organometal complexes from chromium hexacarbonyl with 1-methyl-naphthalene ligand is reported, with the metal carbonyl moiety attached to the benzenic arene ligand.
Journal ArticleDOI

Anion-Anion Interactions in Aerogen-Bonded Complexes. Influence of Solvent Environment.

TL;DR: In this paper, the question of whether a stable anion can engage in a stable complex with another anion: F−, Cl−, or CN− was investigated, and it was shown that the latter approach the central Ae atom from above the molecular plane, along its C5 axis.
Journal ArticleDOI

Stacking of cyclopentadienyl organometallic sandwich and half-sandwich compounds. Strong interactions of sandwiches at large offsets

TL;DR: Stacking interactions of organometallic sandwich and half-sandwich compounds with cyclopentadienyl (Cp) were studied by searching and observing the crystal structures in the Cambridge Structural Database and performing density functional calculations as mentioned in this paper.
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Heteropolynuclear Sodium(I) Lead(II) Complex: Crystal and Molecular Structure of a Novel 3-D Polymer, [(en)Pb(μ3-ONO)2Na(μ3-ONO)2Na(μ-O2ClO2)Na]n

TL;DR: A 3D polymeric heteropolynuclear sodium(I) lead(II) complex containing different ligands, [NaPb(ClO4)(en)(NO2)2] was synthesized and characterized by elemental analysis and IR, and 1H-, 13C-, and 207Pb-NMR spectroscopy as discussed by the authors.
References
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The Protein Data Bank: a computer-based archival file for macromolecular structures.

TL;DR: The Protein Data Bank is a computer-based archival file for macromolecular structures that stores in a uniform format atomic co-ordinates and partial bond connectivities, as derived from crystallographic studies.
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Patterns in Hydrogen Bonding: Functionality and Graph Set Analysis in Crystals

TL;DR: In this article, a review of the most promising systematic approaches to resolving this enigma was initially developed by the late M. C. Etter, who applied graph theory to recognize, and then utilize, patterns of hydrogen bonding for the understanding and design of molecular crystals.
Journal ArticleDOI

Supramolecular Synthons in Crystal Engineering—A New Organic Synthesis

TL;DR: In this article, the authors show that crystal engineering is a new organic synthesis, and that rather than being only nominally relevant to organic chemistry, this subject is well within the mainstream, being surprisingly similar to traditional organic synthesis in concept.
Journal ArticleDOI

Perspectives in Supramolecular Chemistry—From Molecular Recognition towards Molecular Information Processing and Self‐Organization

TL;DR: In this article, the authors proposed a self-assembly approach for the generation of a well-defined supramolecular architecture by self-assembling from their components under a given set of conditions.
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