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Dielectric properties of Na1-xKxNbO3 in orthorhombic phase

TLDR
In this paper, the authors measured the dielectric constant, loss tangent, and conductivity of ceramic Na1−xKxNbO3 (x = 0, 0.2 and 0.5) samples using XRD and SEM.
Abstract
Pellets of ceramic Na1−xKxNbO3 (x = 0, 0.2 and 0.5), were prepared by conventional solid-state reaction method. Prepared samples were characterized using XRD and SEM. The frequency and temperature variation of dielectric constant, loss tangent and dielectric conductivity of prepared samples were measured in the frequency range from 10 KHz-1 MHz, and in the temperature range from 50–250°C for x = 0.2 and 0.5, and between 50 and 480°C for x = 0 compositions. It was observed that the dielectric constant and loss tangent decrease, and conductivity increases with increasing frequency. Near the transition temperature the material shows anomalous behaviour for the observed properties, and the peaks of dielectric constant and loss tangent were observed shifting towards lower temperature with increasing frequency.

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Effect of Calcination Conditions and Excess Alkali Carbonate on the Phase Formation and Particle Morphology of Na0.5K0.5NbO3 Powders

TL;DR: In this article, an orthorhombic XRD pattern was obtained after calcination at 900°C for 6 hours, and cuboid cuboid particles were formed for non-excess powders and also for powders prepared with 1 and 3 mol% excess alkali carbonates.
Journal ArticleDOI

Sol-gel processing of lead-free (Na,K)NbO3 ferroelectric films

TL;DR: In this article, lead-free (Na,K) NbO3 ferroelectric films with orthorhombic perovskite structure were obtained by pyrolyzing at 400°C and annealing at 800-900°C.
Journal ArticleDOI

An investigation of (Na0.5K0.5)NbO3–CaTiO3 based lead-free ceramics and surface acoustic wave devices

TL;DR: In this paper, the results show that the addition of CaTiO3 is very effective in preventing the deliquescence and in improving the electric properties of (Na 0.5K0.5)NbO3 ceramics.
Journal ArticleDOI

Broadband dielectric response and grain-size effect in K0.5Na0.5NbO3 ceramics

TL;DR: In this article, the authors measured the dielectric spectra of two K.5Na0.5NbO3 ceramics with different grain sizes (10 and 0.5μm) in a broad temperature range.
Journal ArticleDOI

The effects of sintering temperature on the properties of (Na0.5K0.5)NbO3-CaTiO3 based lead-free ceramics

TL;DR: In this paper, the authors characterized the dielectric, piezoelectric and ferroelectric properties of NKN-0.5%CT ceramics by X-ray diffraction analysis and scanning electron microscopy, and showed that the increase of the sintering temperature is very effective in improving the density and electric properties.
References
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Journal ArticleDOI

Crystal stability and the theory of ferroelectricity

W. Cochran
- 01 Oct 1960 - 
TL;DR: In this article, it is shown that the parameters which determine the lattice vibrations of a diatomic ionic crystal may be chosen in such a way that the crystal will exhibit ferroelectric properties, and that anti-ferroelectric transitions may be regarded as the result of an instability of the crystal for a certain normal mode of vibration.
Journal ArticleDOI

Piezoelectric and Dielectric Properties of Ceramics in the System Potassium—Sodium Niobate

TL;DR: In this article, high radial coupling coefficients were observed for compositions having up to 50 mole % sodium niobate additions to potassium Niobate, and the activity diminishes with additional sodium Niobates content and disappears beyond about 98 mole % additions.
Journal ArticleDOI

Hot Pressing of Potassium‐Sodium Niobates

TL;DR: In this article, the authors applied the rate equation of Murray, Live, and Williams for hot-pressing ceramics to obtain a fine microstructure and improved piezoelectric activity.
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