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Effect of surface roughness on optical heating of metals

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TLDR
In this paper, a combination of ellipsometric and optical scattering measurements is used to derive a simplified parametrisation which can be used to obtain the absorption of light from random rough metal surfaces, as prepared through conventional grinding and polishing techniques.
Abstract
Heating by absorption of light is a commonly used technique to ensure a fast temperature increase of metallic samples. The rate of heating when using optical heating depends critically on the absorption of light by a sample. Here, the reflection and scattering of light from UV to IR by surfaces with different roughness of iron-based alloy samples (Fe, 1 wt-% Cr) is investigated. A combination of ellipsometric and optical scattering measurements is used to derive a simplified parametrisation which can be used to obtain the absorption of light from random rough metal surfaces, as prepared through conventional grinding and polishing techniques. By modelling the ellipsometric data of the flattest sample, the pseudodielectric function of the base material is derived. Describing an increased roughness by a Maxwell-Garnett model does not yield a reflectivity which follows the experimentally observed sum of scattered and reflected intensities. Therefore, a simple approach is introduced, based on multiple reflections, where the number of reflections depends on the surface roughness. This approach describes the data well, and is subsequently used to estimate the fraction of absorbed energy. Using numerical modelling, the effect on the heating rate is investigated. A numerical example is analysed, which shows that slight changes in roughness may result in big differences of the energy input into a metallic sample, with consequences on the achieved temperatures. Though the model oversimplifies reality, it provides a physically intuitive approach to estimate trends.

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Citations
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Journal ArticleDOI

Effect of surface roughness on the ultrashort pulsed laser ablation fluence threshold of zinc and steel

TL;DR: In this paper, the single and multiple pulse laser ablation threshold of zinc and steel at picosecond laser pulse duration is studied as a function of initial surface roughness at laser wavelengths of 515 and 1030 nm.
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Grain boundary oxidation in iron-based alloys, investigated by 18O enriched water vapour – The effect of mixed oxides in binary and ternary Fe–{Al, Cr, Mn, Si} systems

TL;DR: In this article, the internal oxidation behavior along grain boundaries and inside ferrite grains was analyzed by LOM, SEM and ToF-SIMS, revealing that oxygen transport within ferrite grain is significantly lower than reported from literature.
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A comprehensive study of infrared reflectivity of poly(3,4-ethylenedioxythiophene) model layers with different morphologies and conductivities

TL;DR: In this paper, a series of electropolymerized poly (3,4-ethylenedioxythiophene) (PEDOT) layers were studied in their doped and dedoped states and correlated to their morphology and electronic conductivity properties.
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Modelling and experiment of selective oxidation and nitridation of binary model alloys at 700 degrees C - The systems Fe, 1 wt.%{Al, Cr, Mn, Si}

TL;DR: In this paper, selective oxidation experiments of binary iron alloys, containing 1 wt.%Al, Cr, Mn or Si were performed using hydrogen/water vapour mixtures adjusting low oxygen activities at the surface that hinder the formation of an outer oxide scale.
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Sequential growth of zinc oxide nanorod arrays at room temperature via a corrosion process: application in visible light photocatalysis.

TL;DR: Nanorod arrays of the wide-band-gap semiconductor zinc oxide have been shown to act as photocatalysts for the aerobic photo-oxidation of organic dye Methyl Orange under illumination with red light, which is normally accessible only to narrow-band semiconductors.
References
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Journal ArticleDOI

Investigation of effective-medium models of microscopic surface roughness by spectroscopic ellipsometry

TL;DR: In this article, Bruggeman and Maxwell Garnett showed that the dielectric properties of microscopically rough layers of thicknesses 100-500 \AA{}A are accurately modeled in the effective medium approximation.
Journal ArticleDOI

Evaluation of ultra-high temperature ceramics foraeropropulsion use

TL;DR: In this article, the authors examined three UHTC materials under conditions more representative of a propulsion environment, i.e., higher oxygen partial pressure and total pressure, and showed that these materials offer a good combination of properties that make them candidates for airframe leading edges on sharp-bodied reentry vehicles.
Journal ArticleDOI

A silicon/iron-disilicide light-emitting diode operating at a wavelength of 1.5 μm

TL;DR: In this article, a light-emitting device operating at 1.5 µm was presented that incorporates β-FeSi2 into a conventional silicon bipolar junction, which demonstrates the potential of this material as an important candidate for a silicon-based optoelectronic technology.
Journal ArticleDOI

Temperature rise induced by a laser beam

M. Lax
TL;DR: In this paper, the spatial distribution of the temperature rise induced by a laser beam absorbed in a solid is reduced to a one-dimensional integral which is evaluated numerically, and a closed-form expression in terms of tabulated functions is obtained for the maximum temperature rise.
Book

Nonlinear ordinary differential equations : an introduction for scientists and engineers

TL;DR: In this paper, the existence and uniqueness theorems of second-order differential equations in the phase plane have been studied and the existence of periodic solutions has been shown to exist.
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