Journal ArticleDOI
Electrochemical Synthesis of β-Ketosulfones from Switchable Starting Materials.
Issa Yavari,Sina Shaabanzadeh +1 more
TLDR
An environmentally friendly characteristic of this reaction is that it uses electricity as a valuable energy source for electrochemical synthesis of β-ketosulfones, which is more convenient and practical compared to previous approaches.About:
This article is published in Organic Letters.The article was published on 2020-01-07. It has received 55 citations till now. The article focuses on the topics: Energy source & Aryl.read more
Citations
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Photons or Electrons? A Critical Comparison of Electrochemistry and Photoredox Catalysis for Organic Synthesis.
TL;DR: In this paper, the authors highlight the differences and similarities between electrochemistry and photoredox catalysis by comparing their underlying physical chemistry principles and describing their impact on electrochemical and photochemical methods.
Journal ArticleDOI
Synthesis and applications of sodium sulfinates (RSO2Na): a powerful building block for the synthesis of organosulfur compounds
TL;DR: Sodium sulfinates have been used extensively in the preparation of organosulfur compounds through S-S, N−S, and C-S bond-forming reactions as discussed by the authors.
Journal ArticleDOI
Chemistry of electrochemical oxidative reactions of sulfinate salts
TL;DR: In this article, a review of recent achievements in the development of electrochemical transformations of sulfinate reagents has been presented and discussed, as well as insights into the reaction mechanism.
References
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Journal ArticleDOI
Visible Light Photoredox Catalysis with Transition Metal Complexes: Applications in Organic Synthesis
TL;DR: The conversion of these bench stable, benign catalysts to redox-active species upon irradiation with simple household lightbulbs represents a remarkably chemoselective trigger to induce unique and valuable catalytic processes.
Journal ArticleDOI
Redox catalysis in organic electrosynthesis: basic principles and recent developments.
Robert Francke,R. Daniel Little +1 more
TL;DR: Progress is described in the field of electroorganic synthesis, a process that can be accomplished more efficiently and purposefully using modern computational tools, and summarizes recent advances.
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Modern Strategies in Electroorganic Synthesis
TL;DR: Electrochemical Properties of scCO2 2285 5.1.
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Data-mining for sulfur and fluorine: an evaluation of pharmaceuticals to reveal opportunities for drug design and discovery.
TL;DR: The evolution and structural diversity of sulfur and the popular integration of fluorine into drugs introduced over the past 50 years are evaluated and promoted to promote innovative insights into drug development.
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Electrochemical strategies for C-H functionalization and C-N bond formation.
TL;DR: This review provides an overview on the use of anodic electrochemical methods for expediting the development of carbon-hydrogen functionalization and carbon-nitrogen bond formation strategies and aims to provide inspiration for future synthetic applications in the field of electrosynthesis.