Journal ArticleDOI
Enhanced selectivity of CO2 over CH4 in sulphonate-, carboxylate- and iodo-functionalized UiO-66 frameworks
Shyam Biswas,Jian Zhang,Li Zhibao,Ying-Ya Liu,Maciej Grzywa,Lixian Sun,Lixian Sun,Dirk Volkmer,Pascal Van Der Voort +8 more
TLDR
Three new functionalized UiO-66-X frameworks incorporating BDC-X (BDC: 1,4-benzenedicarboxylate) linkers have been synthesized by a solvothermal method using conventional electric heating.Abstract:
Three new functionalized UiO-66-X (X = –SO3H, 1; –CO2H, 2; –I; 3) frameworks incorporating BDC-X (BDC: 1,4-benzenedicarboxylate) linkers have been synthesized by a solvothermal method using conventional electric heating. The as-synthesized (AS) as well as the thermally activated compounds were characterized by X-ray powder diffraction (XRPD), diffuse reflectance infrared Fourier transform (DRIFT) spectroscopy, thermogravimetric (TG), and elemental analysis. The occluded H2BDC-X molecules can be removed by exchange with polar solvent molecules followed by thermal treatment under vacuum leading to the empty-pore forms of the title compounds. Thermogravimetric analysis (TGA) and temperature-dependent XRPD (TDXRPD) experiments indicate that 1, 2 and 3 are stable up to 260, 340 and 360 °C, respectively. The compounds maintain their structural integrity in water, acetic acid and 1 M HCl, as verified by XRPD analysis of the samples recovered after suspending them in the respective liquids. As confirmed by N2, CO2 and CH4 sorption analyses, all of the thermally activated compounds exhibit significant microporosity (SLangmuir: 769–842 m2 g−1), which are comparable to that of the parent UiO-66 compound. Compared to the unfunctionalized UiO-66 compound, all the three functionalized solids possess higher ideal selectivity in adsorption of CO2 over CH4 at 33 °C.read more
Citations
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Journal ArticleDOI
Water stability and adsorption in metal-organic frameworks.
Journal ArticleDOI
Flexible metal–organic frameworks
Andreas Schneemann,Volodymyr Bon,Inke Schwedler,Irena Senkovska,Stefan Kaskel,Roland A. Fischer +5 more
TL;DR: Advances in flexible and functional metal-organic frameworks (MOFs), also called soft porous crystals, are reviewed by covering the literature of the five years period 2009-2013 with reference to the early pertinent work since the late 1990s.
Journal ArticleDOI
Defect Engineering: Tuning the Porosity and Composition of the Metal–Organic Framework UiO-66 via Modulated Synthesis
Greig C. Shearer,Sachin Chavan,Silvia Bordiga,Silvia Bordiga,Stian Svelle,Unni Olsbye,Karl Petter Lillerud +6 more
TL;DR: In this article, the defect chemistry of UiO-66 when synthesized in the presence of monocarboxylic acid modulators under the most commonly employed conditions is investigated.
Journal ArticleDOI
Brønsted acidity in metal-organic frameworks.
Journal ArticleDOI
Superacidity in sulfated metal-organic framework-808.
Juncong Jiang,Felipe Gándara,Felipe Gándara,Yue-Biao Zhang,Yue-Biao Zhang,Kyungsu Na,Kyungsu Na,Omar M. Yaghi,Omar M. Yaghi,Omar M. Yaghi,Walter G. Klemperer +10 more
TL;DR: This material has a Hammett acidity function H0 ≤ -14.5 and is thus identified as a superacid, providing the first evidence for superacidity in MOFs, attributed to the presence of zirconium-bound sulfate groups structurally characterized using single-crystal X-ray diffraction analysis.
References
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Omar M. Yaghi,Michael O'Keeffe,Nathan W. Ockwig,Hee K. Chae,Hee K. Chae,Mohamed Eddaoudi,Jaheon Kim +6 more
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Metal–organic framework materials as catalysts
JeongYong Lee,Omar K. Farha,John M. Roberts,Karl A. Scheidt,SonBinh T. Nguyen,Joseph T. Hupp +5 more
TL;DR: A critical review of the emerging field of MOF-based catalysis is presented and examples of catalysis by homogeneous catalysts incorporated as framework struts or cavity modifiers are presented.
Journal ArticleDOI
Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
Journal ArticleDOI
Carbon Dioxide Capture in Metal–Organic Frameworks
Kenji Sumida,David L. Rogow,Jarad A. Mason,Thomas M. McDonald,Eric D. Bloch,Zoey R. Herm,Tae-Hyun Bae,Jeffrey R. Long +7 more
TL;DR: Kenji Sumida, David L. Rogow, Jarad A. Mason, Thomas M. McDonald, Eric D. Bloch, Zoey R. Herm, Tae-Hyun Bae, Jeffrey R. Long