scispace - formally typeset
Open AccessJournal ArticleDOI

Enhanced two-photon absorption with novel octupolar propeller-shaped fluorophores derived from triphenylamine.

Laurent Porrès, +6 more
- 08 Jan 2004 - 
- Vol. 6, Iss: 1, pp 47-50
TLDR
Novel octupolar fluorophores derived from the symmetrical functionalization of a triphenylamine core with strong acceptor peripheral groups via phenylene-ethynylene linkers have been synthesized and shown to exhibit high fluorescence quantum yields, very large TPA cross-sections in the red-NIR region, and suitable photostability.
About: 
This article is published in Organic Letters.The article was published on 2004-01-08 and is currently open access. It has received 242 citations till now. The article focuses on the topics: Triphenylamine.

read more

Figures
Citations
More filters
Journal ArticleDOI

Multiphoton Absorbing Materials : Molecular Designs, Characterizations, and Applications

Guang S. He, +3 more
- 25 Mar 2008 - 
TL;DR: Nonlinear Optical Characterizations of Multiphoton Active Materials 1282 5.2.1.
Journal Article

Two-photon polymerization initiators for three-dimensional optical data storage and microfabrication

Brian H. Cumpoton, +15 more
- 01 Jan 2003 - 
TL;DR: In this article, a class of π;-conjugated compounds that exhibit large δ (as high as 1, 250 × 10−50 cm4 s per photon) and enhanced two-photon sensitivity relative to ultraviolet initiators were developed and used to demonstrate a scheme for three-dimensional data storage which permits fluorescent and refractive read-out, and the fabrication of 3D micro-optical and micromechanical structures, including photonic-bandgap-type structures.
Journal ArticleDOI

Two-photon absorption and the design of two-photon dyes.

Miłosz Pawlicki, +3 more
- 20 Apr 2009 - 
TL;DR: The theory of two-photon absorption is introduced, the wide range of potential applications is surveyed, and emerging structure-property correlations that can serve as guidelines for the development of efficient two-Photon dyes are highlighted.
Journal ArticleDOI

Synthetic Methods for Compounds Having CF3–S Units on Carbon by Trifluoromethylation, Trifluoromethylthiolation, Triflylation, and Related Reactions

Xiu-Hua Xu, +2 more
- 28 Jan 2015 - 
Journal ArticleDOI

Enhanced two-photon absorption of organic chromophores: theoretical and experimental assessments ∗∗

Francesca Terenziani, +4 more
- 17 Dec 2008 - 
TL;DR: In this paper, a review of experimental and theoretical methodologies allowing detailed investigation and analysis of two-photon absorption properties of organic chromophores is presented, focusing on symmetric and asymmetric donor/acceptor substitution and branching.
References
More filters
Journal ArticleDOI

Two-Photon Laser Scanning Fluorescence Microscopy

Winfried Denk, +2 more
- 06 Apr 1990 - 
TL;DR: The fluorescence emission increased quadratically with the excitation intensity so that fluorescence and photo-bleaching were confined to the vicinity of the focal plane as expected for cooperative two-photon excitation.
Journal ArticleDOI

A survey of Hammett substituent constants and resonance and field parameters

Corwin Hansch, +2 more
- 01 Mar 1991 - 
TL;DR: The Hammett equation has been widely used for the study and interpretation of organic reactions and their mechanisms as mentioned in this paper, and it is astonishing that u constants, obtained simply from the ionization of organic acids in solution, can frequently predict successfully equilibrium and rate constants for a variety of families of reactions in solution.
Journal ArticleDOI

Finer features for functional microdevices

Satoshi Kawata, +3 more
- 16 Aug 2001 - 
TL;DR: Micromachines can be created with higher resolution using two-photon absorption, and the results can be higher resolution than previously reported using single photon absorption techniques.
Journal ArticleDOI

Association of human papillomavirus types 16 and 18 E6 proteins with p53.

B A Werness, +2 more
- 06 Apr 1990 - 
TL;DR: This study shows that the E6 protein of HPV-16 is capable of binding to the cellular p53 protein, providing further evidence that the human papillomaviruses, the adenovirus type 5, and SV40 may effect similar cellular pathways in transformation.
Journal ArticleDOI

Water-Soluble Quantum Dots for Multiphoton Fluorescence Imaging in Vivo

Daniel R. Larson, +6 more
- 30 May 2003 - 
TL;DR: This work characterized water-soluble cadmium selenide–zinc sulfide quantum dots for multiphoton imaging in live animals and found no evidence of blinking (fluorescence intermittency) in solution on nanosecond to millisecond time scales.
Related Papers (5)

Design of Organic Molecules with Large Two-Photon Absorption Cross Sections

Marius A. Albota, +17 more
- 11 Sep 1998 - 

Structure−Property Relationships for Two-Photon Absorbing Chromophores: Bis-Donor Diphenylpolyene and Bis(styryl)benzene Derivatives

Mariacristina Rumi, +12 more
- 13 Sep 2000 - 

Highly Active Two-Photon Dyes: Design, Synthesis, and Characterization toward Application

Bruce A. Reinhardt, +8 more
- 01 Jul 1998 - 

Measurement of two-photon excitation cross sections of molecular fluorophores with data from 690 to 1050 nm

Chris Xu, +1 more
- 01 Mar 1996 - 

Two-Photon Laser Scanning Fluorescence Microscopy

Winfried Denk, +2 more
- 06 Apr 1990 - 
Frequently Asked Questions (1)
Q1. What contributions have the authors mentioned in the paper "Enhanced two-photon absorption with novel octupolar propeller-shaped fluorophores derived from triphenylamine" ?

In this perspective, the authors have investigated a series of novel three-branched octupolar fluorophores with the aim of optimizing their TPEF cross-section ( σ2φ ) in the NIR region, as well as ensuring suitable photostability.