Journal ArticleDOI
Exciting new directions in the intersection of functionalized sol–gel materials with electrochemistry
TLDR
The implications of organically modified silica-based materials in electrochemical science is reviewed along with some selected recent trends in the field of functionalized and sol-gel silica electrochemistry as discussed by the authors.Abstract:
The implications of organically-modified silica-based materials in electrochemical science is reviewed along with some selected recent trends in the field of functionalized and sol–gel silica electrochemistry. These recent trends include the electro-assisted generation of organosilica films on solid electrode surfaces, the preparation and applications of sol–gel derived composite (carbon, gold, nanotubes) electrodes, the electrochemical characterisation of mass transfer reactions in porous functionalized silicas, solid-state electrochemistry and gas sensors involving sol–gel materials, imprinted functionalized silica, and the electrochemical characterisation and applications of ordered mesoporous organosilicas.read more
Citations
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Damascene copper electroplating for chip interconnections
TL;DR: Damascene copper electroplating for on-chip interconnections, a process that was conceived and developed in the early 1990s, makes it possible to fill submicron trenches and vias with copper without creating a void or a seam and has thus proven superior to other technologies of copper deposition as discussed by the authors.
Journal ArticleDOI
Mesoporous organosilica adsorbents: nanoengineered materials for removal of organic and inorganic pollutants
Alain Walcarius,Louis Mercier +1 more
TL;DR: A review with ca. 400 references dealing with the use of mesoporous silica and organically modified silica-based materials for removal of inorganic and organic pollutants from aqueous solutions is provided in this article.
Journal ArticleDOI
Mesoporous materials and electrochemistry
TL;DR: This review will cover the whole field of the intersection between electrochemistry and ordered mesoporous materials, which includes the generation of mesostructured solids by electro-assisted deposition using appropriate templates and the application of these novel materials for electrochemical purposes.
Journal ArticleDOI
The Sol–Gel Route to Advanced Silica-Based Materials and Recent Applications
Rosaria Ciriminna,Alexandra Fidalgo,Valerica Pandarus,François Béland,Laura M. Ilharco,Mario Pagliaro +5 more
TL;DR: Applications Rosaria Ciriminna,† Alexandra Fidalgo,‡ Valerica Pandarus, Franco̧is Beĺand, Laura M. Ilharco,*,‡ and Mario Pagliaro*.
Journal ArticleDOI
Electrochemically assisted self-assembly of mesoporous silica thin films.
TL;DR: Electrochemistry is likely to induce self-assembly of surfactant-templated (organo)silica thin films on various conducting supports, homogeneously over wide areas, opening the way to electrochemically driven nanolithography for designing complex patterns of widely accessible mesostructured materials.
References
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Journal ArticleDOI
Ordered mesoporous molecular sieves synthesized by a liquid-crystal template mechanism
TL;DR: In this paper, the synthesis of mesoporous inorganic solids from calcination of aluminosilicate gels in the presence of surfactants is described, in which the silicate material forms inorganic walls between ordered surfactant micelles.
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A new family of mesoporous molecular sieves prepared with liquid crystal templates
Jeffrey S. Beck,James C. Vartuli,Wieslaw J. Roth,M. E. Leonowicz,Charles T. Kresge,Kirk D. Schmitt,Cynthia Ting-Wah Chu,David H. Olson,E. W. Sheppard,S. B. McCullen,J. B. Higgins,J.L. Schlenker +11 more
TL;DR: In this paper, the synthesis, characterization, and proposed mechanism of formation of a new family of silicatelaluminosilicate mesoporous molecular sieves designated as M41S is described.
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Chemical strategies to design textured materials: from microporous and mesoporous oxides to nanonetworks and hierarchical structures.
Abstract: 3.
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Functionalized Monolayers on Ordered Mesoporous Supports
Xiangdong Feng,Glen E. Fryxell,Glen E. Fryxell,Li-Qiong Wang,Li-Qiong Wang,A. Y. Kim,A. Y. Kim,Jun Liu,Jun Liu,Kenneth M. Kemner,Kenneth M. Kemner +10 more
TL;DR: The surface modification scheme reported in this paper enables rational design of the surface properties of tailored porous materials and may lead to the synthesis of more sophisticated functionalized composites for environmental and industrial applications.
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Hybrid Inorganic–Organic Mesoporous Silicates—Nanoscopic Reactors Coming of Age
TL;DR: A review of methods of preparing hybrid inorganic-organic mesoporous silicates with uniform channel structures, as well as some of their applications can be found in this article, where both reactive and passive organic groups can be incorporated in the porous solids by grafting methods or by co-condensation under surfactant control.