Ferroelectricity from iron valence ordering in the charge-frustrated system LuFe2O4.

TLDR: Experimental evidence for ferroelectricity arising from electron correlations in the triangular mixed valence oxide, LuFe2O4 is reported, and resonant X-ray scattering measurements are used to determine the ordering of the Fe2+ and Fe3+ ions.

Abstract: Ferroelectric materials have a spontaneous electric polarization and are widely used in electronic devices including memories. Conventional ferroelectricity arises from ionic displacement, but an alternative mechanism has been proposed based on ordered electrons. Evidence for the latter behaviour has now been found in a mixed valence oxide. This type of ferroelectricity may offer potential for devices with enhanced controllability. Ferroelectric materials are widely used in modern electric devices such as memory elements, filtering devices and high-performance insulators. Ferroelectric crystals have a spontaneous electric polarization arising from the coherent arrangement of electric dipoles1 (specifically, a polar displacement of anions and cations). First-principles calculations2,3 and electron density analysis4 of ferroelectric materials have revealed that the covalent bond between the anions and cations, or the orbital hybridization of electrons on both ions, plays a key role in establishing the dipolar arrangement. However, an alternative model—electronic ferroelectricity5—has been proposed in which the electric dipole depends on electron correlations, rather than the covalency. This would offer the attractive possibility of ferroelectric materials that could be controlled by the charge, spin and orbital degrees of freedom of the electron. Here we report experimental evidence for ferroelectricity arising from electron correlations in the triangular mixed valence oxide, LuFe2O4. Using resonant X-ray scattering measurements, we determine the ordering of the Fe2+ and Fe3+ ions. They form a superstructure that supports an electric polarization consisting of distributed electrons of polar symmetry. The polar ordering arises from the repulsive property of electrons—electron correlations—acting on a frustrated geometry.