Journal ArticleDOI
Flexible (Breathing) Interpenetrated Metal−Organic Frameworks for CO2 Separation Applications
Praveen K. Thallapally,Jian Tian,Motkuri Radha Kishan,Carlos Fernandez,Scott J. Dalgarno,Peter B. McGrail,John E. Warren,Jerry L. Atwood +7 more
TLDR
A breathing 2-fold interpenetrated microporous metal-organic framework was synthesized with a flexible tetrahedral organic linker and Zn( 2) clusters that sorb CO(2) preferably over N (2) and H(2).Abstract:
A breathing 2-fold interpenetrated microporous metal-organic framework was synthesized with a flexible tetrahedral organic linker and Zn(2) clusters that sorb CO(2) preferably over N(2) and H(2).read more
Citations
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Journal ArticleDOI
Selective gas adsorption and separation in metal–organic frameworks
TL;DR: This critical review starts with a brief introduction to gas separation and purification based on selective adsorption, followed by a review of gas selective adsorbents in rigid and flexible MOFs, and primary relationships between adsorptive properties and framework features are analyzed.
Journal ArticleDOI
Metal–Organic Frameworks for Separations
Journal ArticleDOI
Carbon Dioxide Capture in Metal–Organic Frameworks
Kenji Sumida,David L. Rogow,Jarad A. Mason,Thomas M. McDonald,Eric D. Bloch,Zoey R. Herm,Tae-Hyun Bae,Jeffrey R. Long +7 more
TL;DR: Kenji Sumida, David L. Rogow, Jarad A. Mason, Thomas M. McDonald, Eric D. Bloch, Zoey R. Herm, Tae-Hyun Bae, Jeffrey R. Long
Journal ArticleDOI
Carbon Dioxide Capture: Prospects for New Materials
TL;DR: The most recent developments and emerging concepts in CO(2) separations by solvent absorption, chemical and physical adsorption, and membranes, amongst others, will be discussed, with particular attention on progress in the burgeoning field of metal-organic frameworks.
References
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Journal ArticleDOI
High-throughput synthesis of zeolitic imidazolate frameworks and application to CO2 capture.
Rahul Banerjee,Anh Phan,Bo Wang,Carolyn B. Knobler,Hiroyasu Furukawa,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Members of a selection of zeolitic imidazolate frameworks have high thermal stability and chemical stability in refluxing organic and aqueous media, and they exhibit unusual selectivity for CO2 capture from CO2/CO mixtures and extraordinary capacity for storing CO2.
PatentDOI
Metal-organic frameworks with exceptionally high capacity for storage of carbon dioxide at room-temperature
Omar M. Yaghi,Andrew R. Millward +1 more
TL;DR: A carbon dioxide storage system includes a container and a conduit attached to the container for introducing or removing a carbon dioxide-containing composition from the container as mentioned in this paper, which is positioned within the container.
Journal ArticleDOI
Reticular Chemistry: Occurrence and Taxonomy of Nets and Grammar for the Design of Frameworks
TL;DR: The structures of all 1127 three-periodic extended metal-organic frameworks reported in the Cambridge Structure Database have been analyzed, and their underlying topology has been determined, leading to a system of classification "taxonomy" for interpreting and rationalizing known MOF structures.
Journal ArticleDOI
Dramatic tuning of carbon dioxide uptake via metal substitution in a coordination polymer with cylindrical pores.
TL;DR: This study demonstrates that physisorptive materials can achieve affinities and capacities competitive with amine sorbents while greatly reducing the energy cost associated with regeneration.
Journal ArticleDOI
Highly controlled acetylene accommodation in a metal–organic microporous material
Ryotaro Matsuda,Ryo Kitaura,Ryo Kitaura,Susumu Kitagawa,Yoshiki Kubota,Rodion V. Belosludov,Tatsuo C. Kobayashi,Hirotoshi Sakamoto,Takashi Chiba,Masaki Takata,Yoshiyuki Kawazoe,Yoshimi Mita +11 more
TL;DR: High levels of selective sorption of acetylene molecules as compared to a very similar molecule, carbon dioxide, onto the functionalized surface of a MOM are reported.