Journal ArticleDOI
Highly Active and Stable CeO2-Promoted CuCl2/Al2O3 Oxychlorination Catalysts Developed by Rational Design Using a Rate Diagram of the Catalytic Cycle
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In this paper, the steady state of the redox cycle is represented by a cross point of the reaction rates of the reduction and oxidation steps as a function of the Cu2+ in the rate diagram.Abstract:
In this study, we have developed a method to predict the steady-state rate and Cu oxidation state during ethylene oxychlorination from a reaction rate diagram of the individual steps involved in the catalytic oxychlorination cycle. The steady state of the redox cycle is represented by a cross point of the reaction rates of the reduction and oxidation steps as a function of the Cu2+ in the rate diagram. Transient kinetics of elementary reactions and steady-state kinetics of the overall catalytic cycle were investigated in an operando study using combined mass and UV–vis-NIR spectrophotometry. The catalytic consequence of the promoters was then evaluated in terms of reduction and oxidation activity as well as number of active sites, site activity, and the catalyst oxidation state at steady state. Results revealed that the neat CuCl2 catalysts operated at low Cu2+ at the steady-state conditions with stoichiometric feed composition, as a result of relatively low oxidation rate of Cu1+. As a consequence of a h...read more
Citations
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Journal ArticleDOI
Simultaneous NOx and Particulate Matter Removal from Diesel Exhaust by Hierarchical Fe-Doped Ce–Zr Oxide
Ying Cheng,Weiyu Song,Weiyu Song,Jian Liu,Huiling Zheng,Zhen Zhao,Chunming Xu,Yuechang Wei,Emiel J. M. Hensen +8 more
TL;DR: An optimized mixed Fe–Ce–Zr oxides material can effectively trap the model soot particles in its open macroporous structure and oxidize the soot below 400 °C while completely removing NO in the 285–420 °C range.
Journal ArticleDOI
Critical review of catalysis for ethylene oxychlorination
TL;DR: The key technology in vinyl chloride (VCM, the monomer of PVC, polyvinyl chloride) production to close the chlorine loop by consuming the HCl released from the former cr...
Journal ArticleDOI
Using inorganic dynamic porogens for preparing high-surface-area capacitive carbons with tailored micropores
TL;DR: In this paper, a new preparation method of capacitive carbons that can meet the abovementioned characteristics using an inorganic CuCl salt as a dynamic porogen and L-glutamic acid as a carbon precursor was reported.
Journal ArticleDOI
Understanding of potassium promoter effects on oxychlorination of ethylene by operando spatial-time resolved UV–vis–NIR spectrometry
TL;DR: In this paper, the effect of promoters on the oxychlorination reaction was investigated and the effects on the individual reduction and oxidation steps, as well as their consequences in steady state in terms of the active site number and the site activity.
Journal ArticleDOI
Cluster-Size-Dependent Interaction between Ethylene and CuCl2 Clusters Supported via γ-Alumina
Yanying Qi,Endre Fenes,Hongfei Ma,Yalan Wang,Kumar Ranjan Rout,Kumar Ranjan Rout,Terje Fuglerud,Marco Piccinini,De Chen +8 more
TL;DR: Alumina supported copper chloride serves as an industrial catalyst for ethylene oxychlorination, resulting from the high activity and selectivity as discussed by the authors, and a better understanding of the detailed active site is provided.
References
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Book
Encyclopedia of polymer science and engineering
TL;DR: In this paper, the authors describe a chain transfer characterisation of polymers charge-transfer complexes, charge transfer complexes and charge transfer complexes of charge transfer and charge-Transfer complexes.
Journal ArticleDOI
Spectroscopic evidence for the supply of reactive oxygen during CO oxidation catalyzed by gold supported on nanocrystalline CeO2.
TL;DR: Nanocrystalline CeO2 supplies reactive oxygen in the form of surface eta1 superoxide species and peroxide adspecies at the one-electron defect site to the supported active species of gold for the oxidation of CO.
Journal ArticleDOI
Alkali Doping in Heterogeneous Catalysis
TL;DR: It has been estimated that approximately 60% of all commercial chemicals are now obtained using processes involving heterogeneous catalysis as discussed by the authors, and over 90% of new large-scale plants employ heterogeneous catalysts.
Journal ArticleDOI
A combined in situ time-resolved UV–Vis, Raman and high-energy resolution X-ray absorption spectroscopy study on the deactivation behavior of Pt and Pt-Sn propane dehydrogenation catalysts under industrial reaction conditions
Ana Iglesias-Juez,Andrew M. Beale,Karin Maaijen,Tsu-Chien Weng,Pieter Glatzel,Bert M. Weckhuysen +5 more
TL;DR: In this article, the catalytic performances of Pt/Al2O3 and Pt-Sn/Al 2O3 catalysts for the dehydrogenation of propane through consecutive reaction-regeneration cycles have been studied under realistic reaction conditions.
Journal ArticleDOI
Combining operando techniques in one spectroscopic-reaction cell: New opportunities for elucidating the active site and related reaction mechanism in catalysis
Stan J. Tinnemans,J. Gerbrand Mesu,Kaisa Kervinen,Tom Visser,T. Alexander Nijhuis,Andrew M. Beale,Daphne E. Keller,Ad M. J. van der Eerden,Bert M. Weckhuysen +8 more
TL;DR: In this article, an overview of the different operando set-ups currently available for obtaining combined spectroscopic and catalytic information on catalytic systems is presented, where the crucial advantage of such multiple couplings is the fact that in principle, spectroscopy and catalyst data are obtained from the same catalyst system for which identical reaction conditions are guaranteed.