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Highly efficient thermal conductivity of polydimethylsiloxane composites via introducing “Line-Plane”-like hetero-structured fillers

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TLDR
In this article , graphite oxide and cetyltrimethylammonium bromide (CTAB) modified multi-walled carbon nanotubes (m-MWCNTs) are utilized to fabricate Line-Plane-like hetero-structured thermally conductive [email protected] fillers by electrostatic self-assembly.
Abstract
Graphite oxide (GO) and cetyltrimethylammonium bromide (CTAB) modified multi-walled carbon nanotubes (m-MWCNTs) are utilized to fabricate “Line-Plane”-like hetero-structured thermally conductive [email protected] fillers by electrostatic self-assembly, which are then introduced into polydimethylsiloxane (PDMS) to fabricate thermally conductive [email protected]/PDMS composites. When the mass ratio of GO to m-MWCNTs is 2:1, [email protected] fillers have optimal morphologies and thermal conductivity contribution. When the mass fraction of [email protected] is 20 wt%, the thermal conductivity coefficient (λ) of [email protected]/PDMS composites reaches 2.10 W/(m·K), 950% higher than that of pure PDMS (0.20 W/(m·K)), which is also superior to the λ of MWCNTs/PDMS (0.68 W/(m·K)), GO/PDMS (1.59 W/(m·K)) and (GO/MWCNTs)/PDMS (1.28 W/(m·K)) composites with the same amount of single or hybrid thermally conductive fillers. Meantime, the [email protected]/PDMS composites also present good thermal conduction stability (average λ after 15 heating-cooling cycles in the temperature of 21 to 100°C is 2.14 W/(m·K)) and thermal stability (heat resistance index is 249.3°C).

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Advances and mechanisms in polymer composites toward thermal conduction and electromagnetic wave absorption.

TL;DR: In this article , the authors provide references for the development of thermal conduction and EMW absorption integrated polymer composites, including integrating functional fillers with both thermally conductive and electromagnetic wave (EMW) absorption functions.
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Optimal particle distribution induced interfacial polarization in hollow double-shell composites for electromagnetic waves absorption performance.

TL;DR: In this article , the co-modification strategies of polydopamine coating and wet impregnation are chosen to construct CoS2 magnetic double-shell microspheres with phase component modulation to achieve the optimized performance.
Journal ArticleDOI

Templating strategies for 3D-structured thermally conductive composites: Recent advances and thermal energy applications

TL;DR: In this paper , the authors present a review of the recent advances in thermally conductive polymer composites based on self-templating, sacrificial templating (StemplA), foam-templating and template-directed chemical vapor deposition techniques.
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Creating thermal conductive pathways in polymer matrix by directional assembly of synergistic fillers assisted by electric fields

TL;DR: In this article , a strategy of creating thermal conductive pathways using micro-sized boron nitride and nano-sized alumina (Al 2 O 3 ) in polydimethylsiloxane (PDMS) matrix by the application of electric fields was demonstrated.
References
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Journal ArticleDOI

Simultaneous surface functionalization and reduction of graphene oxide with octadecylamine for electrically conductive polystyrene composites

TL;DR: In this article, a simple refluxing of GO with octadecylamine (ODA) without the use of any reducing agents was realized by simple surface functionalization and reduction of graphene oxide (GO).
Journal ArticleDOI

Electronic structure of graphite oxide and thermally reduced graphite oxide

TL;DR: In this paper, the electronic structure evolution from graphite oxide to thermally reduced graphite oxides was studied, where most functional groups were removed by thermal reduction as indicated by high resolution X-ray photoelectron spectroscopy.
Journal ArticleDOI

Janus (BNNS/ANF)-(AgNWs/ANF) thermal conductivity composite films with superior electromagnetic interference shielding and Joule heating performances

Yixin Han, +2 more
- 08 Feb 2022 - 
TL;DR: In this article , the authors proposed a thermal conductivity and electromagnetic interference shielding composite film with Janus structures using the "vacuum-assisted filtration and hot-pressing" method.
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Flexible multilayered MXene/thermoplastic polyurethane films with excellent electromagnetic interference shielding, thermal conductivity, and management performances

TL;DR: In this article, a flexible multilayered MXene/thermoplastic polyurethane films were prepared via a simple layer-by-layer spraying technique, which exhibited excellent EMI shielding, thermal conductivity, and management performances.
Journal ArticleDOI

Multifunctional Wearable Silver Nanowire Decorated Leather Nanocomposites for Joule Heating, Electromagnetic Interference Shielding and Piezoresistive Sensing.

TL;DR: In this paper , a multifunctional wearable silver nanowire decorated leather (AgNW/leather) nanocomposites with hierarchical structures for integrated visual Joule heating, electromagnetic interference (EMI) shielding and piezoresistive sensing are fabricated via the facile vacuum assisted filtration process.
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