Journal ArticleDOI
Homogeneously catalysed isomerisation of allylic alcohols to carbonyl compounds
Reads0
Chats0
TLDR
In this paper, a review of the mechanisms proposed for the isomerisation of allylic alcohols is given while some catalyst systems are singled out to discuss mechanistic research, such as the synthesis of enols and enolates, chiral carbonyl compounds and silyl substituted ketones.About:
This article is published in Journal of Organometallic Chemistry.The article was published on 2002-05-01. It has received 228 citations till now. The article focuses on the topics: Allylic rearrangement & Homogeneous catalysis.read more
Citations
More filters
Journal ArticleDOI
Photochemical Reactions as Key Steps in Organic Synthesis
TL;DR: Photochemical Electron-Transfer Reactions with a Catalytic Sensitizer 1068 6.1.1 Photochemical Extrusion of Small Molecules 1067 6.2.2 Photochemical Rearrangings 1061 4.4.3.
Journal ArticleDOI
Ruthenium-catalyzed reactions--a treasure trove of atom-economic transformations.
TL;DR: Ruthenium complexes catalyze a number of non-metathesis conversions and allow the rapid assembly of complex molecules with high selectivity and atom economy, and often exhibit unusual reactivity.
Journal ArticleDOI
Transposition of allylic alcohols into carbonyl compounds mediated by transition metal complexes.
References
More filters
BookDOI
Applied Homogeneous Catalysis with Organometallic Compounds
Boy Cornils,Wolfgang A. Herrmann +1 more
Book
The organometallic chemistry of the transition metals
TL;DR: General Properties of Organometallic Complexes The Metal-Carbon and Metal-Hydrogen Bonds Ligand Substitution Reactions Complexes of Pi-Bound Ligands Oxidative Addition and Reductive Elimination Insertion and Elimination Nucleophilic and Electrophilic Additions and Abstraction Homogeneous Catalysis Characterization of OO Compounds Carbenes, Metathesis and Polymerization The Activation of Small Molecules Clusters and the Metal-Metal Bond Applications to Organic Synthesis Oxidation and High-Oxidation-State