Journal ArticleDOI
Hybrid Organic−Inorganic Polyoxometalate Compounds: From Structural Diversity to Applications
TLDR
Polyoxometalates (POMs) are discrete anionic metaloxygen clusters which can be regarded as soluble oxide fragments which play a great role in various areas ranging from catalysis, medicine, electrochemistry, photochromism,5 to magnetism.Abstract:
Polyoxometalates (POMs) are discrete anionic metaloxygen clusters which can be regarded as soluble oxide fragments. They exhibit a great diversity of sizes, nuclearities, and shapes. They are built from the connection of {MOx} polyhedra, M being a d-block element in high oxidation state, usually VIV,V, MoVI, or WVI.1 While these species have been known for almost two centuries, they still attract much interest partly based on their large domains of applications. They play a great role in various areas ranging from catalysis,2 medicine,3 electrochemistry,4 photochromism,5 to magnetism.6 This palette of applications is intrinsically due to the combination of their added value properties (redox properties, large sizes, high negative charges, nucleophilicity...). Parallel to this domain, the organic-inorganic hybrids area has followed a similar expansion during the last 10 years. The concept of organic-inorganic hybrid materials * To whom correspondence should be addressed. E-mail: dolbecq@ chimie.uvsq.fr. Chem. Rev. 2010, 110, 6009–6048 6009read more
Citations
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Journal ArticleDOI
Metal–organic framework composites
Qi-Long Zhu,Qiang Xu +1 more
TL;DR: This review provides an overview of the significant advances in the development of diverse MOF composites reported till now with special emphases on the synergistic effects and applications of the composites.
Journal ArticleDOI
Recent advances in porous polyoxometalate-based metal-organic framework materials.
TL;DR: This review presents recent developments in porous POM-based MOF materials, including their classification, synthesis strategies, and applications, especially in the field of catalysis.
Journal ArticleDOI
Functionalization and post-functionalization: a step towards polyoxometalate-based materials
Anna Proust,Anna Proust,Benjamin Matt,Richard Villanneau,Geoffroy Guillemot,Pierre Gouzerh,Guillaume Izzet +6 more
TL;DR: This critical review focuses on the use of POM hybrids in selected fields of applications such as catalysis, energy conversion and molecular nanosciences and endeavor to discuss the impact of the covalent approach compared to the electrostatic one.
Journal ArticleDOI
Recent advances on polyoxometalate-based molecular and composite materials
Yu-Fei Song,Ryo Tsunashima +1 more
TL;DR: This critical review summarizes recent progress on POM-based molecular and composite materials, and particularly highlights the emerging areas that are closely related to surface, electronic, energy, environment, life science, etc.
Journal ArticleDOI
Engineering polyoxometalates with emergent properties.
TL;DR: It is shown that it is possible to construct complex chemical systems based upon polyoxometalates, manipulating the templating/self Templating rules to exhibit emergent processes from the molecular to the macroscopic scale.
References
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Journal ArticleDOI
A new arylimido derivative of polyoxometalate (Bu4N)2[Mo6O17(NAr)2] [Ar = 2,6-(CH3)2C6H3]: Synthesis, structure and physicochemical properties
TL;DR: In this article, a bifunctionalized arylimido derivative of hexamolybdate, (Bu4N)2[Mo6O17(NAr)2] [Ar = 2,6-(CH3)2C6H3] (1), was synthesized by a facile reaction of α-octamylbdate with 2.6-dimethylaniline using DCC as a dehydration agent.
Journal ArticleDOI
A new polynuclear Fe(III) cluster based on inorganic O-donor polyoxometalate and organic N-donor ligands
TL;DR: A polynuclear Fe(III) cluster based on both inorganic Odonor polyoxometalate ligand and organic N-donor ligand hexamethylenetetramine has been synthesized and structurally characterized, exhibiting good electrocatalytic properties to reduce the nitrites.
Journal ArticleDOI
Organic‐Inorganic Hybrids: Preparation and Structural Characterization of (Bu4N)2[Mo6O17(NAr)2] and (Bu4N)2[Mo6O18(NAr)] (Ar = o‐CH3C6H4)
TL;DR: In this paper, the molecular and crystal structures of the hybrid compounds 1 and 2 were determined by X-ray single crystal diffraction, and their UV, IR and NMR spectra were compared.
Journal ArticleDOI
Bis(ethylenedithio)tetrathiafulvalene Radical Salts with Anderson Type Heteropolymolybdates Containing Tris(alkoxo) Ligands
Cai-Ming Liu,Yong-Hong Huang,Deqing Zhang,Song Gao,Feng-Chi Jiang,Jian-Ying Zhang,Daoben Zhu +6 more
TL;DR: Anderson type heteropolymolybdates containing trisalkoxo ligands were successfully utilized as anions to generate the bis(ethylenedithio)tetrathiafulvalene (ET) radical cation salts as mentioned in this paper.
Journal ArticleDOI
Oxomolybdenum coordination compounds with pyridine. Syntheses and structures of [Mo4O8(OCH3)2Cl2L4]·2L (L=Py, 4-MePy), [Mo4O8(OCH3)4(4-MePy)4], [Mo6O12(OCH3)6Py4] and [Mo10O26Py8]·7Py
TL;DR: In this paper, the X-ray structure analysis revealed the presence of molybdenum(V,VI) atoms and two molymoxo(VI) centers in neutral decanuclear molecules.
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