Journal ArticleDOI
Hybrid Organic−Inorganic Polyoxometalate Compounds: From Structural Diversity to Applications
TLDR
Polyoxometalates (POMs) are discrete anionic metaloxygen clusters which can be regarded as soluble oxide fragments which play a great role in various areas ranging from catalysis, medicine, electrochemistry, photochromism,5 to magnetism.Abstract:
Polyoxometalates (POMs) are discrete anionic metaloxygen clusters which can be regarded as soluble oxide fragments. They exhibit a great diversity of sizes, nuclearities, and shapes. They are built from the connection of {MOx} polyhedra, M being a d-block element in high oxidation state, usually VIV,V, MoVI, or WVI.1 While these species have been known for almost two centuries, they still attract much interest partly based on their large domains of applications. They play a great role in various areas ranging from catalysis,2 medicine,3 electrochemistry,4 photochromism,5 to magnetism.6 This palette of applications is intrinsically due to the combination of their added value properties (redox properties, large sizes, high negative charges, nucleophilicity...). Parallel to this domain, the organic-inorganic hybrids area has followed a similar expansion during the last 10 years. The concept of organic-inorganic hybrid materials * To whom correspondence should be addressed. E-mail: dolbecq@ chimie.uvsq.fr. Chem. Rev. 2010, 110, 6009–6048 6009read more
Citations
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Journal ArticleDOI
Metal–organic framework composites
Qi-Long Zhu,Qiang Xu +1 more
TL;DR: This review provides an overview of the significant advances in the development of diverse MOF composites reported till now with special emphases on the synergistic effects and applications of the composites.
Journal ArticleDOI
Recent advances in porous polyoxometalate-based metal-organic framework materials.
TL;DR: This review presents recent developments in porous POM-based MOF materials, including their classification, synthesis strategies, and applications, especially in the field of catalysis.
Journal ArticleDOI
Functionalization and post-functionalization: a step towards polyoxometalate-based materials
Anna Proust,Anna Proust,Benjamin Matt,Richard Villanneau,Geoffroy Guillemot,Pierre Gouzerh,Guillaume Izzet +6 more
TL;DR: This critical review focuses on the use of POM hybrids in selected fields of applications such as catalysis, energy conversion and molecular nanosciences and endeavor to discuss the impact of the covalent approach compared to the electrostatic one.
Journal ArticleDOI
Recent advances on polyoxometalate-based molecular and composite materials
Yu-Fei Song,Ryo Tsunashima +1 more
TL;DR: This critical review summarizes recent progress on POM-based molecular and composite materials, and particularly highlights the emerging areas that are closely related to surface, electronic, energy, environment, life science, etc.
Journal ArticleDOI
Engineering polyoxometalates with emergent properties.
TL;DR: It is shown that it is possible to construct complex chemical systems based upon polyoxometalates, manipulating the templating/self Templating rules to exhibit emergent processes from the molecular to the macroscopic scale.
References
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Journal ArticleDOI
Tetrakis(dimethyltin)-Containing Tungstophosphate [{Sn(CH3)2}4(H2P4W24O92)2]28-: First Evidence for a Lacunary Preyssler Ion
TL;DR: It is demonstrated for the first time that the superlacunary polyanion [H(2)P(4)W(24)O(94)](22)(-) reacts with electrophiles.
Journal ArticleDOI
Merging Organometallic Chemistry with Polyoxometalate Chemistry
TL;DR: A series of polyoxomolybdate-incorporated organometallic complexes has been obtained by reaction of Mn or Br with M(CO)3+ ions in methanol, sometimes in the presence of triols of the type RC(CH2OH)3 (R = Me or CH2OH).
Journal ArticleDOI
Octa- and Nonanuclear Nickel(II) Polyoxometalate Clusters: Synthesis and Electrochemical and Magnetic Characterizations
Céline Pichon,Pierre Mialane,Anne Dolbecq,Jerome Marrot,Eric Rivière,Bassem S. Bassil,Ulrich Kortz,Bineta Keita,Louis Nadjo,Francis Sécheresse +9 more
TL;DR: Electronic spectroscopy and electrochemical studies indicate that, while compounds 1-3 decompose in a pure aqueous medium, these complexes are very stable in a pH 6 acetate medium.
Journal ArticleDOI
Synthesis of molecular vanadium(III) phosphonates.
Sumit Khanra,Marc Kloth,Hassanatu Mansaray,Christopher A. Muryn,Floriana Tuna,E. Carolina Sañudo,Madeleine Helliwell,Eric J. L. McInnes,Richard E. P. Winpenny +8 more
TL;DR: Khanra, Sumit Kloth, Marc Mansaray, Hassanatu Muryn, Christopher A. Tuna, Floriana Sanudo, E. L. Winpenny, Richard E. R. WinPenny, Madeleine McInnes, Eric J.
Journal ArticleDOI
Unsymmetrical surface modification of a heteropolyoxotungstate via in - situ generation of monomeric and dimeric copper( ii ) species
TL;DR: Unsymmetrical functionalization of a discrete alpha- Keggin with two heterometallic building blocks, a Cu(II) dimer and a Cu (II) monomer, results in the formation of Cu(5,5'-dimethyl-2,2'-bipy)2 that displays interesting physical properties.
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