Journal ArticleDOI
Hybrid Organic−Inorganic Polyoxometalate Compounds: From Structural Diversity to Applications
TLDR
Polyoxometalates (POMs) are discrete anionic metaloxygen clusters which can be regarded as soluble oxide fragments which play a great role in various areas ranging from catalysis, medicine, electrochemistry, photochromism,5 to magnetism.Abstract:
Polyoxometalates (POMs) are discrete anionic metaloxygen clusters which can be regarded as soluble oxide fragments. They exhibit a great diversity of sizes, nuclearities, and shapes. They are built from the connection of {MOx} polyhedra, M being a d-block element in high oxidation state, usually VIV,V, MoVI, or WVI.1 While these species have been known for almost two centuries, they still attract much interest partly based on their large domains of applications. They play a great role in various areas ranging from catalysis,2 medicine,3 electrochemistry,4 photochromism,5 to magnetism.6 This palette of applications is intrinsically due to the combination of their added value properties (redox properties, large sizes, high negative charges, nucleophilicity...). Parallel to this domain, the organic-inorganic hybrids area has followed a similar expansion during the last 10 years. The concept of organic-inorganic hybrid materials * To whom correspondence should be addressed. E-mail: dolbecq@ chimie.uvsq.fr. Chem. Rev. 2010, 110, 6009–6048 6009read more
Citations
More filters
Journal ArticleDOI
Metal–organic framework composites
Qi-Long Zhu,Qiang Xu +1 more
TL;DR: This review provides an overview of the significant advances in the development of diverse MOF composites reported till now with special emphases on the synergistic effects and applications of the composites.
Journal ArticleDOI
Recent advances in porous polyoxometalate-based metal-organic framework materials.
TL;DR: This review presents recent developments in porous POM-based MOF materials, including their classification, synthesis strategies, and applications, especially in the field of catalysis.
Journal ArticleDOI
Functionalization and post-functionalization: a step towards polyoxometalate-based materials
Anna Proust,Anna Proust,Benjamin Matt,Richard Villanneau,Geoffroy Guillemot,Pierre Gouzerh,Guillaume Izzet +6 more
TL;DR: This critical review focuses on the use of POM hybrids in selected fields of applications such as catalysis, energy conversion and molecular nanosciences and endeavor to discuss the impact of the covalent approach compared to the electrostatic one.
Journal ArticleDOI
Recent advances on polyoxometalate-based molecular and composite materials
Yu-Fei Song,Ryo Tsunashima +1 more
TL;DR: This critical review summarizes recent progress on POM-based molecular and composite materials, and particularly highlights the emerging areas that are closely related to surface, electronic, energy, environment, life science, etc.
Journal ArticleDOI
Engineering polyoxometalates with emergent properties.
TL;DR: It is shown that it is possible to construct complex chemical systems based upon polyoxometalates, manipulating the templating/self Templating rules to exhibit emergent processes from the molecular to the macroscopic scale.
References
More filters
Journal ArticleDOI
Synthesis and characterization of three novel inorganic/organic hybrid materials based on polyoxomolybdate clusters: an investigation into the structural consequences of steric effect of the organoimine ligands
R. Nandini Devi,Jon Zubieta +1 more
TL;DR: The structures of these compounds range from three-dimensional to molecular in the case of 1 to zero-dimensional or molecular in case of 3 in accordance with the extent of steric hindrance presented by the ligand as mentioned in this paper.
Journal ArticleDOI
Hybrid polyoxometalate clusters with appended aromatic platforms
TL;DR: In this article, the assembly of polyoxometalate architectures based on Mn-Anderson clusters capped with different aromatic platforms via the Tris linker allows the formation and isolation of four new hybrid POM compounds of 2-5 with the general composition of [n-N(C4H9)4]3[MnMo6O18{(OCH2)3CN = CH-R}2]·solv.
Journal ArticleDOI
Lanthanopolyoxometalates as Building Blocks for Multiwavelength Photoluminescent Organic-Inorganic Hybrid Materials
Carlos M. Granadeiro,Rute A. S. Ferreira,Paula C. R. Soares-Santos,Luís D. Carlos,Helena I. S. Nogueira +4 more
TL;DR: In this article, an organic-inorganic hybrid material was prepared by combining lanthanide(III) substituted Wells-Dawson anions as inorganic building blocks and 3-hydroxypicolinate (picOH) as the organic ligand.
Journal ArticleDOI
Cyclic molecular materials based on [M2O2S2]2+ cores (M = Mo or W).
TL;DR: How conventional precursors can serve, when used with a drop of imagination, to the synthesis of sophisticated inorganic rings and wheels is illustrated.
Journal ArticleDOI
Photochromic hybrid organic-inorganic liquid-crystalline materials built from nonionic surfactants and polyoxometalates: elaboration and structural study.
Andreas S. Poulos,Doru Constantin,Patrick Davidson,Marianne Impéror,Brigitte Pansu,Pierre Panine,Lionel Nicole,Clément Sanchez +7 more
TL;DR: These hybrid nanocomposites exhibit optical properties that may be useful for applications involving UV-light-sensitive coatings or liquid-crystal-based photochromic switches and should be very helpful models for the study of both the static and dynamic properties of nano-objects confined within soft lamellar structures.
Related Papers (5)
Polyoxometalates: Building Blocks for Functional Nanoscale Systems
Polyoxometalate clusters, nanostructures and materials: From self assembly to designer materials and devices
Polyoxometalate Chemistry: An Old Field with New Dimensions in Several Disciplines
Michael T. Pope,Achim Müller +1 more