Journal ArticleDOI
Hybrid Organic−Inorganic Polyoxometalate Compounds: From Structural Diversity to Applications
TLDR
Polyoxometalates (POMs) are discrete anionic metaloxygen clusters which can be regarded as soluble oxide fragments which play a great role in various areas ranging from catalysis, medicine, electrochemistry, photochromism,5 to magnetism.Abstract:
Polyoxometalates (POMs) are discrete anionic metaloxygen clusters which can be regarded as soluble oxide fragments. They exhibit a great diversity of sizes, nuclearities, and shapes. They are built from the connection of {MOx} polyhedra, M being a d-block element in high oxidation state, usually VIV,V, MoVI, or WVI.1 While these species have been known for almost two centuries, they still attract much interest partly based on their large domains of applications. They play a great role in various areas ranging from catalysis,2 medicine,3 electrochemistry,4 photochromism,5 to magnetism.6 This palette of applications is intrinsically due to the combination of their added value properties (redox properties, large sizes, high negative charges, nucleophilicity...). Parallel to this domain, the organic-inorganic hybrids area has followed a similar expansion during the last 10 years. The concept of organic-inorganic hybrid materials * To whom correspondence should be addressed. E-mail: dolbecq@ chimie.uvsq.fr. Chem. Rev. 2010, 110, 6009–6048 6009read more
Citations
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Journal ArticleDOI
Metal–organic framework composites
Qi-Long Zhu,Qiang Xu +1 more
TL;DR: This review provides an overview of the significant advances in the development of diverse MOF composites reported till now with special emphases on the synergistic effects and applications of the composites.
Journal ArticleDOI
Recent advances in porous polyoxometalate-based metal-organic framework materials.
TL;DR: This review presents recent developments in porous POM-based MOF materials, including their classification, synthesis strategies, and applications, especially in the field of catalysis.
Journal ArticleDOI
Functionalization and post-functionalization: a step towards polyoxometalate-based materials
Anna Proust,Anna Proust,Benjamin Matt,Richard Villanneau,Geoffroy Guillemot,Pierre Gouzerh,Guillaume Izzet +6 more
TL;DR: This critical review focuses on the use of POM hybrids in selected fields of applications such as catalysis, energy conversion and molecular nanosciences and endeavor to discuss the impact of the covalent approach compared to the electrostatic one.
Journal ArticleDOI
Recent advances on polyoxometalate-based molecular and composite materials
Yu-Fei Song,Ryo Tsunashima +1 more
TL;DR: This critical review summarizes recent progress on POM-based molecular and composite materials, and particularly highlights the emerging areas that are closely related to surface, electronic, energy, environment, life science, etc.
Journal ArticleDOI
Engineering polyoxometalates with emergent properties.
TL;DR: It is shown that it is possible to construct complex chemical systems based upon polyoxometalates, manipulating the templating/self Templating rules to exhibit emergent processes from the molecular to the macroscopic scale.
References
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Journal ArticleDOI
Straightforward synthesis of new polyoxometalate-based hybrids exemplified by the covalent bonding of a polypyridyl ligand
TL;DR: A new polyoxometalate-based organic-inorganic platform has been designed for further facile derivatization and covalent attachment of organic linkers; this is exemplified by the grafting of a polypyridyl ligand.
Journal ArticleDOI
Polyoxometalate clusters as building blocks: preparation and structure of bis(hexamolybdate) complexes covalently bridged by organodiimido ligands
TL;DR: Covalently linked polyoxometalate clusters are produced in the reaction of organic diisocyanates with [Bu4N]2[Mo6O19] as mentioned in this paper.
Journal ArticleDOI
A novel isopolytungstate functionalized by ruthenium: [HW9O33RuII2(dmso)6]7−
TL;DR: The ruthenium-supported isopolyanion [HW9O33RuII2(dmso)6]7− (1) is composed of a non-atungstate wheel stabilized by two Ru(DMso)3 groups, representing the first structurally characterized Ru-coordinated polyoxotungstate.
Journal ArticleDOI
Self‐Assembly of [B‐SbW9O33]9− Subunit with Transition Metal Ions (Mn2+, Cu2+, Co2+) in Aqueous Solution: Syntheses, Structures and Magnetic Properties of Sandwich Type Polyoxometalates with Subvalent SbIII Heteroatom
TL;DR: Structural analysis reveals that compound 2 represents the first one-dimensional sinusoidal chain based on sandwich like tungstoantimonate building blocks through the carboxylate-bridging ligands and 3 shows an interesting 3D framework built up from offset sandwich type polyoxoanion.
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