Journal ArticleDOI
Hydrogen adsorption in the nanoporous metal-benzenedicarboxylate M(OH)(O2C–C6H4–CO2)(M = Al3+, Cr3+), MIL-53
Gérard Férey,Michel Latroche,Christian Serre,Franck Millange,Thierry Loiseau,A. Percheron-Guégan +5 more
TLDR
Hydrogen adsorption has been studied in the nanoporous metal-benzenedicarboxylate M(OH)(O2C-C6H4-CO2) (M = Al3+, Cr3+); these solids show a hydrogen storage capacity of 3.8 and 3.1 wt.% respectively when loaded at 77 K under 1.6 MPa.About:
This article is published in Chemical Communications.The article was published on 2003-12-08. It has received 660 citations till now. The article focuses on the topics: Nanoporous & Hydrogen storage.read more
Citations
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Carbon Dioxide Capture in Metal–Organic Frameworks
Kenji Sumida,David L. Rogow,Jarad A. Mason,Thomas M. McDonald,Eric D. Bloch,Zoey R. Herm,Tae-Hyun Bae,Jeffrey R. Long +7 more
TL;DR: Kenji Sumida, David L. Rogow, Jarad A. Mason, Thomas M. McDonald, Eric D. Bloch, Zoey R. Herm, Tae-Hyun Bae, Jeffrey R. Long
Journal ArticleDOI
Hybrid porous solids: past, present, future
TL;DR: The state-of-the-art on hybrid porous solids, their advantages, their new routes of synthesis, the structural concepts useful for their 'design', aiming at reaching very large pores are presented.
Journal ArticleDOI
Hydrogen storage in metal–organic frameworks
TL;DR: This critical review of the current status of hydrogen storage within microporous metal-organic frameworks provides an overview of the relationships between structural features and the enthalpy of hydrogen adsorption, spectroscopic methods for probing framework-H(2) interactions, and strategies for improving storage capacity.
Journal ArticleDOI
Hydrogen Storage in Metal–Organic Frameworks
Journal ArticleDOI
Metal-organic frameworks: a new class of porous materials
TL;DR: A review of the synthesis, structure, and properties of metal-organic frameworks (MOFs) is presented in this paper, highlighting the important advances in their research over the past decade.
References
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Journal ArticleDOI
Hydrogen-storage materials for mobile applications
TL;DR: Recent developments in the search for innovative materials with high hydrogen-storage capacity are presented.
Journal ArticleDOI
Hydrogen Storage in Microporous Metal-Organic Frameworks
Nathaniel L. Rosi,Juergen Eckert,Mohamed Eddaoudi,David T. Vodak,Jaheon Kim,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Inelastic neutron scattering spectroscopy of the rotational transitions of the adsorbed hydrogen molecules indicates the presence of two well-defined binding sites (termed I and II), which are associated with hydrogen binding to zinc and the BDC linker, respectively.
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Very Large Breathing Effect in the First Nanoporous Chromium(III)-Based Solids: MIL-53 or CrIII(OH)·{O2C−C6H4−CO2}·{HO2C−C6H4−CO2H}x·H2Oy
Christian Serre,Franck Millange,Christelle Thouvenot,Marc Noguès,Gérard Marsolier,Daniel Louër,Gérard Férey +6 more
TL;DR: The first three-dimensional chromium(III) dicarboxylate, MIL-53as or CrIII(OH)·{O2C−C6H4−CO2}·{HO2C −C 6H4 −CO2H}0.75, has been obtained under hydrothermal conditions (as: as-synthesized).
Journal ArticleDOI
High H2 uptake by alkali-doped carbon nanotubes under ambient pressure and moderate temperatures
TL;DR: The high hydrogen-uptake capacity of these systems may be derived from the special open-edged, layered structure of the carbon nanotubes made from methane, as well as the catalytic effect of alkali metals.
Journal ArticleDOI
Hydrogen Storage in Graphite Nanofibers
TL;DR: Graphite nanofibers are a novel material that is produced from the dissociation of carbon-containing gases over selected metal surfaces as discussed by the authors, which consists of very small graphite platelets, 30−500...