Journal ArticleDOI
Improved hydrogen production from formic acid on a Pd/C catalyst doped by potassium
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TLDR
The rate of hydrogen production from vapour-phase formic acid decomposition can be increased by 1-2 orders of magnitude by doping a Pd/C catalyst with potassium ions.About:
This article is published in Chemical Communications.The article was published on 2012-04-02. It has received 97 citations till now. The article focuses on the topics: Potassium formate & Potassium.read more
Citations
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Liquid-phase chemical hydrogen storage materials
Mahendra Yadav,Qiang Xu +1 more
TL;DR: In this paper, the authors survey the research progress in hydrogen generation from liquid-phase chemical hydrogen storage materials and their regeneration, and present a review of these materials in hydrogen storage.
Journal ArticleDOI
Liquid organic and inorganic chemical hydrides for high-capacity hydrogen storage
Qi-Long Zhu,Qiang Xu +1 more
TL;DR: A review of the research progress in the development of diverse liquid-phase chemical hydrogen storage materials, including organic and inorganic chemical hydrides, with emphases on the syntheses of active catalysts for catalytic hydrogen generation and storage is presented in this paper.
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In Situ Confinement of Ultrasmall Pd Clusters within Nanosized Silicalite-1 Zeolite for Highly Efficient Catalysis of Hydrogen Generation.
TL;DR: The easy in situ confinement synthesis of metal clusters in zeolites endows the catalysts with superior catalytic activities, excellent recyclability, and high thermal stability, thus opening new perspectives for the practical application of FA as a viable and effective H2 storage material for use in fuel cells.
Journal ArticleDOI
Hydrogen energy future with formic acid: a renewable chemical hydrogen storage system
TL;DR: In this article, the use of formic acid as a reversible source for hydrogen storage is discussed, where the authors focus on recent developments in this direction, which will likely give access to a variety of low-cost and highly efficient rechargeable hydrogen fuel cells within the next few years by using suitable homogeneous metal complex/heterogeneous metal nanoparticle-based catalysts under ambient reaction conditions.
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An Efficient CoAuPd/C Catalyst for Hydrogen Generation from Formic Acid at Room Temperature**
TL;DR: The first-row transition metals (FRTM)innanoscale, such as cobalt (Co) nanoparticles (NPs), have been widelyigated as the catalytic materials in many important reactions because of their potential activities and relatively low costs.
References
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Journal ArticleDOI
Hydrogen production from formic acid decomposition at room temperature using a Ag-Pd core-shell nanocatalyst
Karaked Tedsree,Tong Li,Simon Jones,Chun Wong Aaron Chan,Kai Man Kerry Yu,Paul A. J. Bagot,Emmanuelle A. Marquis,George Davey Smith,Shik Chi Edman Tsang +8 more
TL;DR: It is reported that Ag nanoparticles coated with a thin layer of Pd atoms can significantly enhance the production of H₂ from formic acid at ambient temperature.
Journal ArticleDOI
Alkali-stabilized Pt-OHx species catalyze low-temperature water-gas shift reactions.
Yanping Zhai,Danny Pierre,Rui Si,Weiling Deng,Peter Ferrin,Anand Udaykumar Nilekar,Guowen Peng,Jeffrey A. Herron,David C. Bell,Howard Saltsburg,Manos Mavrikakis,Maria Flytzani-Stephanopoulos +11 more
TL;DR: Alkali ions added in small amounts activate platinum adsorbed on alumina or silica for the low-temperature water-gas shift (WGS) reaction (H2O + CO → H2 + CO2) used for producing H2.
Journal ArticleDOI
Catalytic Generation of Hydrogen from Formic acid and its Derivatives: Useful Hydrogen Storage Materials
TL;DR: In this article, the concept of using formic acid as a hydrogen storage material is presented, and the main part the historic development and recent examples of homogeneously catalyzed hydrogen generation from Formic acid are covered in detail.
Journal ArticleDOI
High-quality hydrogen from the catalyzed decomposition of formic acid by Pd–Au/C and Pd–Ag/C
TL;DR: Pd-Au/C and Pd-Ag/C were found to have a unique characteristic of evolving high-quality hydrogen dramatically and steadily from the catalyzed decomposition of liquid formic acid at convenient temperature, and further this was improved by the addition of CeO(2)(H(2)O)(x).
Journal ArticleDOI
Formic acid dehydrogenation on au-based catalysts at near-ambient temperatures.
Manuel Ojeda,Enrique Iglesia +1 more
TL;DR: Dehydrogenation occurs through formate decomposition limited by H(2) desorption on Au species undetectable by TEM, making products suitable for low-temperature fuel cells.
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