Journal ArticleDOI
Liquid organic and inorganic chemical hydrides for high-capacity hydrogen storage
Qi-Long Zhu,Qiang Xu +1 more
TLDR
A review of the research progress in the development of diverse liquid-phase chemical hydrogen storage materials, including organic and inorganic chemical hydrides, with emphases on the syntheses of active catalysts for catalytic hydrogen generation and storage is presented in this paper.Abstract:
The search for hydrogen storage materials capable of efficiently storing hydrogen in a compact and lightweight package is one of the most difficult challenges for the upcoming hydrogen economy. Liquid chemical hydrides with high gravimetric and volumetric hydrogen densities have the potential to overcome the challenges associated with hydrogen storage. Moreover, the liquid-phase nature of these hydrogen storage systems provides significant advantages of easy recharging, and the availability of the current liquid fuel infrastructure for recharging. In this review, we briefly survey the research progress in the development of diverse liquid-phase chemical hydrogen storage materials, including organic and inorganic chemical hydrides, with emphases on the syntheses of active catalysts for catalytic hydrogen generation and storage. Moreover, the advantages and drawbacks of each storage system are discussed.read more
Citations
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Journal ArticleDOI
Metal-Organic Frameworks for Energy Applications
TL;DR: In this paper, the authors present the recent progress in the field of energy storage and conversion using metal-organic frameworks and their composites and derivatives by focusing on the correlation of structure, composition, and function.
Journal ArticleDOI
Homogeneous Catalysis for Sustainable Hydrogen Storage in Formic Acid and Alcohols.
Katerina Sordakis,Conghui Tang,Lydia K. Vogt,Henrik Junge,Paul J. Dyson,Matthias Beller,Gábor Laurenczy +6 more
TL;DR: In this paper, the authors describe the considerable progress that has been made in homogeneous catalysis for these critical reactions, namely, the hygienic reaction, and describe a review of the most relevant work in this area.
Journal ArticleDOI
Liquid Organic Hydrogen Carriers (LOHCs): Toward a Hydrogen-free Hydrogen Economy
TL;DR: This Account highlights the current state-of-the-art in hydrogen storage using LOHC systems and introduces fundamental aspects of a future hydrogen economy and derives therefrom requirements for suitable LohC compounds.
Journal ArticleDOI
Large-scale storage of hydrogen
TL;DR: In this article, options for the large-scale storage of hydrogen are reviewed and compared based on fundamental thermodynamic and engineering aspects and the application of certain storage technologies, such as liquid hydrogen, methanol, ammonia, and dibenzyltoluene, is found to be advantageous in terms of storage density, cost of storage, and safety.
Journal ArticleDOI
In Situ Confinement of Ultrasmall Pd Clusters within Nanosized Silicalite-1 Zeolite for Highly Efficient Catalysis of Hydrogen Generation.
TL;DR: The easy in situ confinement synthesis of metal clusters in zeolites endows the catalysts with superior catalytic activities, excellent recyclability, and high thermal stability, thus opening new perspectives for the practical application of FA as a viable and effective H2 storage material for use in fuel cells.
References
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Journal ArticleDOI
Hydrogen-storage materials for mobile applications
TL;DR: Recent developments in the search for innovative materials with high hydrogen-storage capacity are presented.
Journal ArticleDOI
Hydrogen storage in metal–organic frameworks
TL;DR: This critical review of the current status of hydrogen storage within microporous metal-organic frameworks provides an overview of the relationships between structural features and the enthalpy of hydrogen adsorption, spectroscopic methods for probing framework-H(2) interactions, and strategies for improving storage capacity.
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Alternative energy technologies
M. S. Dresselhaus,I. L. Thomas +1 more
TL;DR: Fossil fuels currently supply most of the world's energy needs, and however unacceptable their long-term consequences, the supplies are likely to remain adequate for the next few generations.
Journal ArticleDOI
Metal hydride materials for solid hydrogen storage: a review
TL;DR: A review of metal hydrides on properties including hydrogen-storage capacity, kinetics, cyclic behavior, toxicity, pressure and thermal response is presented in this article, where a group of Mg-based hydride stand as promising candidate for competitive hydrogen storage with reversible hydrogen capacity up to 7.6 W% for on-board applications.
Journal ArticleDOI
An overview of hydrogen production technologies
TL;DR: A review of technologies related to hydrogen production from both fossil and renewable biomass resources including reforming (steam, partial oxidation, autothermal, plasma, and aqueous phase) and pyrolysis is presented in this article.
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