Journal ArticleDOI
Kinetic modeling of hydrocarbon/nitric oxide interactions in a flow reactor
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In this paper, the reduction of nitric oxide by reaction with C1 and C2 hydrocarbons under reducing conditions in a flow reactor has been analyzed in terms of a detailed chemical kinetic model.About:
This article is published in Combustion and Flame.The article was published on 1998-10-01. It has received 494 citations till now. The article focuses on the topics: Methane.read more
Citations
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Fuel nitrogen conversion in solid fuel fired systems
TL;DR: In this article, the effect of fuel characteristics, devolatilization conditions and combustion mode on the oxidation selectivity towards NO and N 2 is evaluated and even under idealized conditions, such as a laminar pulverized-fuel flame, the governing mechanisms for fuel nitrogen conversion are not completely understood.
Journal ArticleDOI
Modeling nitrogen chemistry in combustion
TL;DR: In this paper, a review of the current understanding of the mechanisms that are responsible for combustion-generated nitrogen-containing air pollutants is discussed, along with the chemistry of NO removal processes such as reburning and selective non-catalytic reduction of NO.
Journal ArticleDOI
Implementation of the NCN pathway of prompt-NO formation in the detailed reaction mechanism
TL;DR: In this paper, a detailed reaction mechanism for small hydrocarbons combustion with possibly full implementation of available kinetic data related to the prompt NO route via NCN was presented, which can accurately predict the NO formation in lean and rich flames of methane, ethylene, ethane and propane.
Journal ArticleDOI
Unravelling combustion mechanisms through a quantitative understanding of elementary reactions
TL;DR: A review of the role of reaction kinetics in combustion chemistry traces the historical evolution and present state of qualitative and quantitative understanding of a number of reaction systems, starting from the H2-O2 system, in particular from the reaction between H and O2, mechanisms and key reactions for soot formation, for the appearance of NOx, and for processes of peroxy radicals in hydrocarbon oxidation are illustrated as mentioned in this paper.
Journal ArticleDOI
Master equation methods in gas phase chemical kinetics.
TL;DR: The application of master equation methods to problems in gas phase chemical kinetics, focusing on reactions that take place over multiple, interconnected potential wells and on the dissociation of weakly bound free radicals, is discussed.
References
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ReportDOI
Chemkin-II : A Fortran Chemical Kinetics Package for the Analysis of Gas Phase Chemical Kinetics
Journal ArticleDOI
Mechanism and modeling of nitrogen chemistry in combustion
James A. Miller,Craig T. Bowman +1 more
TL;DR: In this article, the mechanisms and rate parameters for the gas-phase reactions of nitrogen compounds that are applicable to combustion-generated air pollution are discussed and illustrated by comparison of results from detailed kinetics calculations with experimental data.
Journal ArticleDOI
Evaluated Kinetic Data for Combustion Modelling
Donald L. Baulch,Carlos J. Cobos,Richard A. Cox,C. Esser,P. Frank,Th. Just,J. A. Kerr,Michael J. Pilling,Jürgen Troe,Raymond W. Walker,J. Warnatz +10 more
TL;DR: In this paper, the authors present a compilation of critically evaluated kinetic data on elementary homogeneous gas phase chemical reactions for use in modelling combustion processes Data sheets are presented for some 196 reactions each data sheet sets out relevant thermodynamic data, rate coefficient measurements, an assessment of the reliability of the data, references and recommended rate parameters Tables summarizing the preferred rate data are also given
Journal ArticleDOI
Chemical Kinetic Data Base for Combustion Chemistry. Part I. Methane and Related Compounds
W. Tsang,R. F. Hampson +1 more
TL;DR: In this paper, the authors evaluated data on the kinetics and thermodynamic properties of species that are of importance in methanepyrolysis and combustion, including H, H2, O, O2, OH, HO2, CH2O, CH4, C2H6, HCHO, CO2, CO, HCO, CH3, CH5, CH6, CH7, CH8, CH9, CH10, CH11, CH12, CH13, CH14, CH15, CH16, CH17, CH
Evaluated kinetic data for combustion modelling supplement I
Donald L. Baulch,Carlos J. Cobos,Richard A. Cox,P. Frank,Garry Hayman,Th. Just,J. A. Kerr,T. Murrells,M. A. Pilling,Jürgen Troe,Raymond W. Walker,J. Warnatz +11 more
TL;DR: In this article, a compilation of kinetic data on elementary, homogeneous, gas phase reactions of neutral species involved in combustion systems has been presented under the auspices of the European Community Energy Research and Development Program.